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Carboxylic acids, functional derivatives reactions with organometallic

Acidity of Amides, Imides, and Sulfonamides Characteristic Reactions Reaction with Water Hydrolysis Reaction with Alcohols Reactions with Ammonia and Amines Reaction of Acid Chiorides with Salts of Carboxylic Acids Interconversion of Functional Derivatives Reactions with Organometallic Compounds 18.10 Reduction... [Pg.736]

The electrochemical incorporation of CO2 into perfluoroalkyl derivatives has been explored in the case of (perfluoroalkyl)alkyl iodides and (perfluoroalkyl)alkenes, with an electrochemical system based on the use of consumable anodes combined with organometallic catalysis by nickel complexes. Iodide derivatives have been functionalized to the corresponding carboxylic acids by reductive carboxylation. Interesting and new results have been obtained from the fixation of CO2 into perfluoroalkyl olefins. Good yields of carboxylic acids could be reached by a carefull control of the reaction conditions and of the nature of the catalytic system. The main carboxylic acids are derived from the incorporation of carbon dioxide with a double bond migration and loss of one fluorine atom from the CF2 in a position of the double bond. [Pg.217]

Furthermore, we could show that this reaction mechanism to produce Cp-complexes of "mTc is not limited to carboxylate derivatives of Cp but that also further functionalities can be conjugated to receive, e.g., amides (49 and 50) [125]. This reactivity implies that, comparable to the SAAC approach, Thiele s acid derivatives can be incorporated in, e.g., a peptide strand and directly be labeled with [99mTc(OH2)3(CO)3]+. The preparation of cyclopentadienyl complexes with a variety of functionalities attached to the cyclopentadienyl ring stands for a more routine introduction of this important tridentate ligand in radiopharmaceutical organometallic complexes. [Pg.240]


See other pages where Carboxylic acids, functional derivatives reactions with organometallic is mentioned: [Pg.203]    [Pg.426]    [Pg.426]    [Pg.426]    [Pg.43]    [Pg.83]    [Pg.418]    [Pg.486]    [Pg.139]    [Pg.566]    [Pg.141]    [Pg.399]    [Pg.141]    [Pg.399]    [Pg.437]    [Pg.478]    [Pg.1210]    [Pg.543]    [Pg.82]    [Pg.141]    [Pg.399]    [Pg.143]    [Pg.289]    [Pg.25]   


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Acidic function

Acidic functionalities

Acidity functions

Acids, acid with organometallics

Carboxyl functionality

Carboxylate functionality

Carboxylates reaction with

Carboxylation reaction with

Carboxylic acid derivates

Carboxylic acid derivatives reactions with organometallic

Carboxylic acid derivs

Carboxylic acids reactions

Carboxylic acids, functional derivatives

Carboxylic derivs., reactions

Carboxylic functionalities

Carboxylic functionalized

Carboxylic functions

Carboxylic reactions with

Carboxylic-functionalization

Derivative function

Function derived

Functional carboxylic acid

Functionalized carboxylate

Organometallic acidity

Organometallic derivative

Reaction function

Reaction with carboxylic acids

Reaction with organometallics

With Carboxylic Acid Derivatives

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