Interfacial stresses

The mechanism of droplet deformation can be briefly summarized as follows. The factors affecting the droplet deformation are the viscosity ratio, shear stress, interfacial tension, and droplet particle size. Although elasticity takes an important role for general thermoplastics droplet deformation behavior, it is not known yet how it affects the deformation of TLCP droplet and its relationship with the processing condition. Some of... 

Mechanical compatibilization is accomplished by reducing the size of the dispersed phase. The latter is determined by the balance between drop breakup and coalescence process, which in turn is governed by the type and severity of the stress, interfacial tension between the two phases, and the rheological characteristics of the components [9]. The need to reduce potential energy initiates the agglomeration process, which is less severe if the interfacial tension is small. Addition... 

Wear is the process of physical loss of material. In sliding contacts this can arise from a number of processes in order of relative importance they are adhesion, abrasion, corrosion and contact fatigue. Wear occurs because of local mechanical failure of highly stressed interfacial zones and the mode of failure is influenced by environmental factors. 

We want to emphasize that a logarithmic time dependence of d and w, and the corresponding decrease of V, are not expected for a Newtonian liquid [42]. Moreover, our results cover times shorter than the longest relaxation time in equilibrated bulk samples (i.e., the reptation time). Thus, the visco-elastic properties of PS certainly affect our dewetting experiments. Thus, a detailed theoretical model has been developed that takes into account residual stresses, interfacial friction (i.e., slippage), and visco-elasticity [42,44,46],... 

Diffusion-induced stress, interfacial charge transfer, and criteria for... 

Diffusion-induced stress, interfacial charge transfer, and criteria for avoiding crack initiation of electrode particles. J. Electrochem. Soc., 157 (4), A508-A516. 

A reasonably close match of thermal expansion of the coating and substrate over a wide temperature range to limit failure caused by residual stresses is desired for coatings. Because temperature gradients cause stress even in a weU-matched system, the mechanical properties, strength, and ductUity of the coating as well as the interfacial strength must be considered. 

Film Adhesion. The adhesion of an inorganic thin film to a surface depends on the deformation and fracture modes associated with the failure (4). The strength of the adhesion depends on the mechanical properties of the substrate surface, fracture toughness of the interfacial material, and the appHed stress. Adhesion failure can occur owiag to mechanical stressing, corrosion, or diffusion of interfacial species away from the interface. The failure can be exacerbated by residual stresses in the film, a low fracture toughness of the interfacial material, or the chemical and thermal environment or species in the substrate, such as gases, that can diffuse to the interface. 

Compressive interfacial stresses increase the interfacial shear resistance. Although usually detrimental to toughening, these stresses can enhance toughening if bridge pullout is the operative toughening process. 

Fig. 9. Residual stresses owing to thermal expansion mismatch between a particle with radius a and thermal expansion coefficient and a matrix with thermal expansion coefficient The stresses illustrated here are for and P is the interfacial pressure.

The emulsification process in principle consists of the break-up of large droplets into smaller ones due to shear forces (10). The simplest form of shear is experienced in lamellar flow, and the droplet break-up may be visualized according to Figure 4. The phenomenon is governed by two forces, ie, the Laplace pressure, which preserves the droplet, and the stress from the velocity gradient, which causes the deformation. The ratio between the two is called the Weber number. We, where Tj is the viscosity of the continuous phase, G the velocity gradient, r the droplet radius, and y the interfacial tension. 

T Solid-vapor interfacial energy dyn/cm dyn/cm z Pow der shear stress kg/cm psf... 

In a mechanical test, interfacial strength may be quantified in terms of either the minimum load required for interface disruption or the total integral energy or work expended. In many situations, due to non-uniformity of chemical or morphological conditions over the area of the interface or to non-uniformity of the applied stress in a given test [7], the two criteria are different. The investigator must thus strive to minimize or deal with both of the above complications, i.e. the interfaces studied should be chemically and morphologically uniform, and the stresses applied in the test should be uniform or distributed in way which is quantitatively describable. 

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