Rocket propellants liquid oxygen

Although modern chemistry allows development of even more effective rocket propellants, energy efficiency is not the only consideration factor. For example, fluorine and its derivatives arc better oxidizers than oxygen, but their extreme toxicity make them environmentally dangerous. The same concerns prevent the use of beryllium hydride—an excellent fuel that combines high density with the energy efficiency comparable to liquid hydrogen. 

The design of propellants for solid fuel rockets differs considerably from that for ordnance, because of the lower operating pressures, usually below 15 MPa. To understand the principles involved it is first necessary to give a brief account of rocket propulsion. In this account considerations will be restricted to motors based on solid propellants. Motors based on liquid fuels, such as petroleum fractions and liquid oxygen, depend on combustion processes of non-explosive type. 

See Dichlorine oxide Dicyanogen Fluorine Halogens Oxygen (Liquid) Liquefied gases Ozone Dicyanogen ROCKET PROPELLANTS... 

Hybrid Rocket Propellants. A special proplnt combination of unlike materials, particularly of unlike physical characteristics. Typical hybrid proplnt combinations are a solid fuel (or oxidizer) in combination with a liquid oxidizer (or fuel) in tjiat order. Sometimes a grain of solid fuel is encased in the combustion chamber of a rocket engine and burned in combination with liq oxygen. Similarly, a liq fuel may be injected into a combustion chamber in contact with a solid oxidizer. Another example is the use of concentrated hydrogen peroxide and a hydrocarbon fuel. In this case, the hydrogen peroxide is converted by decompn into a hot gas contg oxygen. The fuel is injected downstream of the first reaction, mixed with the hot oxidizer-rich gas, and burns (Ref 1)... 

Stettbacher (Rifs 3 5), who obtd information from Amer journal Engineering of Aug 30, 1946 stated that Ger WWII 320-kg rocket was propelled by mixture of alcohol 32-4 parts by wt and liquid oxygen 67.6ps. 

Aliphatic hydrocarbons petrol, paraffin. In the U.S.A. several types of combustibles for liquid propellant jet aircraft are used. One of them, i.e. JP-4, is employed for rocket propulsion, with nitric acid as an oxidizing agent (it can also be used with hydrogen peroxide or liquid oxygen). The specification of JP-4, is as follows ... 

Liquid rocket propellants are subdivided into monopropellants and bipropellants. Monopropellants are liquids which burn in the absence of external oxygen. They have comparatively low energy and specific impulse and are used in small missiles which require low thrust. Hydrazine is currently the most widely used monopropellant however, hydrogen peroxide, ethylene oxide, isopropyl nitrate and nitromethane have all been considered or used as monopropellants. Information on the performance of some monopropellants is presented in Table 8.3. 

S.Gordon A.R.Glueck, "Theoretical Performance of Liquid Amnonia with Liquid Oxygen as a Rocket Propellant, NACA Report RME58A21(May 1958)(Conf)(Not used as a source of info) 86)P.H,Groggins, edit,... 

Effect of hydrocarbon enthalpy of formation and hydrogen to carbon ratio on performance with liquid oxygen as rocket propellants (sea level specific impulse, Pc = 1000 psia, equilibrium expansion, mixture ratio of maximum specific impulse). 

Carbon Ratio on Performance with Liquid Oxygen as Rocket Propellants (Sea Level Specific Impulse, Pc = 1000 psia, Equilibrium Expansion, Mixture Ratio of Maximum Specific Impulse.)... 

The propulsion assembly of a rocket or -> Missile. The driving force can be produced by burning liquid fuels in liquid oxidizers (liquid oxygen, nitric acid, or other oxidants such as liquid fluorine), by burning of solid propellants (-> Solid Propellant Rockets), by burning solid fuels in liquid oxidizers (-> Hybrids), or by catalytic decomposition of endothermal compounds (-> Hydrazine-, - Aerozim, - Aurol). 

For liquid rocket propellants, there is a difference between mono and bipropellants. Monopropellants are endothermic liquids (e.g. hydrazine), which decompose exothermically - mainly catalytically (e.g. Shell-405 Ir/Al203) - in the absence of oxygen ... 

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