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Stark cell

To achieve large electric fields, the separation of the Stark electrodes is made as small as possible (typically about 1 mm). This generally excludes an intracavity arrangement because the diffraction by this narrow aperture would introduce intolerably large losses. The Stark cell is therefore placed outside the resonator, and for enhanced sensitivity the electric field is modulated while the dc field is tuned. This modulation technique is also common in microwave spectroscopy. The accuracy of 10 " for the Stark field measurements allows a precise determination of the absolute value for the electric dipole moment. [Pg.63]

Figure 13. Close-up view of the Stark cell used in Ref. 10. A 5 pm hole in a 10 pm thick stainless steel disk served as aperture. At the same time the steel disk was used as ground electrode for the electrical field. The anode separated by spacers of 300 pm was made out of a glass plate coated with Sn02. A DC-Voltage of 0-1 kV resulted in an electrical field of 0 to 3.3 MV/m in the. .-direction. Figure 13. Close-up view of the Stark cell used in Ref. 10. A 5 pm hole in a 10 pm thick stainless steel disk served as aperture. At the same time the steel disk was used as ground electrode for the electrical field. The anode separated by spacers of 300 pm was made out of a glass plate coated with Sn02. A DC-Voltage of 0-1 kV resulted in an electrical field of 0 to 3.3 MV/m in the. .-direction.
In addition to neuronal loss, more subtle alterations in neuronal and synaptic function are observed after TBI. Because these changes do not involve stark cell loss, they are potentially reversible. Before discussing alterations, it is perhaps important to give an overview of synaptic structure and function. Synapses can be either electrical or chemical. We focus on chemical synapses (called synapses for the rest of the chapter) because they are, by far, the most common type of synapse. Synapses are incredibly small structures, with a diameter of 300 150 nm and a gap of only 20 2.8nm (Ribrault et al., 2011). By and large, synapses comprise three parts a presynaptic site, a postsynaptic site, and a glial element (Figure 47.4). [Pg.699]

Studied with a waveguide bridge-type MWFT spectrometer equipped with flat, oversize Stark cells. [Pg.329]

FIGURE 28 Illustration of a high-temperature reaction flow system coupled to a microwave spectrometer for producing short-lived molecules. The gas is made to flow through the Stark cell by means of vacuum system and the flow rate is adjusted by a needle valve. The 8-mm-inside-diameter quartz tube is heated in a 10-cm-long furnace. The distance between the cell and furnace is also about 10 cm. [From Kroto. H. W. (1982)]. Chem. Soc. Rev. 11,435.)... [Pg.331]

In the microwave region tunable monochromatic radiation is produced by klystrons, each one being tunable over a relatively small frequency range, or a backward wave oscillator, tunable over a much larger range. Both are electronic devices. Absorption experiments are usually carried out in the gas phase, and mica windows, which transmit in this region, are placed on either end of the absorption cell, which may be several metres in length. Stark... [Pg.59]

A striking feature of the cellular automata (CA) models is that they treat not only the ingredients, or agents, of the model as discrete entities, as do the traditional models of physics and chemistry, but now time (iterations) and space (the cells) are also regarded as discrete, in stark contrast to the continuous forms for these parameters assumed in the traditional, equation-based models. In practice, as we shall see, this distinction makes little or no difference, for the traditional continuous results appear, quite naturally, as limiting cases of the discrete CA analyses. Nonetheless, this quantization of time and space does raise some interesting theoretical and philosophical questions, which we shall, however, ignore at this time. ... [Pg.11]

Maly FE, Marti-Wyss S, Blumer S, Cuhat-Stark I, Wiithrich B Mononuclear blood cell sulfidoleukot-riene generation in the presence of interleukin-3 and whole blood histamine release in honey bee and yellow jacket venom allergy. J Investig Allergol Clin Immunol 1997 7 217-224. 49... [Pg.156]

Figure 12.8 CO-saturated electrolyte in the thin cell of Fig. 12.2. (a) CO oxidation the first and second scans are shown, (b) Comparison with the CO stretch frequency shift. (Filled circles denote linear Stark tuning behavior while open circles correspond to deviations from linear behavior during oxidation.)... Figure 12.8 CO-saturated electrolyte in the thin cell of Fig. 12.2. (a) CO oxidation the first and second scans are shown, (b) Comparison with the CO stretch frequency shift. (Filled circles denote linear Stark tuning behavior while open circles correspond to deviations from linear behavior during oxidation.)...
BB-SFG, we have investigated CO adsorption on smooth polycrystaHine and singlecrystal electrodes that could be considered model surfaces to those apphed in fuel cell research and development. Representative data are shown in Fig. 12.16 the Pt nanoparticles were about 7 nm of Pt black, and were immobilized on a smooth Au disk. The electrolyte was CO-saturated 0.1 M H2SO4, and the potential was scanned from 0.19 V up to 0.64 V at 1 mV/s. The BB-SFG spectra (Fig. 12.16a) at about 2085 cm at 0.19 V correspond to atop CO [Arenz et al., 2005], with a Stark tuning slope of about 24 cm / V (Fig. 12.16b). Note that the Stark slope is lower than that obtained with Pt(l 11) (Fig. 12.9), for reasons to be further investigated. The shoulder near 2120 cm is associated with CO adsorbed on the Au sites [Bhzanac et al., 2004], and the broad background (seen clearly at 0.64 V) is from nomesonant SFG. The data shown in Figs. 12.4, 12.1 la, and 12.16 represent a hnk between smooth and nanostructure catalyst surfaces, and will be of use in our further studies of fuel cell catalysts in the BB-SFG IR perspective. [Pg.396]

The hemolymphal transport of carotenoids by lipophorin has been elucidated and documented (Law and Wells 1989, Tsuchida et al. 1998, Arrese et al. 2001, Canavoso et al. 2001), as has plasma transport by mammalian lipoproteins (Paker 1996, Yeum and Russell 2002). Lipophorin serves as a shuttle that moves carotenoids from one tissue to another without itself entering the cells, in stark contrast to the vertebrate low-density lipoprotein (LDL) (Brown and Goldstein 1986), which is endocytosed and metabolized in the cell. Here, we focus on the recent biochemical and genetic studies of the intracellular CBP of the silkworm, which mainly transports lutein. We hope this review provides insights into the studies of CBPs in other organisms. [Pg.512]

Hmbach, L.K., Wick, P., Manser, P., Grass, R.N., Bruinink, A., and Stark, W.J. (2007) Exposure of engineered nanopartides to human lung epithelial cells influence of chemical composition and catalytic activity on oxidative stress. Environmental Science and Technology,... [Pg.136]

Elfinger M, Pfeifer C, Uezguen S, Golas MM, Sander B, Maucksch C, Stark H, Aneja MK, Rudolph C (2009) Self-assembly of ternary insulin-polyethylenimine (PEI)-DNA nanoparticles for enhanced gene delivery and expression in alveolar epithelial cells. Biomacromolecules 10 2912-2920... [Pg.26]

Stark, A. K., Uylings, H. B., Sanz-Arigita, E. and Pakkenberg, B. Glial cell loss in the anterior cingulated cortex, a subregion of the prefrontal cortex, in subjects with schizophrenia. Am. J. Psychiatry 161 882-888, 2004. [Pg.885]

In smooth muscle, the sarcoplasmic reticulum (SR) plays an important role in regulating cell excitability by communicating intimately with ion channels in the surface membrane. In most cases, Ca2+ release from ryanodine-sensitive Ca2+ release channels (RyRs) in the SR leads to a paradoxical decrease in smooth muscle cell excitability due to activation of plasma membrane K+ channels (Fig. 1 Nelson et al 1995). This is in stark contrast to cardiac muscle, where Ca2+ release from RyRs supplies the majority (> 90%) of Ca2+ required for contraction (Cheng et al 1993, Cannell et al 1995). In this paper, we will briefly review the basic... [Pg.189]


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See also in sourсe #XX -- [ Pg.84 , Pg.88 ]




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