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Organometallics reaction with

QrganometaUic compounds (R-Metal) are a source of nucleophilic alkyl or aryl groups. This is because the metal is more electropositive than the carbon atom to which it is bonded. [Pg.127]

The nucleophilic alkyl or aryl group adds to the carbonyl to form an alcohol. These reactions are very useful in the synthesis of complex organic molecules because new carbon-carbon bonds are formed. [Pg.128]

Organolithium and Grignard reagents are prepared from alkyl (or aryl) halides. The reactions are carried out under anhydrous conditions because reaction with water leads to the formation of alkanes. [Pg.128]


Pyran-4-one, 2,2-dimethyltetrahydro-reactions, with organometallic reagents, 3, 726 Pyran-4-one, 2,6-diphenyltetrahydro- C NMR, 3, 589... [Pg.766]

Nitriles are similar in some respects to carboxylic acids and are prepared either by SN2 reaction of an alkyl halide with cyanide ion or by dehydration of an amide. Nitriles undergo nucleophilic addition to the polar C=N bond in the same way that carbonyl compounds do. The most important reactions of nitriles are their hydrolysis to carboxylic acids, reduction to primary amines, and reaction with organometallic reagents to yield ketones. [Pg.774]

Intermolecular C-C Bond-forming Reactions with Organometallic Reagents... [Pg.290]

Furthermore reactions with difluorophosphoric anhydride are of some importance (55). The easy cleavage of the P—0—P-bridge in reactions with organometallic oxides (17) and halides (18) leads to derivatives of difluorophosphoric acid in a very mild way ... [Pg.59]

We begin, however, with a brief consideration of a group of phosphorus compounds of significance for their utility in the formation of carbon-phosphorus bonds via reaction with organometallic reagents in displacement reactions. [Pg.111]

Cross-coupling reactions with organometallic reagents... [Pg.4]

While the transmetalation step is often the rate-determining step for Pd-catalyzed reactions with organometallics, the oxidative addition step is often the rate-determining step in the Heck reactions, although olefin insertion can be rate-limiting in some cases — this is why the Heck reactions of tri- and tetra-substituted olefins sometimes proceed slower than those of di-substituted and terminal olefins. [Pg.15]

Coupling reactions with organometallic reagents 3.3.1 Kumada coupling... [Pg.89]


See other pages where Organometallics reaction with is mentioned: [Pg.155]    [Pg.606]    [Pg.853]    [Pg.148]    [Pg.157]    [Pg.294]    [Pg.577]    [Pg.255]    [Pg.186]    [Pg.38]    [Pg.39]    [Pg.65]    [Pg.142]    [Pg.8]    [Pg.42]    [Pg.186]    [Pg.197]    [Pg.270]    [Pg.324]    [Pg.338]    [Pg.355]    [Pg.366]    [Pg.378]    [Pg.315]    [Pg.330]    [Pg.699]   
See also in sourсe #XX -- [ Pg.802 ]

See also in sourсe #XX -- [ Pg.103 ]

See also in sourсe #XX -- [ Pg.103 ]




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1-Naphthy limine reactions with organometallic compounds

1.3- Oxazines, 4,4,6-trimethyl-5,6-dihydromethiodide salt reactions with organometallic compounds

2- Hexenal reaction with organometallic compounds

2-Cyclohexenone reaction with organometallic reagents

2-Oxazolines, 4,4-dimethylmethiodide salt reactions with organometallic compounds

5a-Cholestan-3-one reactions with organometallic reagents

A -Piperidine reactions with organometallic compounds

A-Alkoxyaldimines reaction with allyl organometallic compounds

Acetals reactions with organometallic compounds

Acetophenone reaction with allylic organometallic compounds

Acid anhydrides reactions with organometallic

Acid chlorides reactions with organometallic

Acid halides reactions with organometallic

Acids reaction with organometallic compounds

Aldehydes reaction with organometallics

Aldehydes reactions with allyl organometallics

Aldehydes reactions with chiral allyl organometallics

Aldehydes reactions with organometallic reagents

Aldehydes reactions with type I crotyl organometallics

Aldehydes reactions with type III crotyl organometallics

Aldehydes, a-alkoxy reactions with organometallic compounds

Aldehydes, p-alkoxy reaction with allyl organometallic compounds

Aldimines reaction with allyl organometallics

Aldimines reactions with organometallic compounds

Aldoxime ethers reactions with organometallic compounds

Alkenyl halides coupling reactions with sp3 organometallics

Allenic organometallic compounds reactions with aldimines

Allenic organometallic compounds reactions with imines

Allyl organometallic compounds reactions with 8-phenylmenthylA-methoxyiminoacetate

Allyl organometallic compounds reactions with a-phenylaldimine

Allyl organometallic compounds reactions with aldimines

Allyl organometallic compounds reactions with chiral C=N electrophiles

Allyl organometallic compounds reactions with gem-amino ethers

Allyl organometallic compounds reactions with glyoxylate aldimines

Allyl organometallic compounds reactions with imines

Amides reaction with organometallic

Amines reactions with organometallics

Amino acids reaction of imines with allyl organometallic

Aziridines reaction with organometallics

Butyraldehyde, 3-methoxy a-alkoxyaldimines derived from reaction with allyl organometallic compounds

By Reaction with Other Organometallic Compounds

Carbon dioxide reaction with organometallic

Carbon dioxide reactions with organometallic reagents

Carbon dioxide, reaction with organometallics

Carbonyl compounds acid derivatives reactions with organometallic reagents

Carbonyl compounds reactions with crotyl organometallics

Carbonyl compounds reactions with organometallic reagents

Carbonyl compounds reactions with organometallics

Carbonylative Coupling Reactions with Organometallic Reagents

Carboxylic acid derivatives reactions with organometallic

Carboxylic acid derivatives reactions with organometallic reagents

Carboxylic acids, functional derivatives reactions with organometallic

Chiral reactions with allyl organometallics

Coupling reactions with organometallic

Coupling reactions with organometallic reagents

Cross-coupling reactions with organometallic reagents

Crotyl organometallic compounds reactions with achiral ketones

Crotyl organometallic compounds reactions with aldehydes

Crotyl organometallic compounds reactions with aldimines

Crotyl organometallic compounds reactions with gem-amino ethers

Crotyl organometallic compounds reactions with imines

Crown ethers reactions with organometallic compounds

Cumulative Subject reactions with organometallic compounds

Diborane reaction with organometallic compounds

Electrophilic cyclopropanes reaction with organometallic compound

Ester reactions with organometallic

Ethylamine, cyclohexylsynthesis reaction with allyl organometallic compounds

Ethylamine, phenylaldimines derived from reaction with allyl organometallic compounds

Felkin-Anh addition reaction with allyl organometallic reagents

Fluorine 18 atom reactions with organometallic compounds

Formaldehyde reactions with organometallic

Formaldoxime ethers reactions with organometallic compounds

Gem-Amino ethers, N- reactions with allyl organometallic compounds

Glyoxylates reaction with allyl organometallic compounds

Group reaction with organometallic

Halides coupling reaction with sp3 organometallics

Halides reaction with organometallics

Heptan-2-one reaction with allylic organometallic compounds

Homoallylamines allyl organometallic reagent reactions with imines

Hydrazones reactions with organometallic compounds

Hydroxylamine, V- reaction with allyl organometallic compounds

Hydroxylamines reactions with organometallic compounds

Imidazoles, l-benzyl-2-alkyl-4,5-dihydromethiodide salt reactions with organometallic compounds

Imines reactions with allyl organometallic reagents

Imines reactions with organometallics

Imines, N-trimethylsilylin situ synthesis reactions with organometallic compounds

Iminium ions reaction with allyl organometallic reagents

Iminium salts reactions with organometallic compounds

Iminium salts reactions with propargyl organometallic reagents

Ketone reactions with organometallic reagents

Ketones reactions with organometallic compounds

Ketones reactions with organometallics

Ketones reactions with type 1 crotyl organometallics

Ketones reactions with type I crotyl organometallics

Ketones reactions with type III crotyl organometallics

Ketones, conjugated reaction with organometallics

Lewis acids reactions with organometallic compounds

Main group organometallics reaction with

Metal halides, reaction with organometallic

Metal reaction with organometallic

Nitriles reactions with organometallic

Nitroarenes reaction with organometallic compound

Nitrones reactions with organometallic compounds

Nucleophilic addition reactions organometallic reagents with

O-Phthalaldehyde reaction with organometallic reagents

Olefinic esters reaction with organometallic compounds

Opening reactions with organometallic compounds

Organometallic compounds acetylene, reactions with

Organometallic compounds allene, reactions with

Organometallic compounds carbene, reactions with

Organometallic compounds carbenes, reactions with

Organometallic compounds carbyne, reactions with

Organometallic compounds dithioacetals, reactions with

Organometallic compounds reaction with 1 -alkynyl halides

Organometallic compounds reaction with alkyl halides

Organometallic compounds reactions with aldehydes

Organometallic compounds reactions with aldimines, regiochemistry

Organometallic compounds reactions with amides

Organometallic compounds reactions with cyclic ketones

Organometallic compounds reactions with electrophiles

Organometallic compounds reactions with epoxides

Organometallic compounds reactions with nitriles

Organometallic compounds reactions with selenides

Organometallic compounds thiophene, reactions with

Organometallic compounds, reactions with alkenes

Organometallic compounds, reactions with carbonyls

Organometallic compounds, reactions with imines

Organometallic compounds, reactions with triflates

Organometallic nucleophiles substitution reactions with

Organometallic nucleophiles, reactions with

Organometallic reactions with pressurized gases

Organometallic reagents reaction with nitriles

Organometallic reagents reaction with oxiranes

Organometallic reagents reactions with acid chlorides

Organometallic reagents reactions with carboxylic acid

Organometallic reagents reactions with epoxides

Organometallic reagents reactions with esters

Organometallics reaction with acetyl chloride

Oximes reactions with allyl organometallic compounds

Oximes reactions with organometallic compounds

Oxirane reactions with organometallic compounds

Oxygen reaction with organometallic compounds

Peroxides reaction with organometallic compounds

Propargyl organometallic compounds reactions with gem-amino ethers

Propargyl organometallic compounds reactions with imines

Propionaldehyde, 2- methoxyaldimine derivatives reaction with allyl organometallic compounds

Protonated from substitution reactions with organometallic

Pyran-4-ones reaction with organometallics

Quinoline reaction with organometallics

Quinones reactions with organometallics

Reaction of Organometallic Reagents with Aldehydes and Ketones

Reaction of Organometallic Reagents with Carboxylic Acid Derivatives

Reaction of Organometallic Reagents with Other Compounds

Reaction with Group-IA Organometallics

Reaction with Other Organometallics

Reaction with Polar Organometallics

Reaction with organometallic

Reaction with organometallic reagents

Reaction with organometallic species

Reaction with other Organometallic Compounds

Reactions of Acid Derivatives with Organometallic Reagents

Reactions of organometallic complexes with halogenes (SE2 mechanism)

Reactions of organometallic compounds with metal halides

Reactions of phosgene with transition metal organometallics

Reactions with organometallic compounds

Reactions with organometallic compounds Lewis acid promotion

Reactions with organometallic compounds alcohol synthesis

Reactions with organometallic compounds chemoselectivity

Reactions with organometallic compounds stereoselectivity

Selenones, vinyl reactions with organometallic compounds

Selenoxides, vinyl reactions with organometallic compounds

Stannanes reactions with organometallic compounds

Subject coupling reactions with organometallics

Subject reactions with organometallic compounds

Sulfamides, diaryl reactions with organometallic compounds

Sulfonimines reactions with organometallic compounds

Synthesis coupling reactions with organometallics

Through Reactions with Organometallic Compounds

Triflates reactions with organometallics

Water reactions with organometallic

Water reactions with organometallic compound

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