Stibine sulfides

Complexes with absorbing solution Arsine, stibine, hydrogen sulfide... 

Antimon-saure, /. antimonic acid, -saureanhy-drid, n. antimonic anhydride, antimony pent-oxide. -silber, n. antimonial silver, dyscrasite. -silberblende,/. pyrargyrite. -silberglanz, m. stephanite. -spiegel, m. antimony mirror, -sulfid, n. antimony sulfide, specif, antimony pentasulfide, antimony(V) sulfide, -sulfiir, n. antimony trisulfide, antimony(III) sulfide, -yerblndung,/. antimony compound, -wasser--stoff, m. antimony hydride, stibine. -weiss, n. antimony white (Sb Oa). -zinnober, m. kermes mineral. 

MLTC bands, S, 575 NMR.5,574 Raman, 5, 575 stereochemistry, 5,538-572 stibine ligands, S, 584 sulfides, S, 584 sulfurdiimine reactivity, 2,194 sulfur dioxide, 5,584 sulfur ligands, 5,584 synthesis, 5,536-538... 

Stannic and stannous, see under Tin Stibine, see Antimony hydride Stibnite, see Antimony(III) sulfide Stolzite, see Lead tungstate(VI)(2—)... 

Bis(trifluoromethyl) stibine, 16 49 Bis(trifluoromethyl) sulfide, 2 134, 146 Bis(trifluoromethyl) sulfur tetrafluoride, 2 139,... 

Oxidations of Amines, Amides, Ethers, Sulfides, Phosphines, Arsines, Stibines and Miscellaneous Substrates... 

Abstract This chapter principally concerns oxidations of organic substrates containing N, O, S, P, As and Sb. Oxidations of amines are covered first, including primary amines to nitriles or amides secondary amines to imines or other products tertiary amines to N-oxides or other prodncts (Section 5.1) and the oxidation of amides (5.2). Oxidation of ethers to esters or lactones follows (5.3), then of sulfides to sulfoxides or sulfones (5.4) and of phosphines, arsine and stibines to their oxides (5.5). A final section (5.6) concerns such miscellaneous oxidations not covered by other sections in the book. 

Antimony Pentasulfide. See under Sulfides Antimony Selenide. See under Selenides Antimony Sulfides. See under Sulfides Antimony Telluride, See under Tellurides Antimony Trichloride. See under Chlorides Antimony Triethyl. Same as Triethylstibine Antimony Trimethyl. Same as Trimethyl-stibine... 

Triphenyl stibine has been prepared 1 from antimony trichloride and chlorobenzene dissolved in dry benzene in the presence of sodium. This yields triphenyl stibine dichloride, which on decomposition with hydrogen sulfide yields triphenyl stibine. Triphenyl stibine has also been prepared2 by the action of phenyl magnesium bromide and antimony trichloride. 

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