Sandalwoods East Indian

Sandalwood, East Indian Santalum album L. (-l-)-a-Santalol (45-55), (-)-p-santalol (18-24)... 

C15H21N30 5-(3-(dimethylamino)propoxy)-3-methyl-1-phen 15083-53-1 450.15 39.116 2 28769 C15H240 oil of sandalwood, east Indian 8006-87-9 553.43 49.040 2... 

Sandalwood, East Indian, oil. See Sandalwood (Santalum album) oil... 

Sandalwood, East Indian Santalum album L. Santalaceae Wood Wild MQ... 

C. The only lerpene-like natural hydrocarbon containing nine C atoms. It is found in East Indian sandalwood oil and also in Siberian, German and Swedish pine-needle oils. It has a rather unpleasant smell, resinifies easily and is difficult to obtain pure. 

East Indian sandalwood oil contains a hydrocarbon given the name santene (C9H14) Ozona tion of santene followed by hydrolysis gives compound A What is the structure of santene" ... 

Sandalwood Oil, East Indian. The use of sandalwood oil for its perfumery value is ancient, probably extending back some 4000 years. Oil from the powdered wood and roots of the tree Santalum album L. is produced primarily in India, under government control. Good quaUty oil is a pale yellow to yellow viscous Hquid characterized by an extremely soft, sweet—woody, almost ariimal—balsarnic odor. The extreme tenacity of the aroma makes it an ideal blender—fixative for woody-Oriental—floral fragrance bases. It also finds extensive use for the codistillation of other essential oils, such as rose, especially in India. There the so-called attars are made with sandalwood oil distilled over the flowers or by distillation of these flowers into sandalwood oil. The principal constituents of sandalwood oil are shown in Table 11 (37) and Figure 2. 

There exists in East Indian sandalwood oil an alcohol, of the formula CjHjgO, which has been named santelol, or santenone alcohol. It is closely allied to, and much resembles, the alcohol obtained by the hydration of the hydrocarbon, santene q.v.), and is probably stereo-isomeric with it. There is some difference of opinion as to the proper nomenclature of the two alcohols. According to Charabot, the naturally occurring alcohol, also obtainable by the reduction of santenone, is analogous to borneol, and should therefore be termed, if that analogy is... 

Sandalwood oil. East Indian is obtained by steam distillation of the heartwood of Santalum album L. (Santalaceae). It is a slightly viscous, almost colorless to yellow liquid with a characteristic, sweet, woody, long-lasting odor. 

East Indian sandalwood oil consists almost exclusively of closely related sesquiterpenoids by far the main constituents are the alcohols a-santalol [115-71-9], 45-55%, and /3-santalol [77-42-9], 18-24%. Mainly responsible for the odor is /3-santalol. [261, 764-769]. 

East Indian sandalwood oils are used extensively in perfumery as very valuable, stable fixatives. FCT 1974 (12) p.989 [8006-87-9], [84787-70-2]. 

Sandalwood Oil, East Indian Type, occurs as a pale yellow to yellow, somewhat viscous, oily liquid with a strong, persistent, characteristic odor. It is the volatile oil obtained by steam distillation from the dried, ground roots and wood of Santalum album L. (Fam. Santalaceae). It is soluble in most fixed oils, in propylene glycol, and in mineral oil, sometimes with haziness. It is insoluble in glycerin. 

Infrared Spectra / Sandalwood Oil, East Indian Type / 809... 

SYNS ARHEOL EAST INDIAN SANDALWOOD OIL FEMA No. 3006 OILS, SANDALWOOD OIL OF SANTAL SANTAL OIL a-SANTALOL (FCC)... 

An extensive examination of the minor components of East Indian sandalwood oil has revealed as one component (177), ° which is also synthesized from teresantalic acid by oxidative decarboxylation and cyclopropylmethylhomoallylic rearrangement. 

Two additional minor components of East Indian sandalwood oil have been identified as trans-fi-santalol (111) (cf. Vol 11, ref. 48) and e/n-cw-p-santalol (112).71 New syntheses in this area include those of cw-p-santalol (113) (Scheme 9),72... 

C12 hydrocarbon (271)135 by a similar route but this compound is not identical to a tricyclic hydrocarbon isolated from East Indian sandalwood oil and reported to have this structure. (+)-Copacamphor (272) and (+)-copaborneol (273) have been isolated from Espeltiopsis guacharaca.136 The interesting sinularene derivative (274) and the acetoxycyclosinularane (275) have been isolated from the marine source, Clavularia inflata.137 These compounds, together with an aromadendrane derivative (see p. 181) are the first sesquiterpenoids from Octocorallia of the order Stolonifera. 

Heissler, D., and Riehl, J.-J., Synthesis with benzenesulfenyl chloride. On the structure of a ( 12IIis hydrocarbon from East Indian sandalwood oil. Tetrahedron Lett., 21, 4711, 1980. 

East Indian sandalwood oils are used extensively in perfumery as very valuable, stable fixatives. 

Oil of Santal. Sandalwood oil arheol East Indian sandalwood oil. Volarile oil from dried heart wood of Sonfci-lum album L, Santalaceae, Constit. At least 90% total alcohols calculated as santalo], about 2-4% santalol as esters. 

Pale yellow somewhat viscid liquid characteristic sandalwood odor and taste. dg 0.965-0 980. aas —15 to —20 . njj 1.500-1 510. Very slightly sol in warer sol in 5 vols 70% alcohol. Keep well closed, cool and protected from light, Note West Indian sandalwood oil is derived from Amyris balsamifera and is not official. Its rotation is +24 to +29 . ll is less sol in 70% a]c than the East Indian, therap CAT Urinary anti-infective. 

Diels-Alder reaction of l,l-dimethylcyclopenta-2,4-diene and 2-acetoxy-acrylic acid ester gives two esters (290), which can be converted by conventional reductive steps into the two a-fenchene hydrates (291) and (292). Cyclopen-tadiene and ethyl but-2-ynoate also undergo a Diels-Alder reaction, this time to a norbornadiene ester (293), which was the start of a synthesis of a Cu aldehyde (294) found in East Indian sandalwood oil. ... 

The two a-santalene derivatives (79) and (80) are constituents of the aerial parts of Ayapana amygdalina. (+)-Epi-c/5-/S-santalol (81) has been identified as a new minor component of East Indian sandalwood oil. Treatment of (+)-a-santalyl acetate (82) with hydrogen chloride followed by dehydrOchlorination with basic alumina produces a mixture of /3-santalyl acetate (83) and the acetate of (81). Last year Christenson and Willis reported the acid-catalysed rearrange-... 

OCN East Indian sandalwood white saunders yellow sandalwood yellow saunders... 

Occurrence Tricyclene in juniper oil (Juniperus communis, Cupressaceae) and in the essential oil of the fir Abies balsamea (Pinaceae) ca. 1.3%. Teresantalol, ter-santalal, and teresantalic acid are isolated from East Indian sandalwood oil. sandalwood oil (Santalum album, Santalaceae). 

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