Riser density

Fig. 7. Axial density profiles in the (—) bubbling, (------) turbulent, and (----) fast and ( ) riser circulating fluidization regimes. Typical gas velocities for...

Fresh butane mixed with recycled gas encounters freshly oxidized catalyst at the bottom of the transport-bed reactor and is oxidized to maleic anhydride and CO during its passage up the reactor. Catalyst densities (80 160 kg/m ) in the transport-bed reactor are substantially lower than the catalyst density in a typical fluidized-bed reactor (480 640 kg/m ) (109). The gas flow pattern in the riser is nearly plug flow which avoids the negative effect of backmixing on reaction selectivity. Reduced catalyst is separated from the reaction products by cyclones and is further stripped of products and reactants in a separate stripping vessel. The reduced catalyst is reoxidized in a separate fluidized-bed oxidizer where the exothermic heat of reaction is removed by steam cods. The rate of reoxidation of the VPO catalyst is slower than the rate of oxidation of butane, and consequently residence times are longer in the oxidizer than in the transport-bed reactor. 

Radial density gradients in FCC and other large-diameter pneumatic transfer risers reflect gas—soHd maldistributions and reduce product yields. Cold-flow units are used to measure the transverse catalyst profiles as functions of gas velocity, catalyst flux, and inlet design. Impacts of measured flow distributions have been evaluated using a simple four lump kinetic model and assuming dispersed catalyst clusters where all the reactions are assumed to occur coupled with a continuous gas phase. A 3 wt % conversion advantage is determined for injection feed around the riser circumference as compared with an axial injection design (28). 

In energy extraction, titanium alloys are being used in deep-water hydrocarbon and geothermal weUs for risers. Corrosion resistance, high strength, low modulus (flexible), and low density can result in risers one-fourth the weight and three times the flexibiHty of steel. 

High pressure in the riser could also be due to insufficient fluidization gas in the base of the riser. Fluffing gas will vary the catalyst density more fluffing gas lowers the density in the system and the backpressure on the slide valve. 

A conventional FCC unit can be an olefin machine with proper operating conditions and hardware. Catalysts with a low unit cell size and a high silica/alumina ratio favor olefins. Additionally, the addition of ZSM-5, with its lower acid site density and very high framework silica-alumina ratio, converts gasoline into olefins. A high reactor temperature and elimination of the post-riser residence time will also produce more olefins. Mechanical modification of the FCC riser for millisecond cracking has shown potential for maximizing olefin yield. 

In an airlift fermenter, mixing is accomplished without any mechanical agitation. An airlift fermenter is used for tissue culture, because the tissues are shear sensitive and normal mixing is not possible. With the airlift, because the shear levels are significantly lower than in stirred vessels, it is suitable for tissue culture. The gas is sparged only up to the part of the vessel cross section called the riser. Gas is held up, fluid density decreases causing liquid in the riser to move upwards and the bubble-free liquid to circulate through the down-comer. The liquid circulates in airlift reactors as a result of the density difference between riser and down-comer. 

For the sake of developing commercial reactors with high performance for direct synthesis of DME process, a novel circulating slurry bed reactor was developed. The reactor consists of a riser, down-comer, gas-liquid separator, gas distributor and specially designed internals for mass transfer and heat removal intensification [3], Due to density difference between the riser and down-comer, the slurry phase is eirculated in the reactor. A fairly good flow structure can be obtained and the heat and mass transfer can be intensified even at a relatively low superficial gas velocity. 

Fig.2 and Fig.3 show the typical liquid velocity and gas hold up distribution in the ALR. From the figures, one notices that the cyclohexane circulates in the ALR under the density difference between the riser and the downcomer. An apparent large vortex appears near the air sparger when the circulating liquid flows fi om the downcomer to the riser at the bottom. In the riser, liquid velocity near the draft-tube is much larger than that near the reactor wall, the latter moved somewhat downward. The gas holdup is nonuniform in the reactor, most gas exists in the riser while only a little appears in the dowmcomer. 

In the Fig.4, it can be seen that the gas hold-up in both riser and downcomer decreases with increasing the draft-tube horn-mouth diameter and approaches the maximum when the draft-tube hom-mouth diameter is 1.05m. However, due to the gas hold-up decreases more in the downcomer, the gas hold-up difference between the downcomer and the riser increases. Therefore, the apparent density difference between the riser and the downcomer enhances, causing higher liquid superficial velocity in the downcomer and in the riser With increasing the hom-mouth diameter. Fig.5 also shows that the existence of hom-mouth promotes the ability to separate gas from liquid and decreases the amount of gas entrained into the downcomer. 

Figure 25. The effect of pressure on radial density distribution in a riser.

The air-lift consists of two pipes, intercoimected at top and bottom. In one of the pipes (the riser) air is sparged at the bottom. The air rises and escapes at the top. Therefore, nnder most circnmstances there is no air present in the other pipe (the downcomer). The density difference between riser and downcomer canses an intensive liquid circulation. Two designs can be used, i.e., the internal (Figure 11.8A) and the external loop reactor (Figure 11.8B). 

The purpose of a tray is to mix vapor and liquid. This produces aerated liquid—or foam. The purpose of a reboiler is to produce vapor. In a circulating reboiler, the reboiler effluent flows up the riser as a froth. Of course, the flow from the bottom of the tower is going to be a clear liquid. Foam cannot be pumped. But there will always be some ratio of foam to clear liquid in the bottom of the tower, and we have no method of determining this ratio, or even the density of the foam. 

The boiler shown in Fig. 15.2 relies on natural circulation. The density difference between the water plus steam in the downflow pipes and the riser pipes causes the water to circulate through the pipes. A typi-... 

The local gas holdup and bubble behavior were measured by a reflective optic fiber probe developed by Wang and co-workers [21,22]. It can be known whether the probe is im-merging in the gas. The rate of the time that probe immerg-ing in the gas and the total sample time is gas holdup. Gas velocity can be got by the time difference that one bubble touch two probes and the distance between two probes. Chord length can be obtained from one bubble velocity and the time that the probe stays in the bubble. Bubble size distribution is got from the probability density of the chord length based on some numerical method. The local liquid velocity in the riser was measured by a backward scattering LDA system (system 9100-8, model TSI). Details have been given by Lin et al. [23]. 

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