Organometallic reagents reaction with acid chlorides

Reaction of Acid Chlorides with Organometallic Reagents Grignard reagents react with acid chlorides to yield tertiary alcohols in which two of the substituents are the same. [Pg.804]

Ziegeler-Natta conditions 304 zig zag chromophores 217 zinc-copper exchange 275 zinc-copper organometallics 397 zinc-copper reagents 396, 397 reactions with acid chlorides 398 zinc-copper species RCu(CN)ZnX 394 zinc enolates 20 zinc metal, activated 291 zinc organometallics 278, 389 zinc salts 9... [Pg.270]

Organometallic reagents react with carboxylic acid derivatives (RCOZ) to form two different products, depending on the identity of both the leaving group Z and the reagent R-M. The most useful reactions are carried out with esters and acid chlorides, forming either ketones or 3° alcohols. [Pg.750]

Reaction of Acid Chlorides with Organometallic Reagents... [Pg.862]

The reaction of acid chlorides with 2 equiv of a trimethylsi-lylmethyl organometallic reagent, where the metal can be chloro-magnesium, lithium, or, best, dichlorocerium, proved to be an excellent direct synthesis of allylsilanes via the intermediacy of an a-trimethylsilyl ketone (eq 3). By reaction of a-trimethylsilyl ketones with vinylmagnesium bromide, one can prepare 2-substituted 1,3-butadienes (eq4). ... [Pg.563]

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