Segregation flow-induced

Fig.36. Variation in electrical conductivity (o) with molecular weight for polyethylene composites filled with 4% by volume carbon black, demonstrating the effects of orientation (I), degradation (II) and flow-induced segregation of carbon black aggregates (III). ( ) injection moulded (O) compression moulded (unoriented) [181]...

Carrera, C. and Patino, J.M.R. Flow-induced molecular segregation in p-casein-monoglyceride mixed films spread at the air-water interface, Langmuir, 20, 6327, 2004b. 

Because of the flow-induced segregation of phases with different shear viscosity, the preferred method of testing multiphase polymeric systems is dynamic, in cone-and-plate geometry (alternatively, between parallel plates). An exception is a study of the... 

These measures of solute segregation are closely related to the spatial and temporal patterns of the flow in the melt. Most of the theories that will be discussed are appropriate for laminar convection of varying strength and spatial structure. Intense laminar convection is rarely seen in the low-Prandtl-number melts typical of semiconductor materials. Instead, nonlinear flow transitions usually lead to time-periodic and chaotic fluctuations in the velocity and temperature fields and induce melting and accelerated crystal growth on the typically short time scale (order of 1 s) of the fluctuations. 

The mixing efficiency was characterized by a dimensionless parameter, called the intensity of segregation, for the six scenarios [68], This parameter is based on the distribution of the mass fractions of the species. The results given in Table 1.4 show the importance of the z-component of the flow velocity to induce penetration of species and thus to promote mixing. 

The ultimate cause of bubble formation is the universal tendency of gas-solid flows to segregate. Many studies on the theory of stability [3, 4] have shown that disturbances induced in an initially homogeneous gas-solid suspension do not decay but always lead to the formation of voids. The bubbles formed in this way exhibit a characteristic flow pattern whose basic properties can be calculated with the model of Davidson and Harrison [30], Figure 5 shows the streamlines of the gas flow relative to a bubble rising in a fluidized bed at minimum fluidization conditions (e = rmf). The characteristic parameter is the ratio a of the bubble s upward velocity u, to the interstitial velocity of the gas in the suspension surrounding the bubble ... 

Furthermore, the friction forces acting in the flow field can induce phase segregation at the mould surface [189]. As pointed out by Cakmak and Cronin [191], in PP/EP blends with a high content of EP particles even shear amplification phenomena may occur due to the presence of the small rubber particles. The shear amplification results from considerable shear fields occurring in small gaps between rubber particles which in turn are subjected to the macroscopic shear field extended over the whole width of the sample. 

Dust generation and fluidization of the material should be minimized during material movement. Dust can be controlled by way of socks or sleeves, to contain the material as it drops from the blender to the bin, for example. Some devices are commercially available. An example of this is a solids decelerator shown in Figure 11. Drop heights should be minimal, as they aerate the material, induce dust, and increase momentum of the material as it hits the pile, all of which can increase the tendency for each of the three segregation mechanisms to occur. Valves should be operated correctly. Butterfly valves should be operated in the full open position, not throttled to restrict flow. 

Computational mechanics, and in particular the DE method, may be successfully used to analyze a wide range of operations involving powders and granular materials. Of particular relevance in a pharmaceutical context are applications related to flow of powders in hoppers (66), fluidized beds (67), and mixers (68,69). The method has been applied in the analysis of ball mills (70) and may be used to look more deeply into certain processes such as vibration-induced size segregation of granular materials (71) and packing (72). 

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