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Primary ammonium

Although the clam structures are of interest as ammonium ion binders, they are by no means the only azacrown compounds of interest in this application. Sutherland and coworkers have examined a number of azacrowns as primary ammonium ion bind-ers - . In addition, Metcalfe and Stoddart have utilized bis-azacrowns to bind secondary ammonium cations. [Pg.160]

Carboxylic ionophores selectively transport cations by using intramolecular complexation in the uptake process of cations (basic region). A new ion transport system has been developed which incorporates a structural device which assists in the release process by using intramolecular complexation of an [18]crown-6 ring and a primary ammonium ion 48>. The experimental conditions are shown in Fig. 7. All these com-... [Pg.49]

Even though formic anhydride is not a stable compound (see p. 714), amines can be formylated with the mixed anhydride of acetic and formic acids (HCOO-COMe) °°° or with a mixture of formic acid and acetic anhydride. Acetamides are not formed with these reagents. Secondary amines can be acylated in the presence of a primary amine by conversion to their salts and addition of 18-crown-6. ° The crown ether complexes the primary ammonium salt, preventing its acylation, while the secondary ammonium salts, which do not fit easily into the cavity, are free to be acylated. [Pg.508]

Dynamics in Organic Inclusion Crystals of Steroids and Primary Ammonium Salts 505... [Pg.330]

A system exhibiting chiral recognition. The chiral macrotricyclic tet-raamide (250) (Lehn, Simon Moradpour, 1978) has been used for the complexation, extraction and transport of primary ammonium salts. The tetraamide was used rather than the corresponding tetraamine because of the lower basicity of the nitrogens in the former ligand. This avoids the possibility of proton transfer occurring from the primary ammonium substrates R-NH3+ used as guests. In a typical experiment, a solution of a primary ammonium salt, such as naphthylethyl ammonium or phenylalanine methylester hydrochloride in hydrochloric acid was... [Pg.153]

Several limitations on the synthetic techniques that can be employed are imposed by the need for rapidity and minimization of handling because of the radiation hazard, and the low concentration and small physical quantities of the compounds. Purification steps should be eliminated if possible by optimizing yields. Where purification is unavoidable, simple procedures are employed such as use of anion exchange columns to remove perrhenate (the most common contaminant in the final product). A variety of disposable sample preparation columns are well suited to this purpose and are available containing small quantities of anion or cation exchange materials (0.1 to 0.5 g typically) such as quaternary ammonium-, primary ammonium-, or sulfonate-derivatized silica. Reversed phase columns are also often used (C8 or C18-derivatized silica). The purification is often thus reduced to a simple filtration step which can be performed aseptically. [Pg.132]

The maximum observed free energy difference between two enantiomeric host-guest complexes in which one 1,1 -dinaphthyl element is the only source of chirality in the crown ether is about 0.3 kcal mol-1. Improvement of the free energy difference can be achieved by introduction of two such elements. Unfortunately crown ethers with three 1,1 -dinaphthyl groups did not form complexes with primary ammonium salts (de Jong et al., 1975). The dilocular chiral crown ether [294] forms complexes of different stability with R- and 5-cr-phenylethylammonium hexafluorophosphate. The (J )-J J -[284] complex was the more stable by 0.3 kcal mol-1 at 0°C (EDC value 1.77) (Kyba et al., 1973b). Crown ether [284] also discriminates between the two enantiomers of phenylglycine methyl ester hexafluorophosphate and valine methyl ester... [Pg.389]

The influence of the counterion on the stability of crown-ether complexes in general was reviewed in detail in one of the preceding sections. There it was shown to be an important parameter. The nature of the counterion in diastereomeric complexes of chiral crown ethers with primary ammonium salts also influences the chiral recognition. First of all it greatly determines whether salt can be extracted into the organic phase where the chiral discrimination takes place. In a series of experiments (Kyba et al., 1978) it was shown that when S,S -6zs(dinaphthyl)-22-crown-6 [284] in chloroform was equilibrated with racemic er-phenylethylammonium salts the type of anion also influences the degree of enantiomeric differentiation (Table 70). The highest... [Pg.399]

Another example of the use of Lewis acids in organic reactions in water is the lan-thanide(III) triflate catalysed aza-Diels-Alder reaction, exemplified in Scheme 14. In this reaction the hetero-dienophile is formed in situ from a primary ammonium hydrochloride and a carbonyl compound followed by the actual Diels-Alder reaction288,289. This type of reaction proceeds readily in aqueous media290-296, and a dramatic increase in the yield upon addition of lanthanide triflates was observed288,289. The exact role of the catalyst, however, is not entirely clear. Although it was suggested that the catalyst binds to the dienophile, other mechanisms, such as simple proton catalysis, are also plausible. Moreover, these reactions are further complicated since they are often heterogeneous. [Pg.1075]

The isomerization from 10 to 11 in the crystalUne state requires not only the movements of atoms but also a change in the crystal symmetry and the reconstruction of the hydrogen bond network pattern. In the crystals of these primary ammonium carboxylates, ID ladder-type hydrogen bonds are observed. The isomerization from the ZZ to EE form is associated with the rotation of carbonyl groups and the change in the hydrogen bond structure in this case. The quantitative transformation of 10 to 11 in the crystalUne state suggests that the molecular motion in the crystals occurred cooperatively with the minimum movement of atoms in the crystals via a phase transition from the crystal of 10... [Pg.299]

Synonyms ammonium dihydrogen phosphate ammonium hiphosphate primary ammonium phosphate... [Pg.43]

The major previously used routes to the higher cages (i.e. where n > 4) involved elimination reactions between aluminium alkyls and primary amines or the reaction of an aluminium hydride species, e.g.. MesN AlHs orLiAlH4 with primary amines or primary ammonium halides. A number of other routes had also been used among which was the reaction between a nitrile and aluminium hydride, Equation (8.7). [Pg.233]

Compound 28 is able to form 1 1 1 complexes with organic primary ammonium salts and water, or, alternatively, with a primary amine. In the... [Pg.107]

D. I. Mendeleeff argued that just as primary ammonium mesonitrate, (NH40)(H0)2N0,.is supposed to furnish nitrous oxide by the loss of three mols. of water, so may secondary ammonium mesonitrate, (NHiO)2(HO)NO, furnish hydrazoic acid by the loss of four mols. of water. This would make hydrazoic acid the nitrile of mesonitric acid ... [Pg.342]

Figure 3. Log K vs. carbon number for various alkylamnonium ions < > = primary ammonium ions, = secraidary amnonium ions, = tertiary ammonium ions, X = quaternary ammonium ions. Figure 3. Log K vs. carbon number for various alkylamnonium ions < > = primary ammonium ions, = secraidary amnonium ions, = tertiary ammonium ions, X = quaternary ammonium ions.

See other pages where Primary ammonium is mentioned: [Pg.180]    [Pg.185]    [Pg.187]    [Pg.45]    [Pg.222]    [Pg.49]    [Pg.50]    [Pg.55]    [Pg.197]    [Pg.759]    [Pg.716]    [Pg.287]    [Pg.287]    [Pg.291]    [Pg.744]    [Pg.744]    [Pg.745]    [Pg.744]    [Pg.744]    [Pg.745]    [Pg.153]    [Pg.935]    [Pg.943]    [Pg.944]    [Pg.180]    [Pg.185]    [Pg.187]    [Pg.26]    [Pg.57]    [Pg.72]    [Pg.342]    [Pg.1069]    [Pg.88]   
See also in sourсe #XX -- [ Pg.208 ]




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Organic Inclusion Crystals of Steroids and Primary Ammonium Salts

Primary ammonium phosphate

Recognition primary ammonium ions

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