Solutions, low-viscosity

Compared with insulin aqueous solution, low-viscosity insulin containing hyalur-onate (0.1-0.2%) greatly enhanced the pharmacological availability of insulin via pulmonary delivery routes to rats [57]. Morimoto et al. [57] subsequently examined the effects of intratracheal administration of different concentrations and pH va-... 

Although commonly used resins are sometimes sold as solutions, they are usually obtained in powder or pellet form. No single solvent is suitable for all types of resin, so that the choice of solvent must be tailored to the particular resin used. For wood, the first choice might be between polar and nonpolar solvents. The latter would allow resin solutions to penetrate wood better because polar solvents tend to get adsorbed on cell walls, and adsorption reduces their mobility (11). Additionally, solvents with low boiling points are preferable because they minimize problems with residual vapors. Another consideration is the viscosity of a given solution. Low viscosity is necessary if good penetration is desired. Some commonly used solvents are ethanol, methanol, acetone, and toluene. 

Solution Low viscosity Better heat control May be used directly as solution Potential toxicity, flammability and environmental pollution of solvents Polymer product contains solvent impurities Yield lower than in bulk polymerization Expensive due to additional solvent costs... 

Dimethyl sulfite and diethyl sulfite EC-based electrolyte solution Low viscosity co-solvents, good low temperature performance 151... 

Small molecules in low viscosity solutions have, typically, rotational correlation times of a few tens of picoseconds, which means that the extreme narrowing conditions usually prevail. As a consequence, the interpretation of certain relaxation parameters, such as carbon-13 and NOE for proton-bearing carbons, is very simple. Basically, tlie DCC for a directly bonded CH pair can be assumed to be known and the experiments yield a value of the correlation time, t. One interesting application of the measurement of is to follow its variation with the site in the molecule (motional anisotropy), with temperature (the correlation... 

Microemulsion Polymerization. Polyacrylamide microemulsions are low viscosity, non settling, clear, thermodynamically stable water-in-od emulsions with particle sizes less than about 100 nm (98—100). They were developed to try to overcome the inherent settling problems of the larger particle size, conventional inverse emulsion polyacrylamides. To achieve the smaller microemulsion particle size, increased surfactant levels are required, making this system more expensive than inverse emulsions. Acrylamide microemulsions form spontaneously when the correct combinations and types of oils, surfactants, and aqueous monomer solutions are combined. Consequendy, no homogenization is required. Polymerization of acrylamide microemulsions is conducted similarly to conventional acrylamide inverse emulsions. To date, polyacrylamide microemulsions have not been commercialized, although work has continued in an effort to exploit the unique features of this technology (100). 

Some plastics caimot be obtained in a low viscosity melt or solution that can be processed into a cellular state. For these cases two methods have been used to achieve the needed dispersion of gas in solid sintering of solid plastic particles and leaching of soluble inclusions from the solid plastic phase. 

Gum Arabic. Gum arabic [9000-01-5] is an exudate of the Acacia tree, found in the Middle East. It dissolves readily in water to produce low viscosity solutions. It is used in confectionery products, bakery toppings, beverages, fro2en dairy products, and dry drink mixes (86). 

Succinoglycan can form viscous solutions if in the free acid or calcium salt form, but produces low viscosity solutions if in the sodium salt form... 

Spray Drying. Spray-dry encapsulation processes (Fig. 7) consist of spraying an intimate mixture of core and shell material into a heated chamber where rapid desolvation occurs to thereby produce microcapsules (24,25). The first step in such processes is to form a concentrated solution of the carrier or shell material in the solvent from which spray drying is to be done. Any water- or solvent-soluble film-forming shell material can, in principle, be used. Water-soluble polymers such as gum arable, modified starch, and hydrolyzed gelatin are used most often. Solutions of these shell materials at 50 wt % soHds have sufficiently low viscosities that they stiU can be atomized without difficulty. It is not unusual to blend gum arable and modified starch with maltodextrins, sucrose, or sorbitol. 

Depending on the concentration, the solvent, and the shear rate of measurement, concentrated polymer solutions may give wide ranges of viscosity and appear to be Newtonian or non-Newtonian. This is illustrated in Eigure 10, where solutions of a styrene—butadiene—styrene block copolymer are Newtonian and viscous at low shear rates, but become shear thinning at high shear rates, dropping to relatively low viscosities beyond 10 (42). The... 

Gum arable comes from various species of Acacia. The gum exudes through cracks, injuries, and incisions in the bark and is collected by hand as dried tears. Gum arable is unique among gums because of its high solubiUty and the low viscosity and Newtonian flow of its solutions. While other gums form highly viscous solutions at 1—2% concentration, 20% solutions of gum arable resemble a thin sugar symp in body and flow properties. 

Higher butyryl esters, formulated with acryUc polymers, provide coatings with excellent weather resistance, good colorfastness and dispersibiUty, and good flow properties (154). Formulations for a typical automotive refinishing lacquer and a wood furniture lacquer are given in Tables 12 and 13, respectively. Low viscosity, high butyryl cellulose esters tolerate substantial amounts of alcohol solvent without appreciable increase in solution viscosity. 

Individual particle surfaces can be lubricated by an adsorbed film that produces a smoother surface and/or decreases interparticle attraction. A plasticized binder may serve this purpose. Forming surfaces can be lubricated by coating with a film of low viscosity Hquid such as water or oil. Die surfaces can also be coated with a solution of stearic acid dissolved in a volatile Hquid that rapidly evaporates to leave a lubricating film. 

Infiltration (67) provides a unique means of fabricating ceramic composites. A ceramic compact is partially sintered to produce a porous body that is subsequently infiltrated with a low viscosity ceramic precursor solution. Advanced ceramic matrix composites such as alumina dispersed in zirconia [1314-23-4] Zr02, can be fabricated using this technique. Complete infiltration produces a homogeneous composite partial infiltration produces a surface modified ceramic composite. 

An appHcation where latex paints show outstanding performance is over masonry such as stucco or ciader block constmction. This performance results from saponification resistance ia the preseace of the alkaH from the cement. Furthermore because masoary surfaces are porous, having both small and large pores, the low viscosity external phase of a latex paint can penetrate rapidly iato the small pores, causiag a rapid iacrease ia the viscosity of the remaining paiat. The bulk paiat, ia turn, sinks iato the larger holes more slowly than a solution-based paint. Thus less latex paint is required to cover the same surface area as compared to alkyd paints. 

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