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Fluorides enol silane reaction with aldehydes

Silyl enol ethers of acyl silanes have been used in Lewis acid-mediated Mukaiyama reactions with acetals. Treatment of the resulting /1-alkoxy acyl silanes with tetrabutylammonium hydroxide or tetrabutylammonium fluoride gave the corresponding a,/J-unsaturated aldehydes (Scheme 99)210. [Pg.1649]

Table 2 Ratio of Diastereoisomers in the Fluoride Ion Catalyzed Reactions of Enol Silanes with Aldehydes... Table 2 Ratio of Diastereoisomers in the Fluoride Ion Catalyzed Reactions of Enol Silanes with Aldehydes...

See other pages where Fluorides enol silane reaction with aldehydes is mentioned: [Pg.642]    [Pg.642]    [Pg.642]    [Pg.132]    [Pg.261]    [Pg.633]    [Pg.634]    [Pg.633]    [Pg.634]    [Pg.119]    [Pg.633]    [Pg.634]    [Pg.410]    [Pg.410]    [Pg.410]   
See also in sourсe #XX -- [ Pg.2 , Pg.633 ]

See also in sourсe #XX -- [ Pg.633 ]

See also in sourсe #XX -- [ Pg.633 ]

See also in sourсe #XX -- [ Pg.2 , Pg.633 ]

See also in sourсe #XX -- [ Pg.633 ]




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Aldehyde enolate

Aldehyde enols

Aldehydes enolates

Aldehydes enolization

Aldehydes reaction with silanes

Aldehydes reactions with enolates

Aldehydes silanes

Ammonium fluoride, tetrabutylcatalyst enol silane reaction with aldehydes

Enol silanes

Enolate reaction with aldehydes

Enols reactions with

Fluorides reaction with

Reactions with silanes

Reactions, with enolates

Silane, reaction

Silanes reactions

Silanization reaction

With fluoride

With silane

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