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Ring hydrogenation, partial

Reductive alkylations and aminations requite pressure-rated reaction vessels and hiUy contained and blanketed support equipment. Nitrile hydrogenations are similar in thein requirements. Arylamine hydrogenations have historically required very high pressure vessel materials of constmction. A nominal breakpoint of 8 MPa (- 1200 psi) requites yet heavier wall constmction and correspondingly more expensive hydrogen pressurization. Heat transfer must be adequate, for the heat of reaction in arylamine ring reduction is - 50 kJ/mol (12 kcal/mol) (59). Solvents employed to maintain catalyst activity and improve heat-transfer efficiency reduce effective hydrogen partial pressures and requite fractionation from product and recycle to prove cost-effective. [Pg.211]

It will be clear from the results so far presented that both C5 and C dehydrocyclization products can be formed, with aromatization proceeding (one would expect) by further dehydrogenation of the initially formed C6 ring-closure species. There is another pathway for the production of aromatics based upon cyclization of a linear triene (133), but this is of relatively small importance, and is only significant at all at quite high temperatures and low hydrogen partial pressures. [Pg.52]

Stereoselective reduction of some triazolodiazines (derivatives of ring systems 33 and 37) bearing chiral terpene residues has been elaborated by Groselj el al. <2006TA79>. With catalytic hydrogenation, partial saturation of the six-membered ring was experienced, while reaction with borane-methyl sulfide resulted in formation of triazole-boron complexes. [Pg.755]

In chlorophyll iron as complex-forming metal is replaced by magnesium (Willstatter). The structure of chlorophyll differs from that of haemin as follows. In chlorophyll one propionic acid chain (a) in oxidised form has condensed with a methine carbon atom to form a cyclopentane ring which takes the position at (c) of the vinyl ethyl. Further the two carbonyl groups are esterified and one of the four pyrrole rings is partially hydrogenated... [Pg.410]

Acetylenic aromatic acids having the triple bond Hanked by carboxyl and an aromatic ring were partially reduced to olefinic aromatic acids by chromous sulfate in aqueous dimethylformamide at room temperature in high yields. Phenylpropiolic acid afforded irani -cinnamic acid in 91% yield [195]. Its sodium salt in aqueous solution gave on catalytic hydrogenation over colloidal platinum at room temperature and atmospheric pressure 80% yield of cis-cinnamic acid if the reaction was stopped after absorption of 1 mol of hydrogen. Otherwise phenylpropanoic acid was obtained in 75-80% yield [992]. [Pg.141]

As described in Section IV.B, dibenzothiophenes, when substituted in positions adjacent to the sulfur atom, have reduced activity for direct sulfur extraction. As a result, catalysts that promote aromatic ring hydrogenation offer another route to desulfurization, as the partially hydrogenated ring presents much less steric restrictions to adsorption via r -S type bonding (17,21) or to oxidative addition to form a metallathiabenzene intermediate, as discussed in Section IV.E.3. In addition, the metal-S coordination bond strength is increased by increasing the electron density on sulfur, and the C-S bonds in hydrothiophenes are much weaker. [Pg.457]

Electrocyclization is an efficient reaction that has been employed in creating new photochromic systems (see also Ref. 3). The main challenge in the field is to prepare colorless and colored forms having almost equal energy content. 1,5-Electrocyclization of the colored betaine to the colorless cyclic structure can be controlled by the substitution pattern of the molecules. Tailor-made molecules with appropriate properties can thus be prepared. This basic concept has been extended from monoaza- (DHI), to diaza-(DHPP) and finally to triaza-5-ring heterocycles. Partially hydrogenated systems are possible as well. [Pg.263]


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Partial hydrogenation

Ring hydrogenation

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