Radionuclides, properties

The physical system consists of a single fracture located in a saturated porous rock (Fig. 6.7). The properties of the fracture and the porous matrix and the radionuclide properties are listed in Tables 6.7 and 6.8. 

Table 6.7 Fracture characteristics and radionuclide properties in the fracture.

W/ Re generators were described as early as 1966 using zirconium oxide (Lewis and Eldridge, 1966) and with aluminum oxide in 1972 (Mikheev et al. 1972), in spite of the excellent radionuclidic properties of Re, there was no practical use of this therapeutic... 

N. Quintero, I. M. Cohen, and G. Restrepo, Relating p+ radionuclides properties by order theory, /. Radioanal. Nucl. Chem. 298 (2013) 1937-1946. 

Several portions of Section 4, Properties of Atoms, Radicals, and Bonds, have been significantly enlarged. For example, the entries under Ionization Energy of Molecular and Radical Species now number 740 and have an additional column with the enthalpy of formation of the ions. Likewise, the table on Electron Affinities of the Elements, Molecules, and Radicals now contains about 225 entries. The Table of Nuclides has material on additional radionuclides, their radiations, and the neutron capture cross sections. 

The abundance of a trace element is often too small to be accurately quantihed using conventional analytical methods such as ion chromatography or mass spectrometry. It is possible, however, to precisely determine very low concentrations of a constituent by measuring its radioactive decay properties. In order to understand how U-Th series radionuclides can provide such low-level tracer information, a brief review of the basic principles of radioactive decay and the application of these radionuclides as geochronological tools is useful. " The U-Th decay series together consist of 36 radionuclides that are isotopes (same atomic number, Z, different atomic mass, M) of 10 distinct elements (Figure 1). Some of these are very short-lived (tj j 1 -nd are thus not directly useful as marine tracers. It is the other radioisotopes with half-lives greater than 1 day that are most useful and are the focus of this chapter. 

The thermodynamic properties of U-Th series nuclides in solution are important parameters to take into account when explaining the U-Th-Ra mobility in surface environments. They are, however, not the only ones controlling radionuclide fractionations in surface waters and weathering profiles. These fractionations and the resulting radioactive disequilibria are also influenced by the adsorption of radionuclides onto mineral surfaces and their reactions with organic matter, micro-organisms and colloids. 

The role of radionuclides as tracer of the chemical transport in river is also reinforced by the fact that each of the U-Th-Ra elements has several isotopes of very different half-lives belonging to the U-Th radioactive series. Thus, these series permit comparison of the behavior of isotopes of the same element which are supposed to have the same chemical properties, but very different lifetimes. These comparisons should be very helpful in constraining time scales of transport in rivers. This was illustrated by Porcelli et al. (2001) who compared ( " Th/ U) and ( °Th/ U) ratios in Kalix river waters and estimated a transit time for Th of 15 10 days in this watershed. The development of such studies in the future should lead to an important progress in understanding and quantifying of transport parameters in surface waters. This information could be crucial for a correct use of U-series radioactive disequilibria measured in river waters to establish weathering budgets at the scale of a watershed. 

Radioactivity, Natural—The property of radioactivity exhibited by more than 50 naturally occurring radionuclides. 

The numerical combination of protons and neutrons in most nuclides is such that the nucleus is quantum mechanically stable and the atom is said to be stable, i.e., not radioactive however, if there are too few or too many neutrons, the nucleus is unstable and the atom is said to be radioactive. Unstable nuclides undergo radioactive transformation, a process in which a neutron or proton converts into the other and a beta particle is emitted, or else an alpha particle is emitted. Each type of decay is typically accompanied by the emission of gamma rays. These unstable atoms are called radionuclides their emissions are called ionizing radiation and the whole property is called radioactivity. Transformation or decay results in the formation of new nuclides some of which may themselves be radionuclides, while others are stable nuclides. This series of transformations is called the decay chain of the radionuclide. The first radionuclide in the chain is called the parent the subsequent products of the transformation are called progeny, daughters, or decay products. 

Because estimates of health risk are based on the levels of radionuclides in or near the vicinity properties, the quality of the potential health risk estimates depends upon the availability of appropriate measurement data. Hence, the first steps involved the determination of the appropriate environmental pathways of exposure and developing the source term for the exposure of persons potentially at risk. For our work, the radiological source-term data was based on measurements made principally by the Oak Ridge National Laboratory and the Mound Laboratory. 

The principal problem in estimating potential health effects is one of relating the measured levels of radiation and/or radionuclides in/on a property to the projected cancer deaths if the location of occupants differs from where the measurements were taken. Aberrant high values can also easily distort and invalidate a comparison between properties. For this reason, we have based our estimates on mean or most likely, rather than maximal, values. 

For comparison, we have calculated the health effects for typical residential properties (4 occupants each) based on 1) the naturally occurring background radiation levels and radionuclide concentrations in four cities across the U.S. (see Table V) and 2) the EPA (CFR, 1981) guideline values (20 yR/h, 0.02 WL, 5 pCi Ra-226/g of soil) for cleanup at inactive uranium processing sites (see Table VI). 

Table II Range of Observed Radiation Levels and Radionuclide Concentrations at Uranium Mill Tailings Vicinity Properties...

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