Processing temperature, activation

Catalyst CAS Registry Number Activator Processing temperature, °C... 

This catalyst is noteworthy in that it represents a good example of a Hquid active phase, actually molten at the typical 600° C+ process temperatures, supported on a soHd support. 

The catalyst is then transferred back to the first process reactor and is reheated to the reforming process temperature at the reactor inlet using a flow of hydrogen-rich process recycle gas, thereby achieving reduction of the platinum to a catalyticaUy active state. 

The skin receives heat from the core by passive conduction and active skin blood flow (Table 5.3). It transfers this heat to the surroundings by convection, radiation, and evaporative (perspiration and diffusion) mechanisms. All of these mechanisms are unregulated or passive except evaporation from sweating. The sweating process is actively controlled by the humarrs thermoregulatory center where the rate of sweat secretion is proportional to eleva tions in core and skin temperature from respective set point temperatures (Table 5.3). 

In contrast to the influence of velocity, whose primary effect is to increase the corrosion rates of electrode processes that are controlled by the diffusion of reactants, temperature changes have the greatest effect when the rate determining step is the activation process. In general, if diffusion rates are doubled for a certain increase in temperature, activation processes may be increased by 10-100 times, depending on the magnitude of the activation energy. 

As stated in the introduction to this chapter, CVD can be classified by the method used to apply the energy necessary to activate the CVD reaction, i.e., temperature, photon, or plasma. This section is a review of temperature-activation process commonly known as thermal CVD. 

Consist of a range of chemicals which promote cross-linking can initiate cure by catalysing ( catalysts , hardeners, initiators), speed up and control cure (activators, promoters) or perform the opposite function (inhibitors) producing thermosetting compounds and specialised thermoplastics (e.g. peroxides in polyesters, or amines in epoxy formulations). The right choice of a cure system is dependent on process, process temperature, application and type of resin. 

Low-temperature activity promotion is an issue in mobile (diesel) applications, but may not be a critical issue in several stationary applications, apart from those where the temperature of the emissions to be treated is below 200°C (for example, when a retrofitting SCR process must be located downstream from secondary exchangers, or in the tail gas of expanders in a nitric acid plant). In the latter cases, a plasmacatalytic process [91] could be interesting. In the other cases, the use of NTP together with the SCR catalyst is not economically viable. However, the synergetic combination of plasma and catalysts has been shown to significantly promote the conversion of hazardous chemicals such as dioxins [92], Although this field has not yet been explored, it may be considered as a new plasmacatalytic SCR process for the combined elimination of NO, CO and dioxins in the emissions from incinerators. 

The first type of materials, i.e. KOH activated carbons constitute an interesting class of capacitor electrodes due to their highly developed surface area of the order of 3000 m2/g. Especially, inexpensive natural precursors are well adapted for this process. The activation process is strongly affected by the C KOH ratio, temperature and time. The optimal ratio seems to be 4 1 and the temperature for activation ca. 800°C. The total activation process is quite complicated and proceeds via different pathways and by-products. The... 

Finally, we tried to activate dopant atoms using pulsed laser irradiation, which is effective in lowering the process temperature. The light source was a 308-nm XeCl excimer laser, which is a standard source for crystallizing a-Si films used in the LTPS process.19 A test sample of 76 nm thickness, prepared from the copolymerized solution (l-wt% phosphorus, 30-min UV irradiation, 500 °C 2hr annealing), was irradiated using a XeCl laser at various intensities to activate the dopant atoms. Figure 5.19 shows the relationship between the... 

Pellistors are used to detect flammable gases like CO, NH3, CH4 or natural gas. Some flammable gases, their upper and lower explosion limits and the corresponding self-ignition temperatures are listed in Tab. 5.1. This kind of gas sensor uses the exothermicity of gas combustion on a catalytic surface. As the combustion process is activated at higher temperatures, a pellistor is equipped with a heater coil which heats up the active catalytic surface to an operative temperature of about 500 °C. Usually a Platinum coil is used as heater, embedded in an inert support structure which itself is covered by the active catalyst (see Fig. 5.33). The most frequently used catalysts are platinum, palladium, iridium and rhodium. 

Solid phase polymerisation is used for chain polymerisation processes which are carried out at low temperatures. In such processes the thermal activation is difficult and so for activation of such processes radiation-activation technique is used. These processes are very slow. An example of such a solid phase polymerisation is the preparation of Polyformaldehyde by the radiation polymerisation of solid trioxane. 

Neither o-NCB nor 2-EHA, individually, demonstrates exothermic activity at the normal Yellow 96 process temperatures. Morton s initial research and development for the Yellow 96 process identified the existence and described the two exothermic chemical reactions that can occur when the chemicals used to produce Yellow 96 are mixed and heated. The desired exothermic reaction to form Yellow 96 is initiated at an onset temperature of 38°C (100°F) and begins to proceed rapidly at a temperature of approximately 75°C (167°F). The undesired, exothermic reaction that results from the thermal decomposition of the Yellow 96 product is initiated at an onset temperature 195°C (383°F). 

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