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Reorganization

Within this framework, by considering the physical situation of the electrode double layer, the free energy of activation of an electron transfer reaction can be identified with the reorganization energy of the solvation sheath around the ion. This idea will be carried through in detail for the simple case of the strongly solvated... [Pg.604]

Hammer B and Norskov J K 1997 Adsorbate reorganization at steps NO on Pd(211) Phys. Rev. Lett. 79 4441 Hammer B, Scheffler M, Jacobsen K W and Norskov J K 1994 Multidimensional potential energy surface for H2 dissociation over Cu(111) Phys. Rev. Lett. 73 1400... [Pg.2235]

Imahori H, Hagiwara K, Akiyama T, Aoki M, Taniguchi S, Okada T, Shirakawa M and Sakata Y 1996 The small reorganization energy of Cgg in electron transfer Chem. Phys. Lett. 263 545-50... [Pg.2435]

Here X is tire reorganization energy associated witli the curvature of tire reactant and product free energy wells and tlieir displacement witli respect to one another. Assuming a stmctureless polarizable medium, Marcus computed the solvent or outer-sphere component of tire reorganization energy to be... [Pg.2975]

The explorative analysis of data sets by visual data mining applications takes place in a three-step process During the first step (overview), the user can obtain an overview of the data and maybe can identify some basic relationships between specific data points. In the second step (filtering), dynamic and interactive navigation, selection, and query tools will be used to reorganize and filter the data set. Each interaction by the user will lead to an immediate update of the data scene and will reveal the hidden patterns and relationships. Finally, the patterns or data points can be analyzed in detail with specific detail tools. [Pg.476]

The transition state for the first step of the Claisen rearrangement bears much m common with the transition state for the Diels-Alder cycloaddition Both involve a con certed six electron reorganization... [Pg.1012]

Section 24 13 On being heated allyl aryl ethers undergo a Claisen rearrangement to form o allylphenols A cyclohexadienone formed by a concerted six tt electron reorganization is an intermediate... [Pg.1018]

Electron reorganization. The orbitals in are not quite the same as in M because there... [Pg.296]


See other pages where Reorganization is mentioned: [Pg.46]    [Pg.605]    [Pg.894]    [Pg.1249]    [Pg.1855]    [Pg.1889]    [Pg.1978]    [Pg.2421]    [Pg.2421]    [Pg.2422]    [Pg.2498]    [Pg.2976]    [Pg.2981]    [Pg.2984]    [Pg.2984]    [Pg.2986]    [Pg.2988]    [Pg.478]    [Pg.134]    [Pg.150]    [Pg.223]    [Pg.199]    [Pg.1011]    [Pg.134]    [Pg.1284]    [Pg.218]    [Pg.296]    [Pg.175]    [Pg.176]    [Pg.209]    [Pg.237]    [Pg.432]    [Pg.434]    [Pg.130]    [Pg.308]    [Pg.538]    [Pg.225]    [Pg.338]    [Pg.390]    [Pg.390]    [Pg.299]    [Pg.92]   
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A general expression for the dielectric reorganization energy

Actin reorganization

Charge recombination reorganization

Charge recombination reorganization energies

Chemical concepts reorganization

Climate system reorganization

Density functional theory reorganization energy

Determination of the Reorganization Energy

Diabatic solvent reorganization energy

Dissociation reorganization dynamics

Donor acceptor solvent reorganization energy

Dynamics solvent reorganization

Effective reorganization energy

Electron inner coordination shell reorganization

Electron reorganization

Electron self-exchange, reorganization energy

Electron transfer processes reorganization energy

Electron transfer solvent reorganization

Electron transfer, activation control reorganization energy

Electronic reorganization

Electronic reorganization errors

Energy Reorganization Act

Energy bond reorganization

Energy of reorganization

Enynes skeletal reorganization

Experimental reorganization

Frank-Condon reorganization energy

Free energy of reorganization

Free radicals reorganization energy

Frequency reorganization, solvent

Hole mobility reorganization energy

Hydration spheres, reorganization

INTRINSIC BARRIER REORGANIZATION ENERGY

Inner reorganization

Inner reorganization energies

Inner-sphere reorganization, Marcus

Inner-sphere reorganization, Marcus theory

Internal reorganization energy

Intramolecular charge reorganization

Intramolecular reorganization

Intrinsic reorganization factor

Ionization potentials reorganization energy

Ligand The Outer-Shell Reorganization Energy

Ligand reorganization

Local cells reorganization

Marcus kinetic theory reorganization energy

Marcus reorganization energy

Marcus theory nuclear reorganization

Marcus theory solvent reorganization

Media reorganization

Memory reorganization

Molecular reorganization processes

Monoxide-Induced Reorganizations of Metal Atoms

Morphological reorganization

Nuclear reorganization

Nuclear reorganization free energy

Nuclear reorganization parameter

Organolithium compounds reorganization dynamics

Ousters and Reorganizations

Pentacene reorganization energy

Photoinduced electron transfer reorganization energy

Photosynthetic reaction centers reorganization energies

Process reorganization

Protein reorganization energy and

Quantum Reorganization energy

Quinone diacetals Reorganization energy

Reorganization Energies of Optical Electron Transfer Processes

Reorganization Energies of Optical Electron Transfer Processes R. D. Cannon

Reorganization Energy (X)

Reorganization Reactions of Olefins

Reorganization barrier

Reorganization during

Reorganization dynamics

Reorganization dynamics dissociative

Reorganization dynamics first order

Reorganization effect

Reorganization energy

Reorganization energy Marcus approximation

Reorganization energy calculated

Reorganization energy cofactors

Reorganization energy correlation with rates

Reorganization energy defined

Reorganization energy definition

Reorganization energy dynamical proposals

Reorganization energy electron-transfer oxidation

Reorganization energy inner shell

Reorganization energy inner-sphere

Reorganization energy intramolecular

Reorganization energy of optical electron

Reorganization energy of the medium

Reorganization energy outer shell

Reorganization energy outer-sphere

Reorganization energy protein

Reorganization energy solvent

Reorganization energy solvent effects

Reorganization energy vibrations

Reorganization energy, electron transfer

Reorganization energy, electron-transfer Fermi Golden Rule

Reorganization energy, of a solvent

Reorganization enthalpy

Reorganization external

Reorganization free energy

Reorganization inertial

Reorganization inner-shell

Reorganization inner-sphere

Reorganization internal

Reorganization of hydrogen bonds

Reorganization of solvents

Reorganization of surfaces

Reorganization of the solvent molecules

Reorganization outer-shell

Reorganization outer-sphere

Reorganization parameter

Reorganization self-exchange

Reorganization total

Reorganization, during melting

Reorganization, of electrons

Reorganizations number

Reorganizing Traditional Financial Statements

Reorganizing your work

Reorganizing your work an example

Ring transformations reorganization

Roseophilin synthesis skeletal reorganization

Side chain reorganization

Skeletal reorganization reaction

Skeletal reorganizations

Solvent effects, reaction coordinates, and reorganization energies

Solvent effects, reaction coordinates, and reorganization energies on nucleophilic substitution

Solvent effects, reaction coordinates, and reorganization energies on nucleophilic substitution reactions in aqueous solution

Solvent reorganization

Solvent reorganization energy in ET

Solvent reorganization energy, Born

Solvent reorganization energy, electron

Solvent reorganization energy, electron transfer reactions

Solvent reorganization model

Solvent reorganization nucleophilic addition

Solvent reorganization reactions

Solvent reorganization solvolysis

Structural Reorganization in Degenerate Reactions

Structural reorganizations

Surface reorganization

Tautomerizations Requiring Reorganization of the Environment

Tautomerizations requiring reorganization

Tautomerizations requiring reorganization environment

Tautomerizations without Requiring Reorganization of the Environment

The Inner-Shell Reorganization Energy Exchange Rates of Aquo Ions

The Reorganization Energy

The energy of reorganization

The nuclear reorganization

Thermodynamics binding site reorganization

Total reorganization energy

Vibrational reorganization energy

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