Specialty plastics polyethylene

Polymerization of alkene monomers, with or without functional groups, are very important industrial processes. Until recently the use of homogeneous catalysts was restricted to relatively small-volume production of specialty dimers and oligomers. The manufacture of the two largest-tonnage plastics— polyethylene and polypropylene—has so far been based on heterogeneous catalytic processes. 

Specialty polymers achieve very high performance and find limited but critical use in aerospace composites, in electronic industries, as membranes for gas and liquid separations, as fire-retardant textile fabrics for firefighters and race-car drivers, and for biomedical applications (as sutures and surgical implants). The most important class of specialty plastics is polyimides. Other specialty polymers include polyetherimide, poly(amide-imide), polybismaleimides, ionic polymers, polyphosphazenes, poly(aryl ether ketones), polyarylates and related aromatic polyesters, and ultrahigh-molecular-weight polyethylene (Fig. 14.9). 

Another version of PE, the ultra-high molecular weight polyethylene is used as a specialty plastic (in artificial hip, knee and shoulder joints), mainly due to its exceptional impact strength, low wear, good stress-crack resistance, durability, and excellent energy absorption characteristics. 

Plastic lumber is recycled plastics processed such as commingled plastic, polyethylene plastic, and polypropylene plastic. To improve their performances different developments have been used such as specialty additives (lubricants, deoxidizers, etc.). An example is by adding as low as 10 wt% of short glass fiber to these recycled plastics can double their strength. Other fibers used include hemp, flax, and sisal. They are principally extruded other processes are used such as injection and compression molding, to produce products competitive to wood lumber on land and in the water. Compression molding allows for a deep-molded grain and a much more dense board. The density also helps the product resist moisture absorption and improves weatherability. 

Styrene-based plastics are used somewhat in blow mol ding but not as much as linear polyethylene and PVC. HIPS and ABS are used in specialty botdes, containers, and furniture parts. ABS is also used as one of the impact modifiers for PVC. Clear, tough bottles with good barrier properties are blow-molded from these formulations. 

The isoprene units in the copolymer impart the ability to crosslink the product. Polystyrene is far too rigid to be used as an elastomer but styrene copolymers with 1,3-butadiene (SBR rubber) are quite flexible and rubbery. Polyethylene is a crystalline plastic while ethylene-propylene copolymers and terpolymers of ethylene, propylene and diene (e.g., dicyclopentadiene, hexa-1,4-diene, 2-ethylidenenorborn-5-ene) are elastomers (EPR and EPDM rubbers). Nitrile or NBR rubber is a copolymer of acrylonitrile and 1,3-butadiene. Vinylidene fluoride-chlorotrifluoroethylene and olefin-acrylic ester copolymers and 1,3-butadiene-styrene-vinyl pyridine terpolymer are examples of specialty elastomers. 

The second section deals with the degradability of commodity plastics and specialty potymers. Emphasis is on the biodegradation of polyethylene, its blends with starch, and constraints in the decay of such composites. Additionally, the biodegradability of different functional groups (polyethers, carbotylic adds, esters, and dioxanones) is mcamined with respect to composition and miaostructure. 

As of 1998, Exxon was the third largest U.S. corporation in terms of revenues, in excess of 122 billion. It was incorporated in the state of New Jersey in 1898 and became a distinct entity upon the dissolution of the Standard Oil Trust in 1911. In 1997 about 14 billion (10.3% of Exxon s total revenue) was attributed to chemicals, making it the third largest U.S. producer of chemicals. The chemical products include basic petrochemicals, including olefins and aromatics, additives for fuels and lubricants, polyethylene and polypropylene plastics, specialty resins, specialty and commodity solvents, and performance chemicals for oil field operations. 

Exxon Chemical Company became a worldwide organization in 1965 and in 2000 was a major producer and marketer of olefins, aromatics, polyethylene and polypropylene along with specialty lines such as elastomers, plasticizers, solvents, process fluids, oxo alcohols and adhesive resins. The two chemical companies combined their operations within ExxonMobil Chemical. 

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