Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Reduced space

Certain devices may be obtained which are factory-sealed —that is, interconnecting wiring is sealed by the manufacturer where it enters/exits enclosures. These devices do not require an additional (external) seal, and often can be utilized to advantage in lessening installation time and reducing space requirements (for an external seal). [Pg.540]

According to relation (17), the p SRH matrix is a sum of terms and each term is the product of the energy and the RDM corresponding to an eigen-state of the system. Therefore for p > 2 the - SRH matrix has all the relevant information about the eigen-states of our system and is represented in a reduced space which renders it easy to handle. [Pg.59]

A first introduction to principal components analysis (PCA) has been given in Chapter 17. Here, we present the method from a more general point of view, which encompasses several variants of PCA. Basically, all these variants have in common that they produce linear combinations of the original columns in a measurement table. These linear combinations represent a kind of abstract measurements or factors that are better descriptors for structure or pattern in the data than the original measurements [1]. The former are also referred to as latent variables [2], while the latter are called manifest variables. Often one finds that a few of these abstract measurements account for a large proportion of the variation in the data. In that case one can study structure and pattern in a reduced space which is possibly two- or three-dimensional. [Pg.88]

The reconstruction Z of the transformed contingency table Z in a reduced space of latent vectors follows from ... [Pg.192]

Equation 3.2 was proposed by Roach (1968) almost 40 years ago to model the overlap of coal particulates sampled from air onto a flat surface. The equation was verified by studying the clustering of randomly distributed circles in a square representing the reduced space of a 2D separation (Oros and Davis, 1992). It then was modified (Rowe and Davis, 1995) to study the clustering of inhomogeneous random distributions of circles (Rowe et al., 1995 Davis, 2004), in which more circles are found in parts of the reduced square than in others, and to address the clustering of ellipses and reduction of clustering that occurs near the reduced-square boundaries (Davis, 2005). For simplicity, only Equation 3.2 is used in this chapter. [Pg.39]

SNOPT Reduced space SQP, active set Line search Quasi-Newton... [Pg.65]

However, the most significant development in recent years has been represented by the trend towards smaller facilities based on smaller accelerators. The work done at ETH in Zurich on the study of stripping yields, molecular dissociation and detection efficiency at low energies has led to the development of systems based on low voltage tandem machines they have demonstrated that 14C measurement is also possible using 500 kV or even 200 kV accelerators.[61,62] The main advantage in the use of dedicated 14C smaller accelerators is the reduced space requirements [63] for example, while the 3 MV VERA facility covers an area of 192 m2, the compact 500 kV AMS system at the Poznan Radiocarbon Laboratory in Poland covers an area of 30 m2 and the 200 kV MICADAS system in Zurich only about 7 m2. [Pg.473]

Use of the reduced space SQP mentioned in Section 15.1 has facilitated the implementation of simultaneous modular optimization. The modeling equations representing the individual modules are not explicitly made part of the optimization problem. Instead, the equations are solved by taking successive steps using Newton s... [Pg.543]

However, by increasing temperature or reducing space velocity, methyl formate can be decomposed to further yield H2 and CO 12... [Pg.106]

Reduced gradient method. This technique is based on the resolution of a sequence of optimization subproblems for a reduced space of variables. The process constraints are used to solve a set of variables (zd), called basic or dependent, in terms of the others, which are known as nonbasic or independent (zi). Using this categorization of variables, problem (5.3) is transformed into another one of fewer dimensions ... [Pg.104]

Figure 4.16 Phase diagram of poly(isoprene-Z>-2-vinylpyridine) with octyl gallate, indicating the transition between different morphologies with octyl gallate content and temperature (D, disordered S, spherical H, hexagonal L, lamellar L2, lamellar with reduced spacing I, intermediate state). Reprinted ftomBondzic et al. (2004). Copyright2004 American Chemical Society. Figure 4.16 Phase diagram of poly(isoprene-Z>-2-vinylpyridine) with octyl gallate, indicating the transition between different morphologies with octyl gallate content and temperature (D, disordered S, spherical H, hexagonal L, lamellar L2, lamellar with reduced spacing I, intermediate state). Reprinted ftomBondzic et al. (2004). Copyright2004 American Chemical Society.
The space velocity is generally chosen to give conversions of 85 to 95% of the olefins charged. Higher conversions are possible, but uneconomical, as more catalyst is required and catalyst life is reduced. Space velocities, based on total feed, may range from about 0.3 to 0.5 gallon per hour per pound of catalyst or 4.5 to 7.0 cubic feet per hour per pound of catalyst, depending on olefin content of feed and other process variables. [Pg.93]

The methods given are presented in Table II exactly as they were reported by the laboratories (as nearly as possible). The detail in which methods are reported varies from elaborate to scanty. No literature references were given by any laboratory. In one case (laboratory 02) results came back on a form marked report of chemical analysis, and we had to go back to the questionnaire to find that wet chemistry was the method used. Abbreviations are used to reduce space in the method column. [Pg.160]

VII. Reduced Space Analyses of the Control of Quantum Dynamics... [Pg.213]

Vn. REDUCED SPACE ANALYSES OF THE CONTROL OF QUANTUM DYNAMICS... [Pg.253]

In this chapter Prof. Rice has advocated two techniques that should be useful for evaluations of optimal fields for laser control of chemical reactions (i) reduced space of eigenstates for representations of nuclear wavepackets and (ii) the use of effective reaction coordinates. Both techniques have already been used for efficient evaluations of reaction probabilities in model reactions. See, for example, Ref. 1 for the prediction of population inversion and Ref. 2 for the demonstration of rather strong deviations of chemical reactions from the reaction path, specifically in the case of hydrogen transfer reactions. [Pg.281]

This coordinated use of power supplies will assist in reducing space, weight and plot area. [Pg.32]

Arrays can be divided into three groups depending on their design (Fig. 32.2). In the first design, each electrode is independently addressed (Fig. 32.2a). This type of array allows several practical applications. On one hand, these devices can be fabricated for obtaining the same information at different sites of a medium. For example, studies about the responses of neuronal cell cultures under different stimulus [85-87]. On the other hand, these devices can be designed to obtain different information at reduced spaces, i.e. multianalyte determination. Those arrays can be employed directly like detectors in flow systems [88] (where each electrode is maintained at a different potential) or they can be individually modified for specific analytes [89],... [Pg.779]

The advantage of the effective Hamiltonian (7), beside the reduced space of nuclear coordinates, is that it involves effective force constants (elements of the matrix K) which rapidly decrease with the distance between centres. This allows for efficient models involving only few force constants. Furthermore, the force constants can be calculated. For this purpose the local nuclear coordinates, at the centre n, are expanded in Cartesian displacements, uKa n ), of surrounding atoms ... [Pg.652]

The proposed approach to static cooperative Jahn-Teller effect is based on the exact effective Hamiltonian (7), acting in the reduced space of active one-centre distortions only. It involves effective force constants, which are analytically related to the parameters of the full microscopic Hamiltonian. Direct electronic interactions between sites, such as orbital-dependent electrostatic and exchange interactions [28], can be added to the effective Hamiltonian without modifying it. This approach proves to be especially efficient in the case of strong Jahn-Teller distortions, when the effects of second-order Jahn-Teller coupling become important. [Pg.665]


See other pages where Reduced space is mentioned: [Pg.15]    [Pg.255]    [Pg.900]    [Pg.288]    [Pg.234]    [Pg.252]    [Pg.170]    [Pg.65]    [Pg.529]    [Pg.358]    [Pg.223]    [Pg.219]    [Pg.98]    [Pg.203]    [Pg.205]    [Pg.205]    [Pg.206]    [Pg.227]    [Pg.274]    [Pg.253]    [Pg.32]    [Pg.255]    [Pg.117]    [Pg.152]    [Pg.229]    [Pg.59]    [Pg.48]   
See also in sourсe #XX -- [ Pg.259 ]




SEARCH



© 2024 chempedia.info