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Organolithium compounds reorganization dynamics

We have shown how organolithium compounds adopt a variety of structures which differ in state of aggregation and degree of solvation. These species interconvert rapidly at equilibrium by different mechanisms, such as intermolecular C—Li exchange ligand transfer and dissociation-recombination processes as well as first-order reorganizations such as inversion and rotation. Dynamics of many of these processes have been determined by our methods of NMR line shape analysis. [Pg.59]

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Dynamics organolithium compounds

Organolithium compounds

Reorganization

Reorganization dynamics

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