Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Preparation reaction conditions

Catalyst Preparation, Reaction Conditions and Catalytic Cycle... [Pg.217]

Reac- tion Chemical composition (wt )) SSA (mVgy Method of preparation Reaction conditions P effeet Memo Refer- ence... [Pg.477]

Table 5. Preparative reaction conditions for the metallation of saturated sulfur compounds... Table 5. Preparative reaction conditions for the metallation of saturated sulfur compounds...
Methylolmelamines can be prepared that are either water soluble, hydrocarbon soluble, or insoluble depending on their preparative reaction conditions. [Pg.27]

IMP process. Developed by the Mexican Institute of Petroleum. It uses FBR in series with selective catalyst for removal of metals and sulfur, as well as hydrocracking of asphaltenes. The operation of reactors is at moderate severity, thus minimizing the formation of sediments. It employs proprietary catalysts that are designed according to the type and quality of heavy crude oil to be upgraded. Proper selection of feed preparation, reaction conditions, reactor arrangement, and catalyst properties assure the process to operate continuously (Ancheyta et al., 2010). [Pg.56]

Colourless solid m.p. 132-134 C. An important intermediate for preparing indole derivatives, produced by treating indole under Mannich reaction conditions with methanal and dimethylamine. [Pg.140]

Silyl ethers serve as preeursors of nucleophiles and liberate a nucleophilic alkoxide by desilylation with a chloride anion generated from CCI4 under the reaction conditions described before[124]. Rapid intramolecular stereoselective reaction of an alcohol with a vinyloxirane has been observed in dichloro-methane when an alkoxide is generated by desilylation of the silyl ether 340 with TBAF. The cis- and tru/u-pyranopyran systems 341 and 342 can be prepared selectively from the trans- and c/.y-epoxides 340, respectively. The reaction is applicable to the preparation of 1,2-diol systems[209]. The method is useful for the enantioselective synthesis of the AB ring fragment of gambier-toxin[210]. Similarly, tributyltin alkoxides as nucleophiles are used for the preparation of allyl alkyl ethers[211]. [Pg.336]

This chapter is an attempt to present the important results of studies of the synthesis, reactivity, and physicochemical properties of this series of compounds. The subject was surveyed by Bulka (3) in 1963 and by Klayman and Gunther (4) in 1973. Unlike the oxazoles and thiazoles. there are few convenient preparative routes to the selenazoles. Furthermore, the selenium intermediates are difficult to synthesize and are often extremely toxic selenoamides tend to decompose rapidly depositing metallic selenium. This inconvenience can be alleviated by choice of suitable reaction conditions. Finally, the use of selenium compounds in preparative reactions is often complicated by the fragility of the cycle and the deposition of metallic selenium. [Pg.219]

Dimerization in concentrated sulfuric acid occurs mainly with those alkenes that form tertiary carbocations In some cases reaction conditions can be developed that favor the formation of higher molecular weight polymers Because these reactions proceed by way of carbocation intermediates the process is referred to as cationic polymerization We made special mention m Section 5 1 of the enormous volume of ethylene and propene production in the petrochemical industry The accompanying box summarizes the principal uses of these alkenes Most of the ethylene is converted to polyethylene, a high molecular weight polymer of ethylene Polyethylene cannot be prepared by cationic polymerization but is the simplest example of a polymer that is produced on a large scale by free radical polymerization... [Pg.267]

A useful alternative to catalytic partial hydrogenation for converting alkynes to alkenes IS reduction by a Group I metal (lithium sodium or potassium) m liquid ammonia The unique feature of metal-ammonia reduction is that it converts alkynes to trans alkenes whereas catalytic hydrogenation yields cis alkenes Thus from the same alkyne one can prepare either a cis or a trans alkene by choosing the appropriate reaction conditions... [Pg.376]

Suggest reaction conditions suitable for the preparation of compound A from 5 hydroxy 2 hexynoic acid... [Pg.828]

Acroleki acetals have also been prepared ki high yields (66). The formation of the acetal requkes the careful control of reaction conditions to avoid additions to the double bond. Table 5 Hsts a variety of acroleki acetals that have been prepared and thek boiling points (68). [Pg.125]

Bromohydrins can be prepared direcdy from polyhydric alcohols using hydrobromic acid and acetic acid catalyst, followed by distillation of water and acetic acid (21). Reaction conditions must be carehiUy controlled to avoid production of simple acetate esters (22). The raw product is usually a mixture of the mono-, di-and tribromohydrins. [Pg.464]

HVP products prepared by hydrolysis with HCl contain varying amounts of glycerol chlorohydrins, such as 3-chloro-l,2-propanediol [96-24-2] and l,3-dichloro-2-propanol [96-23-1J, depending on reaction conditions and Hpid contents of the starting material (135). As a result of their toxicides, regulating agencies in many countnes have restncted the contents of these compounds in food. [Pg.470]

Akylsilanes are more reactive than vinylskanes in Friedel-Crafts reactions, as shown in the selective acylation of 2,3-disilylalkenes. The akylsilanes, a-skyloxyakyltrialkylsilanes, have been used as enolate equivalents in the preparation of 1,4-diketones (178). The mild reaction conditions required for these reactions tolerate many other functional groups, providing valuable synthetic routes. [Pg.562]

In Du Pont patents (116) the catalyst is prepared by spray-drying a mixture of colloidal siUca or other carriers and Pt/Pd salts. Aqueous hydrogen peroxide solutions up to 20 wt % ate reported for reaction conditions of 10—17°C and 13.7 MPa (140 kg/cm ) with 60—70% of the hydrogen feed selectively forming hydrogen peroxide. [Pg.478]

Typical reaction conditions are 150 to 300°C and up to 2 MPa pressure. Polyalkenyl succinic anhydrides are prepared under these conditions by the reaction of polyalkenes in a nonaqueous dispersion of maleic anhydride, mineral oil, and surfactant (33). [Pg.449]

Red mercuric oxide generally is prepared in one of two ways by the heat-induced decomposition of mercuric nitrate or by hot precipitation. Both methods require careful control of reaction conditions. In the calcination method, mercury and an equivalent of hot, concentrated nitric acid react to form... [Pg.113]

Acylation. Reaction conditions employed to acylate an aminophenol (using acetic anhydride in alkaU or pyridine, acetyl chloride and pyridine in toluene, or ketene in ethanol) usually lead to involvement of the amino function. If an excess of reagent is used, however, especially with 2-aminophenol, 0,A/-diacylated products are formed. Aminophenol carboxylates (0-acylated aminophenols) normally are prepared by the reduction of the corresponding nitrophenyl carboxylates, which is of particular importance with the 4-aminophenol derivatives. A migration of the acyl group from the O to the N position is known to occur for some 2- and 4-aminophenol acylated products. Whereas ethyl 4-aminophenyl carbonate is relatively stable in dilute acid, the 2-derivative has been shown to rearrange slowly to give ethyl 2-hydroxyphenyl carbamate [35580-89-3] (26). [Pg.310]

Dehydration. Dehydration of amyl alcohols is important for the preparation of specialty olefins and where it may produce unwanted by-products under acidic reaction conditions. Olefin formation is especially facile with secondary or tertiary amyl alcohols under acidic conditions. The reverse reaction, hydration of olefins, is commonly used for the preparation of alcohols. [Pg.372]

Cationic Starches. The two general categories of commercial cationic starches are tertiary and quaternary aminoalkyl ethers. Tertiary aminoalkyl ethers are prepared by treating an alkaline starch dispersion with a tertiary amine containing a P-halogenated alkyl, 3-chloto-2-hydtoxyptopyl radical, or a 2,3-epoxypropyl group. Under these reaction conditions, starch ethers are formed that contain tertiary amine free bases. Treatment with acid easily produces the cationic form. Amines used in this reaction include 2-dimethylaminoethyl chloride, 2-diethylaminoethyl chloride, and A/-(2,3-epoxypropyl) diethylamine. Commercial preparation of low DS derivatives employ reaction times of 6—12 h at 40—45°C for complete reaction. The final product is filtered, washed, and dried. [Pg.345]

The metabohcahy active folate cofactors (see Table 2) are prepared synthetically as follows. 7,8-Dihydrofohc acid (2) and 5,6,7,8-tetrahydrofohc acid (3) are prepared via catalytic hydrogenation of fohc acid under controUed reaction conditions (51,52). Optical rotation of (63, R)-H4 folate (3) is [oc] = +14.9° (0.1 NNaOH) and the natural (63)-H folate (3) is [oi] = —16.9° (0.1 NNaOH). [Pg.40]

Reactions. Although carbapenems are extremely sensitive to many reaction conditions, a wide variety of chemical modifications have been carried out. Many derivatives of the amino, hydroxy, and carboxy group of thienamycin (2) have been prepared primarily to study stmcture—activity relationships (24). The most interesting class of A/-derivatives are the amidines which are usually obtained in good yield by reaction of thienamycin with an imidate ester at pH 8.3. Introduction of this basic but less nucleophilic moiety maintains or improves the potency of the natural material while greatiy increasing the chemical stabiUty. Thus /V-formimidoyl thienamycin [64221-86-9] (MK 0787) (18), C 2H yN204S, (25) was chosen for clinical evaluation and... [Pg.5]

Optimization of the ATP—hemoglobin reaction conditions produced a preparation having a markedly reduced oxygen affinity. Five fractions from a reaction mixture, when isolated, were found to have P q values ranging from 1.1 to 5.0 kPa (8 to 38 torr), most withUtfle cooperativity (118). These results are consistent with those found with other polyfunctional reagents that react on the surface of hemoglobin. [Pg.166]

Borate salts or complexes of virtually every metal have been prepared. For most metals, a series of hydrated and anhydrous compounds maybe obtained by varying the starting materials and/or reaction conditions. Some have achieved commercial importance. [Pg.209]


See other pages where Preparation reaction conditions is mentioned: [Pg.42]    [Pg.204]    [Pg.42]    [Pg.204]    [Pg.48]    [Pg.2901]    [Pg.20]    [Pg.155]    [Pg.206]    [Pg.209]    [Pg.245]    [Pg.852]    [Pg.421]    [Pg.170]    [Pg.304]    [Pg.307]    [Pg.385]    [Pg.455]    [Pg.496]    [Pg.269]    [Pg.126]    [Pg.317]    [Pg.49]    [Pg.252]    [Pg.538]    [Pg.269]    [Pg.283]   
See also in sourсe #XX -- [ Pg.262 , Pg.263 , Pg.264 ]




SEARCH



Catalyst Preparation, Reaction Conditions and Catalytic Cycle

Catalyst samples preparation reaction conditions

Reaction condition

The Wrong Choice of Reaction Conditions How not to Prepare an

© 2024 chempedia.info