Stress ceramic

Residual radiation, from nuclear power facilities, 17 553-554 Residual stress/strain measurement diffractometers in, 26 428—430 Residual thermal stresses ceramics, 5 632-633... 

Ceramic Pressure stressed ceramic per Me Cormick Selph Specification NS—161. Will withstand 25,000 psi applied in 10 msec. Insulation resistance is above 10QQO- megohms... 

With increasing demands for electric transportation systems and/or electric vehicles, semiconductor power modules such as electric power converters and DC-AC inverters will continue to expand in terms of their applications. In these systems, in order to transmit a high electric current, thick copper electrodes are often directly bonded to ceramic substrates, the structures of which may cause major residual stresses in ceramic parts. Thus, to avoid failure due to residual stress, ceramic materials are required to have a high strength and, in order to further improve the reUabUity of the systems, improvements in the mechanical properties of high-thermal conductivity materials are clearly required. Consequently, the electrical industries are continuing an active search for alternative materials with both high thermal conductivity and superior mechanical properties. 

Fligh-tech ceramics withstand great mechanical stresses even thin structures and sharp edges are feasible with high reliability. This allows connecting the HT cables reliably to the ceramic part of the tubes directly. Many available resin systems bond easily to ceramics. 

Fig. 1. Stress and temperature ranges of apphcation for Zr02 (—), Si N (-), and SiC (--) advanced stmctural ceramics. To convert MPa to psi,...

Fig. 3. Stress mpture behavior in air at 1200°C for SiC stmctural ceramics —hot-pressed -, reaction-bonded , sintered alpha —sintered beta. To...

SiHcon nitride (see Nitrides) is a key material for stmctural ceramic appHcations in environments of high mechanical and thermal stress such as in vehicular propulsion engines. Properties which make this material uniquely suitable are high mechanical strength at room and elevated temperatures, good oxidation and creep resistance at high temperatures, high thermal shock resistance, exceUent abrasion and corrosion resistance, low density, and, consequently, a low moment of inertia. Additionally, siHcon nitride is made from abundant raw materials. 

A more extensive comparison of many potential turbine blade materials is available (67). The refractory metals and a ceramic, sHicon nitride, provide a much higher value of 100 h stress—mpture life, normalised by density, than any of the cobalt- or nickel-base aHoys. Several intermetaHics and intermetaUic matrix composites, eg, aHoyed Nb Al and MoSi —SiC composites, also show very high creep resistance at 1100°C (68). Nevertheless, the superaHoys are expected to continue to dominate high temperature aHoy technology for some time. 

Thermal Stresses and Properties. In general, ceramic reinforcements (fibers, whiskers, or particles) have a coefficient of thermal expansion greater than that of most metallic matrices. This means that when the composite is subjected to a temperature change, thermal stresses are generated in both components. 

Boltzmann s constant, and T is tempeiatuie in kelvin. In general, the creep resistance of metal is improved by the incorporation of ceramic reinforcements. The steady-state creep rate as a function of appHed stress for silver matrix and tungsten fiber—silver matrix composites at 600°C is an example (Fig. 18) (52). The modeling of creep behavior of MMCs is compHcated because in the temperature regime where the metal matrix may be creeping, the ceramic reinforcement is likely to be deforming elastically. 

Cases can be classified as either hermetic or nonhermetic, based on their permeabiUty to moisture. Ceramics and metals are usually used for hermetic cases, whereas plastic materials are used for nonhermetic appHcations. Cases should have good electrical insulation properties. The coefficient of thermal expansion of a particular case should closely match those of the substrate, die, and sealing materials to avoid excessive residual stresses and fatigue damage under thermal cycling loads. Moreover, since cases must provide a path for heat dissipation, high thermal conductivity is also desirable. 

Over time a large variety of materials have been used, including ivory, stainless steel, chromium—cobalt, and ceramics for the acetabular component. None proved sufficient. The implant material composition must provide a smooth surface for joint articulation, withstand hip joint stresses from normal loads, and the substance must disperse stress evenly to the cement and surrounding bone. 

Vitahium FHS ahoy is a cobalt—chromium—molybdenum ahoy having a high modulus of elasticity. This ahoy is also a preferred material. When combiaed with a properly designed stem, the properties of this ahoy provide protection for the cement mantle by decreasing proximal cement stress. This ahoy also exhibits high yields and tensile strength, is corrosion resistant, and biocompatible. Composites used ia orthopedics include carbon—carbon, carbon—epoxy, hydroxyapatite, ceramics, etc. 

Plastic Forming. A plastic ceramic body deforms iaelastically without mpture under a compressive load that produces a shear stress ia excess of the shear strength of the body. Plastic forming processes (38,40—42,54—57) iavolve elastic—plastic behavior, whereby measurable elastic respoase occurs before and after plastic yielding. At pressures above the shear strength, the body deforms plastically by shear flow. 

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