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Silanes reactions with

The ion clusters (Si2H+, Si.sH, ,...) are also present, and larger clusters (positive and neutral) can be formed through reactions with silane molecules. Negative ions have been detected [321], which are thought responsible for the powders in the discharge [322]. [Pg.92]

The introduction of small amounts of boron into precursors that produce silicon nitride have been known to improve the ceramic yields of silicon nitride and Si—B—C—N ceramics as first reported in 1986.110 Several reports have appeared in the past couple of years alone that utilize borazine precursors such as 2,4-diethylb-orazine and other cyclic boron precursors, such as pinacolborane, 1,3-dimethyl-1, 3-diaza-2-boracyclopentane, for their reactions with silanes, polysilazanes, and polysilylcarbodiimides for the high-yield production of Si—B—N—C ceramics.111... [Pg.53]

Tuulmets, A. Nguyen, B. T. Panov, D. Sassian, M. Jarv, J. Kinetics of the Grignard Reaction with Silanes in Diethyl Ether and Ether-Toluene Mixtures. J. Org. Chem. 2003, 68, 9933-9937. [Pg.681]

Acohols - [ALCOHOL FUELS] (Vol 1) - [FEEDSTOCKS-COALCHEMICALS] (Vol 10) - [DISTILLATION, AZEOTROPIC AND EXTRACTIVE] (Vol 8) - [COALCONVERSIONPROCESSES - LIQUEFACTION] (Vol 6) - [FLAME RETARD ANTS - PHOSPHORUS FLAME RETARD ANTS] (Vol 10) - [EXPLOSIVES AND PROPELLANTS - PROPELLANTS] (Vol 10) -as antifreeze [ANTIFREEZES AND DEICING FLUIDES] (Vol 3) -for automotive motor fuel [FUELS, SYNTHETIC - LIQUID FUELS] (Vol 12) -from castor oil [CASTOR OIL] (Vol 5) -in ceramic processing [CERAMICS - CERAMIC PROCESSING] (Vol 5) -from hydrocarbon oxidation [HYDROCARBON OXIDATION] (Vol 13) -as hypnotic and sedative [HYPNOTICS, SEDATIVES, ANTICONVULSANTS, AND ANXIOLYTICS] (Vol 13) -m metal polishes [POLISHES] (Vol 19) -from oxo process [OXO PROCESS] (Vol 17) -permanganate oxidation [MANGANESE COMPOUNDS] (Vol 15) -reactions with silanes [SILICON COMPOUNDS - SILANES] (Vol 22) -role m mineral processing [MINERALS RECOVERY AND PROCESSING] (Vol 16)... [Pg.24]

Using the metalloradical reactivity of the Rh(II)OEP (OEP = 2,3,7,8,12,13,17,18-octaethylphorphynato) dimer, the preparation of silyl rhodium complexes was achieved by the hydrogen elimination reaction with silanes I R SiH (R = R = Et, Ph R = Me, R = Ph, OEt). The Rh—Si bond length of 2.32(1) A, found when R = Et, is comparable to those in other Rh(III) complexes (Table 11). The crystal packing indicates that all the ethyl groups on the porphyrin periphery are directed toward the silyl group. Consequently, the aromatic part of one complex molecule is in contact with the aromatic part of the next molecule and the aliphatic part is in contact with the aliphatic part of the next molecule204. [Pg.2104]

Synthetic application of group-10 complexes in catalytic and stoichiometric reactions with silanes has produced a large number of interesting compounds which have been recently reviewed elsewhere231,250-253. [Pg.2117]

Tilley and coworkers reported a more direct procedure for the synthesis of late transition metal silylenoid complexes by reaction with silanes [equation (7.1)].36,37 Exposing iridium complex 14 to dimesitylsilane afforded iridium silylenoid 15.36 In addition to dimesitylsilane, other silanes could be used, including diphenyl-, diethyl-, or dimethylsilane. Primary silanes such as mesitylsilane and 2,4,6-triisopropylphe-nylsilane were also tolerated as substrates.37... [Pg.185]

Ph3P)CuH]6 did not catalyze reaction of Et2NH with secondary and tertiary silanes.145 This is not surprising in view of the results of Liu and Harrod, who showed that CuCl, or CuH catalysts do not activate the second N—H of primary amines, or the third N—H bond of NH3, toward reaction with silanes.147148... [Pg.391]

Instead of O addition to the substrate, the reaction with silanes R3 SiH results in a clean and net insertion of O into a Si-H bond to give R3SiOH via the computed transition state (67). ... [Pg.4024]

Reaction with silanes 5.8.3.2.5 trans-l2Pt(PEt3)2 Reaction with GeHjX 5.8.4.2.2 12 30 4P2P 2 Pi2l4(PPl3)2... [Pg.622]


See other pages where Silanes reactions with is mentioned: [Pg.24]    [Pg.41]    [Pg.47]    [Pg.167]    [Pg.461]    [Pg.747]    [Pg.753]    [Pg.168]    [Pg.36]    [Pg.225]    [Pg.225]    [Pg.41]    [Pg.47]    [Pg.167]    [Pg.461]    [Pg.747]    [Pg.753]    [Pg.1825]    [Pg.54]    [Pg.129]    [Pg.591]    [Pg.602]    [Pg.615]    [Pg.615]    [Pg.623]    [Pg.623]    [Pg.626]   
See also in sourсe #XX -- [ Pg.535 ]




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Aldehydes reaction with silane carbanions

Aldehydes reaction with silanes

Aldehydes reactions with allylic silanes

Aldehydes, a-methyl reaction with enol silanes

Aldehydes, p-alkoxy reaction with enol silanes

Aminals reaction with enol silanes

Ammonium fluoride, tetrabutylcatalyst enol silane reaction with aldehydes

Atomic reaction with silane

Benzonitrile oxide reaction with silane

Carbonyl compounds reaction with enol silanes

Cobalt, octacarbonylbiscatalyst silane reaction with carbonyl compounds

Cumulative Subject reactions with enol silanes

Dienes reaction with silanes

Electrophiles, reaction with allyl silane

Enol silanes reaction with acetals

Enol silanes reaction with aldehydes

Enol silanes reaction with aldehydes, diastereoselectivity

Enol silanes reaction with aldehydes, stereoselectivity

Enol silanes reaction with chiral a-alkoxy aldehydes

Enol silanes reaction with chiral a-methyl aldehydes

Enol silanes reaction with chiral acetals

Enol silanes reaction with chiral azetinones

Enol silanes reaction with dimethyl acetals

Enol silanes reaction with imines

Enol silanes, nonstereogenic reaction with aldehydes

Enol silanes, nonstereogenic reaction with aldehydes, diastereoselectivity

Enol silanes, stereogenic reaction with aldehydes

Enol silanes, stereogenic reaction with chiral azetinones

Epoxides reaction with allyl silanes

Esters (cont reaction with allylic silanes

Fluoride, tetrabutylammonium reaction with silanes

Fluorides enol silane reaction with aldehydes

Grignard reagents, reactions with silanes

Group reaction with silanes

Imines (cont reactions with unsaturated silanes

Iminium ions reaction with enol silanes

Ketones, reaction with silane carbanions

Nickel sulfide silane reaction with carbonyl compounds

Nitrones reaction with enol silanes

Oxonium ions reaction with enol silanes

Phosphine oxides reactions with silanes

Photochemical Reaction with Silanes

Radical photochemical reaction with silane

Radicals reaction with silanes

Reaction with silane carbanions

Reactions of Silanes with CO

Reactions of Silanes with Transition Metals

Reactions of silanes with

Reactions of with Primary and Secondary Silanes

Reactions with Silane (SiH

Reactions with Silanes and Alkali Aluminiumhydrides

Rhodium, chlorotris catalyst silane reaction with carbonyl compounds

Silane carbanions, reaction with aldehydes Silanes

Silane carbanions, reaction with aldehydes ketones

Silane coupling agents reaction with filler surfaces

Silane reaction with silyl radical

Silane reaction with thiyl radical

Silane, allenylreaction with acetals Friedel-Crafts reaction

Silane, allenylreaction with acetals Mannich reaction

Silane, allenylreaction with acetals reactions

Silane, propargylacylation reaction with acetals

Silane, propargylacylation reaction with aldehydes

Silane, propargylacylation reaction with ketals

Silane, propargylacylation reaction with ketones

Silane, reaction

Silane, triethylionic hydrogenation reaction with unsaturated esters

Silane, vinylepoxidation reaction with acetals

Silane, vinylepoxidation reaction with aldehydes

Silane, vinylepoxidation reaction with carbonyl compounds

Silane, vinylepoxidation reaction with glycine cation equivalents

Silane, vinylepoxidation reaction with ketals

Silane, vinylepoxidation reaction with ketones

Silane, vinylepoxidation reaction with methoxymethyl chloride

Silanes alkenyl, reactions with electrophiles

Silanes allyl, reactions with electrophilic intermediate

Silanes allylic, reaction with electrophiles

Silanes reaction with alcohols

Silanes reaction with alkenes

Silanes reaction with carbonyl compounds

Silanes reaction with epoxides

Silanes reaction with iminium salts

Silanes reaction with metal halides

Silanes reactions

Silanes reactions with electrophiles

Silanes vinyl, reaction with electrophiles

Silanes, allenyl annulations reactions with a,p-unsaturated carbonyl compounds

Silanes, allyl, reaction with

Silanization reaction

Silica compounds silanization reaction with

Silica reaction with silanes

Silicon Reaction of Silanes with Ni, Rh, Pd, Pt

Subject reactions with enol silanes

Transition metal ions, reaction with silane

With silane

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