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Reflection caustic

The spectacular success (in 1807) of Humphry Davy, then aged 29 y, in isolating metallic potassium by electrolysis of molten caustic potash (KOH) is too well known to need repeating in detail." Globules of molten sodium were similarly prepared by him a few days later from molten caustic soda. Earlier experiments with aqueous solutions had been unsuccessful because of the great reactivity of these new elements. The names chosen by Davy reflect the sources of the elements. [Pg.68]

Industries producing chlorine, sodium hydroxide (also known as caustic soda), sodium carbonate (or soda ash) and its derivatives and compounds based on calcium oxide (or lime) are usually included under this category. As both sodium hydroxide and chlorine have a common raw material, sodium chloride, they are produced in quantities that reflect their equal molar ratio, irrespective of the market for either product. Since they are produced by electrolysis, they require a cheap source of brine and electricity... [Pg.220]

The most consistent outlet for chlorine will continue to be vinyl chloride, and future growth is tied to its fortunes. With its wide variety of uses, caustic soda demand generally reflects the health of the entire U.S. economy. The unpredictable financial returns attributable to the co-products will make it very difficult for producers to manage the large capital outlays required as aging diaphragm plants are replaced by membrane facilities. [Pg.1208]

Although compounds of sodium and potassium were known in ancient times, it was not until Humphrey Davy s famous electrolytic experiments in 1807 on molten caustic soda and potash that the metals themselves were first isolated. Lithium was first recognized as an alkali metal in various silicate and mica minerals in 1817 (by ArfVedson, who thus named it from the Greek word for stone) and first isolated, again by Davy, in 1818. The discovery of cesium (1860) and rubidium (1861) had to await the development of atomic spectroscopy (by Bunsen and Kirchoff) their names reflect the colors of their dominant spectral lines (Latin caesius, sky blue, and rubidus, deep-red). [Pg.60]

In calculating the amount of caustic required for caustic neutralization, the oil is titrated to a phenolphthalein end point. This titration endpoint includes not only the FFA, but also the oryzanol compounds. With the higher caustic addition, the ory-zanol is transferred to the soapstock away from the oil. The nutritional benefit of these compounds is lost. An alternative indicator for titration uses alkali blue (8). This indicator reflects the acidity contributed only by the free fatty acids. [Pg.1116]

As well as the most common form of stain, namely that caused by deposits of foreign substances, there are two further kinds. One occurs owing to localized effects of chemicals which modify the fibres in such a way that they reflect light or take up dye differently, for example splashes of caustic soda on cellulose. For the... [Pg.222]

Creep behavior of the sodium type membrane is given in Figure 10, where deformation is seen to be highly dependent upon caustic concentration. Such a phenomenon also reflects the effect of water content of the membrane. [Pg.432]

Figure 18 shows the influence of caustic concentration upon conductivity of the membrane. The decrease of conductivity with the increase in caustic concentration is ascribed to the decrease in mobility of sodium ions caused by the dehydration of the membrane. The increase of apparent activation energy for ionic conductance along with caustic concentration as is given in Table IE reflects the existance of increasing interaction between sodium ion and the fixed ion in the membrane. [Pg.439]

If a given system of rays be incident upon a bright curve, the envelope of the reflected rays is called a caustic by reflection. [Pg.183]

There can be other phenomena that reflect the crisis in classical mechanics. In Section IV.D, we showed that the folding patterns show the number of degrees of freedom involved in chaos. These patterns correspond, in quantum mechanics, to caustics. Therefore, the crisis would show up in the transition of the types of caustics. Thus, the difference between twofold and... [Pg.180]

Since markets do not consider the laws of stoichiometry, the electrolytic chlor-alkali industry is in a state of perpetual imbalance. Nearly always, either chlorine or caustic soda is in long supply, while there is a shortage of the other. This situation is reflected in spot market prices, which can fluctuate wildly over short periods, usually in opposite directions for the two products. The combined price of an ecu is less volatile, and ecu customers who take nearly equivalent amounts of chlorine and caustic soda are a stabilizing influence in the industry. KOH, as a relatively minor product, is somewhat immune to these problems. Total KOH production is free to respond to market pressures the amount of chlorine produced along with KOH is a small part of the total and not a large factor in the market. The KOH producer who is also a chlorine merchant, however, is still subject to the fluctuating market prices of chlorine. [Pg.47]


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See also in sourсe #XX -- [ Pg.151 ]




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