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Sulfur stripping

Aspirate through ammoniacal cadmium chloride strip sulfur dioxide by aeration dissolve cadmium sulfide precipitate in concentrated HC1 titrate with iodine using a starch indicator. Iodometric titration 0.7 qg/L NR EPA 1978... [Pg.161]

Material Beaker, battery (4.5 V), voltmeter (multimeter), electric motor, cable and alligator clips two lead strips, sulfuric acid solution (20%). [Pg.231]

If sulfur is a contaminant, its content can be measured, but it may suffice to characterize its effects by the copper strip corrosion test, or by the doctor test". [Pg.274]

Corrosive sulfur NFT 60-131 ISO 5662 ASTM D 1275 Observation of copper strip after immersion for 19 h at HOT... [Pg.447]

Science dealerships aren t the only places to get the stuff one needs. At those mega hardware stores one can find pure acetone, methanol, ethanol, toluene, methyl ethyl ketone, DCM(as a constituent of some stripping agents), sodium hydroxide in the form of lye, and some acids such as sulfuric and hydrochloric. These precious tools can be bought there cheaply and in great quantity. [Pg.13]

Naphtha desulfurization is conducted in the vapor phase as described for natural gas. Raw naphtha is preheated and vaporized in a separate furnace. If the sulfur content of the naphtha is very high, after Co—Mo hydrotreating, the naphtha is condensed, H2S is stripped out, and the residual H2S is adsorbed on ZnO. The primary reformer operates at conditions similar to those used with natural gas feed. The nickel catalyst, however, requires a promoter such as potassium in order to avoid carbon deposition at the practical levels of steam-to-carbon ratios of 3.5—5.0. Deposition of carbon from hydrocarbons cracking on the particles of the catalyst reduces the activity of the catalyst for the reforming and results in local uneven heating of the reformer tubes because the firing heat is not removed by the reforming reaction. [Pg.420]

Stripping is accompHshed by dehydration using sulfuric acid (38), lithium chloride [7447-41-8] (39), and tertiary amines containing from 14—32 carbon atoms in an organic solvent immiscible with water followed by thermal treatment of the HCl—organic complex (40). [Pg.446]

Aniline Oxidation. Even though this is quite an old process, it still has limited use to produce hydroquinone on a commercial scale. In the first step, aniline is oxidized by manganese dioxide in aqueous sulfuric acid. The resulting benzoquinone, isolated by vapor stripping, is reduced in a second step by either an aqueous acidic suspension of iron metal or by catalytic hydrogenation. [Pg.487]

Owing to the cycHc nature of the TBRC operation, waste heat recovery from the off-gases is not practical and the SO2 content of the gas varies with the converter cycle. In order to supply a relatively uniform flow and strength SO2 gas to a sulfuric acid plant, a system has been installed at RonnskAr whereby the SO2 from fluctuating smelter gases is partially absorbed in water. During smelter gas intermption, SO2 is stripped with air and the concentrated gas deflvered to the acid plant. [Pg.40]

The development of selective extractants for copper has made extraction from dilute solutions (1—5 kg/m ) economically feasible. Transfer of the copper by stripping to a more concentrated sulfuric acid solution, ie, 30—40 kg/m for Cu " and 150—170 kg/m for H2SO4, from which the copper is recovered by electrowinning. The simplified reaction,... [Pg.172]

Natural gas contains both organic and inorganic sulfur compounds that must be removed to protect both the reforming and downstream methanol synthesis catalysts. Hydrodesulfurization across a cobalt or nickel molybdenum—zinc oxide fixed-bed sequence is the basis for an effective purification system. For high levels of sulfur, bulk removal in a Hquid absorption—stripping system followed by fixed-bed residual clean-up is more practical (see Sulfur REMOVAL AND RECOVERY). Chlorides and mercury may also be found in natural gas, particularly from offshore reservoirs. These poisons can be removed by activated alumina or carbon beds. [Pg.276]

The reaction is completed after 6—8 h at 95°C volatiles, water, and some free phenol are removed by vacuum stripping up to 140—170°C. For resins requiring phenol in only trace amounts, such as epoxy hardeners, steam distillation or steam stripping may be used. Both water and free phenol affect the cure and final resin properties, which are monitored in routine quaHty control testing by gc. OxaHc acid (1—2 parts per 100 parts phenol) does not require neutralization because it decomposes to CO, CO2, and water furthermore, it produces milder reactions and low color. Sulfuric and sulfonic acids are strong catalysts and require neutralization with lime 0.1 parts of sulfuric acid per 100 parts of phenol are used. A continuous process for novolak resin production has been described (31,32). An alternative process for making novolaks without acid catalysis has also been reported (33), which uses a... [Pg.297]

In another process variant, only 88% of the nitrobenzene is reduced, and the reaction mixture then consists of two phases the precious metal catalyst (palladium on activated carbon) remains in the unreacted nitrobenzene phase. Therefore, phase separation is sufficient as work-up, and the nitrobenzene phase can be recycled direcdy to the next batch. The aqueous sulfuric acid phase contains 4-aminophenol and by-product aniline. After neutralization, the aniline is stripped, and the aminophenol is obtained by crystallization after the aqueous phase is purified with activated carbon (53). [Pg.311]

Fixed-bed desulfuri2ation is impractical and uneconomical if the natural gas contains large amounts of sulfur. In this case, bulk sulfur removal and recovery (qv) in an acid gas absorption—stripping system, followed by fixed-bed residual cleanup is usually employed. [Pg.346]

The sulfate ester hydrolysate is stripped to give a mixture of isopropyl alcohol, isopropyl ether, and water overhead, and dilute sulfuric acid bottoms. The overhead is neutralized using sodium hydroxide and refined in a two-column distillation system. Diisopropyl ether is taken overhead in the first, ie, ether, column. This stream is generally recycled to the reactors to produce additional isopropyl alcohol by the following equiUbrium reaction ... [Pg.108]

The bottoms from the stripper (40—60 wt % acid) are sent to an acid reconcentration unit for upgrading to the proper acid strength and recycling to the reactor. Because of the associated high energy requirements, reconcentration of the diluted sulfuric acid is a cosdy operation. However, a propylene gas stripping process, which utilizes only a small amount of added water for hydrolysis, has been described (63). In this modification, the equiUbrium quantity of isopropyl alcohol is stripped so that acid is recycled without reconcentration. Kquilibrium is attained rapidly at 50°C and isopropyl alcohol is removed from the hydrolysis mixture. Similarly, the weak sulfuric acid process minimizes the reconcentration of the acid and its associated corrosion and pollution problems. [Pg.108]

Chemical recovery ia sodium-based sulfite pulpiag is more complicated, and a large number of processes have been proposed. The most common process iavolves liquor iaciaeration under reduciag conditions to give a smelt, which is dissolved to produce a kraft-type green liquor. Sulfide is stripped from the liquor as H2S after the pH is lowered by CO2. The H2S is oxidized to sulfur ia a separate stream by reaction with SO2, and the sulfur is subsequendy burned to reform SO2. Alternatively, ia a pyrolysis process such as SCA-Bidemd, the H2S gas is burned direcdy to SO2. A rather novel approach is the Sonoco process, ia which alumina is added to the spent liquors which are then burned ia a kiln to form sodium aluminate. In anther method, used particulady ia neutral sulfite semichemical processes, fluidized-bed combustion is employed to give a mixture of sodium carbonate and sodium sulfate, which can be sold to kraft mills as makeup chemical. [Pg.274]

The anaerobic reaction of sulfur dioxide with aqueous ammonia produces a solution of ammonium sulfite [10192-30-0]. This reaction proceeds efficientiy, even with a gas stream containing as Httie as 1 wt % sulfur dioxide. The sulfur dioxide can be regenerated at a high concentration by acidulation or by stream stripping of the ammonium sulfite solution, or the sulfite can be made to precipitate and the ammonia recovered by addition of lime (243). The process can also be modified to produce ammonium sulfate for use as fertili2er (244) (see Fertilizers). In a variant of this process, the use of electron-beam radiation cataly2es the oxidation of sulfur dioxide in the presence of ammonia to form ammonium sulfate (245). [Pg.144]

Liquid SO is usually produced by distilling SO vapor from oleum and condensing it. This operation is normally carried out at a sulfuric acid plant where the stripped oleum can be readily refortified or reused. EHminating all traces of sulfuric acid from the SO vapor stream is important to minimize polymerization of the Hquid condensate. When this is done, it is frequently possible to utilize unstabilized Hquid SO if precautions are taken to prevent it from freezing before use. At some plants, gaseous 100% SO is utilized directly instead of producing Hquid. [Pg.187]

Sulfur dioxide concentrations in oleum ate rarely specified or measured, but typical values are considerably higher than in acids of <99 wt % concentrations. This occurs because oleum is produced at relatively low temperatures in the presence of appreciable SO2 in the gas phase, thus lea ding to high solubihty. It is not possible to strip SO2 from oleums by air blowing, a technique that is ftequentiy appHed to product acids of <99% concentration. [Pg.192]


See other pages where Sulfur stripping is mentioned: [Pg.41]    [Pg.627]    [Pg.41]    [Pg.627]    [Pg.80]    [Pg.81]    [Pg.279]    [Pg.186]    [Pg.428]    [Pg.428]    [Pg.446]    [Pg.516]    [Pg.185]    [Pg.132]    [Pg.175]    [Pg.251]    [Pg.64]    [Pg.131]    [Pg.3]    [Pg.169]    [Pg.169]    [Pg.328]    [Pg.346]    [Pg.353]    [Pg.353]    [Pg.422]    [Pg.283]    [Pg.565]    [Pg.50]    [Pg.81]    [Pg.88]    [Pg.120]   
See also in sourсe #XX -- [ Pg.190 ]




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