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This article is an attempt at evaluating new important features of tin(II) chemistry the central point is the interrelationship between molecular structure and reactivity of molecular tin(II) compounds. To define these compounds more closely, only those are discussed which are stable, monomeric in solvents and which may be classified as carbene analogs21. Thus, not a complete survey of tin(II) chemistry is given but stress is laid on the structures and reactions of selected compounds. A general introduction to the subject precedes the main chapters. For comparison, also solid-state tin(II) chemistry is included to demonstrate the great resemblance with molecular tin(II) chemistry. Tin(II) compounds, which are either generated as intermediates or only under definite conditions such as temperature or pressure, are not described in detail. [Pg.8]

Liquid chromatography is preceded by a precipitation of the asphaltenes, then the maltenes are subjected to chromatography. Although the separation between saturated hydrocarbons and aromatics presents very few problems, this is not the case with the separation between aromatics and resins. In fact, resins themselves are very aromatic and are distinguished more by their high heteroatom content (this justifies the terms, polar compounds or N, S, 0 compounds , also used to designate resins). [Pg.83]

Jet fuel is subject to particular attention in all operations that precede and accompany its use in accordance with the draconian air transport safety regulations (Anon., 1983). [Pg.250]

Various kinds of potentials have been referred to in the course of this and the preceding chapter, and their interrelation is the subject of the present section. The chief problem is that certain types of potential differences are physically meaningful in the sense that they are operationally defined, whereas others that may be spoken of more vaguely are really conceptual in nature and may not be definable experimentally. [Pg.205]

The matter of surface mobility has come up at several points in the preceding material. The subject has been a source of confusion—see Ref. 112. Actually, two kinds of concepts seem to have been invoked. The first is that invoked in the discussion of physical adsorption, which has to do with whether the adsorbate can move on the surface so freely that its state is essentially that of a two-dimensional nonideal gas. For an adsorbate to be mobile in this sense, surface barriers must be small compared to kT. This type of mobile adsorbed layer seems unlikely to be involved in chemisorption. [Pg.709]

In an extension of the work described m the preceding section Bender showed that basic ester hydrolysis was not concerted and like acid hydrolysis took place by way of a tetrahedral intermediate The nature of the experiment was the same and the results were similar to those observed m the acid catalyzed reaction Ethyl benzoate enriched m 0 at the carbonyl oxygen was subjected to hydrolysis m base and samples were isolated before saponification was complete The recovered ethyl benzoate was found to have lost a por tion of Its isotopic label consistent with the formation of a tetrahedral intermediate... [Pg.855]

The contents of each tube are then subjected to electrophoresis m separate lanes on the same sheet of polyacrylamide gel and the DNAs located by autoradiography A typical electrophoresis gel of a DNA fragment containing 50 nucleotides will exhibit a pattern of 50 bands distributed among the four lanes with no overlaps Each band cor responds to a polynucleotide that is one nucleotide longer than the one that precedes it (which may be m a different lane) One then simply reads the nucleotide sequence according to the lane m which each succeeding band appears... [Pg.1181]

The material of this chapter and, for that matter, of the two preceding chapters has wide applicability in the area of technology and manufacture. To do justice to this facet of the subject would require a book in itself, so we must settle for a few paragraphs concerned with industrial applications. [Pg.200]

In addition to the various vinyl polymers diseussed in the preceding seven chapters a large number of other polymers of this type have been described in the literature. Some of these have achieved commercial significance and those which have interest as plastics or closely related materials are the subject of this chapter. [Pg.466]

The many papers in this proceedings are partitioned into very abstruse theoretical analyses of structure and stability of quasicrystals on the one hand, and practical studies of surface structures, mechanical properties and potential applications. The subject shows signs of becoming as deeply divided between theorists and practical investigators, out of touch with each other, as magnetism became in the preceding century. [Pg.418]

A fault tree may either stand alone or be coupled to an event tree to quantif" bability. The top event in either case is the abjective of performing the analysis. If tht is the reliability of a system under specific conditions - then that is the top event. If it is to qua iify a node of an event tree the top event title is that of that particular node subject to the condi ons imposed by the preceding modes. [Pg.105]

The category indicator results may then be analyzed further by norrnaliza tion, grouping, and weighting. 7 hese procedures are optional in the standard, as they are not as well known as the preceding steps and they contain more subjective elements. The aim of these steps is to clarify the results by comparing them to some reference. [Pg.1363]

The preceding stress-strain and strain-stress relations are the basis for stiffness and stress analysis of an individual lamina subjected to forces in its own plane. Thus, the relations are indispensable in laminate analysis. [Pg.72]

Arcing contacts in Division 2 areas must be installed in explosion-proof enclosures, be immersed in oil, be hermetically sealed, or be non-incendive. High-temperature devices must be installed in explosion-proof enclosures. Fuses must be enclosed in explosion-proof enclosures unless the fuses are preceded by an explosion-proof, hermetically sealed, or oil-immersed switch and the fuses are used for overcurrent protection of instrument circuits not subject to overloading in normal use. [Pg.525]

While the smooth substrate considered in the preceding section is sufficiently reahstic for many applications, the crystallographic structure of the substrate needs to be taken into account for more realistic models. The essential complications due to lack of transverse symmetry can be dehneated by the following two-dimensional structured-wall model an ideal gas confined in a periodic square-well potential field (see Fig. 3). The two-dimensional lamella remains rectangular with variable dimensions Sy. and Sy and is therefore not subject to shear stresses. The boundaries of the lamella coinciding with the x and y axes are anchored. From Eqs. (2) and (10) one has... [Pg.12]

When corrosion develops on painted steel the question is often raised as to whether corrosion was a result of paint failure or the paint failure was caused by corrosion. Several studies have shown that adhesion forces are reduced greatly after water soaking or even at very high humidity -and it has been argued that film detachment by water usually precedes underfilm corrosion . Against this view others have claimed that those paints known to have reduced wet adhesion, e.g. those based on alkyd resins, are not uniquely, or even especially, subject to underfilm corrosion Several factors should be considered in this discussion ... [Pg.618]

The preceding four sections summarize only part of the content of the following four chapters several interesting results have not been mentioned. To keep the paper within bounds, I had to forego detailed discussion of aspects I deemed less important. For this subject matter, definitions and even formal calculations and heuristic deductions seem to me often more important than complete proofs. Thus, proofs were eliminated first in particular, in the case of several analogous propositions the proof of only one theorem is... [Pg.8]

In conclusion, the agreement of all of these methods based upon radioactive decay furnishes a strong clue that the earth s crust as we know it today was formed about five billion years ago. What preceded is a subject of intense interest and monumental disagreement. [Pg.444]

Standards Most buildings have never been subjected to thorough engineering analyses. Traditional precedent and judgment as reviewed under Codes have (logically) controlled the standards. In fact if wood had never been used, it would be difficult to approve (burns, rots, etc.) of course it is ridiculous to assume that wood would not be approved. [Pg.245]

A description of an aura (a subjective sensation preceding a seizure) if any has oocurred... [Pg.259]

Please describe planned study population. Choice of participants should be appropriate for the indication proposed. Subjects should not have enrolled in a clinical trial during the preceding 12 weeks. Please describe how special populations such as women of childbearing age, children and the elderly will be handled in this study. Please comment on the special need for close monitoring due to safety considerations. [Pg.83]

Figure 10. The relationship between the initial glycogen content in vastus lateralis muscle and work time in six subjects who cycled to exhaustion at 75% VO2 max. Each subject cycled to exhaustion on three occasions. The first experiment was preceded by a mixed diet (a), the second by a carbohydrate-poor diet (o), and the third by a carbohydrate-rich diet ( ). The energy contents of the diets were identical. In all experiments depletion of the muscle glycogen store coincided with exhaustion and muscle fatigue. From Bergstrom et al. (1967) with permission from the publisher. Figure 10. The relationship between the initial glycogen content in vastus lateralis muscle and work time in six subjects who cycled to exhaustion at 75% VO2 max. Each subject cycled to exhaustion on three occasions. The first experiment was preceded by a mixed diet (a), the second by a carbohydrate-poor diet (o), and the third by a carbohydrate-rich diet ( ). The energy contents of the diets were identical. In all experiments depletion of the muscle glycogen store coincided with exhaustion and muscle fatigue. From Bergstrom et al. (1967) with permission from the publisher.

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See also in sourсe #XX -- [ Pg.13 , Pg.67 , Pg.68 , Pg.69 , Pg.70 , Pg.71 , Pg.72 , Pg.73 , Pg.126 , Pg.127 ]




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