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Potential equation

It is not difficult to show that, for a constant potential, equation (A3.11.218) and equation (A3.11.219) can be solved to give the free particle wavepacket in equation (A3.11.7). More generally, one can solve equation (A3.11.218) and equation (A3.11.219) numerically for any potential, even potentials that are not quadratic, but the solution obtained will be exact only for potentials that are constant, linear or quadratic. The deviation between the exact and Gaussian wavepacket solutions for other potentials depends on how close they are to bemg locally quadratic, which means... [Pg.1002]

Figure C2.6.5. Examples of tire AO potential, equation (C2.6.12). The values of are indicated next to tire curves. The hard-sphere repulsion at r = 7 has not been drawn. Figure C2.6.5. Examples of tire AO potential, equation (C2.6.12). The values of are indicated next to tire curves. The hard-sphere repulsion at r = 7 has not been drawn.
Charged particles in polar solvents have soft-repulsive interactions (see section C2.6.4). Just as hard spheres, such particles also undergo an ordering transition. Important differences, however, are that tire transition takes place at (much) lower particle volume fractions, and at low ionic strengtli (low k) tire solid phase may be body centred cubic (bee), ratlier tlian tire more compact fee stmcture (see [69, 73, 84]). For tire interactions, a Yukawa potential (equation (C2.6.11)1 is often used. The phase diagram for the Yukawa potential was calculated using computer simulations by Robbins et al [851. [Pg.2687]

The potential energy of a molecular system in a force field is the sum of individnal components of the potential, such as bond, angle, and van der Waals potentials (equation H). The energies of the individual bonding components (bonds, angles, and dihedrals) are function s of th e deviation of a molecule from a h ypo-thetical compound that has bonded in teraction s at minimum val-n es. [Pg.22]

Equations (5,61) and (5.62) can be used to derive a pressure potential equation applicable to thin-layer flow between curved surfaces using the following procedure. In a thin-layer flow, the following velocity boundary conditions are prescribed ... [Pg.179]

After the substitution for Ai and A2 into Equation (5.74) the pressure potential equation corresponding to creeping flow of a power law fluid in a thin curved layer is derived as... [Pg.182]

The comparison of flow conductivity coefficients obtained from Equation (5.76) with their counterparts, found assuming flat boundary surfaces in a thin-layer flow, provides a quantitative estimate for the error involved in ignoring the cui"vature of the layer. For highly viscous flows, the derived pressure potential equation should be solved in conjunction with an energy equation, obtained using an asymptotic expansion similar to the outlined procedure. This derivation is routine and to avoid repetition is not given here. [Pg.182]

This is a typical function for electrostatic potential (equation 13). [Pg.27]

Whereas lowering the potential results in a decrease in, the converse applies when the potential is raised. However, this increase in activity is again limited by the formation of a solid phase. Thus curve e of Fig. 1.15 (top) gives the equilibrium between Fe(OH)3 and Fe at any predetermined activity of the latter in the range 10 — 10". At flpe2+ = 10 g-ion/l, E= [ 1-06-t-(-6 X 0-059)] - 0-177pH which defines the boundary between corrosion and passivity at high potentials (equation 1.19). [Pg.66]

Matsui441 has computed energies (Evdw) due to the van der Waals interaction between a-cyclodextrin and some guest molecules by the use of Hill s potential equation 451 ... [Pg.65]

Finally we shall show that the potential equation is generally applicable to systems defined by the independent variables ... [Pg.110]

This equation applies to nearly all practical cases of gaseous equilibria, and it may be called the Canonical Potential Equation for Gaseous Equilibrium. [Pg.326]

In this case, equation (17) can he derived from the canonical potential equation by putting ... [Pg.328]

To compare molecular theoretical and molecular dynamics results, we have chosen the same wall-particle potential but have used the 6 - oo fluid particle potential. Equation 14, Instead of the truncated 6-12 LJ potential. This Is done because the molecular theory Is developed In terms of attractive particles with hard sphere cores. The parameter fi n Equation 8 Is chosen so that the density of the bulk fluid In equilibrium with the pore fluid Is the same, n a = 0.5925, as that In the MD simulations. [Pg.270]

Analytical solutions for the closure problem in particular unit cells made of two concentric circles have been developed by Chang [68,69] and extended by Hadden et al. [145], In order to use the solution of the potential equation in the determination of the effective transport parameters for the species continuity equation, the deviations of the potential in the unit cell, defined by... [Pg.598]

The above equation allows the calculation of Galvani potentials at the interfaces of immiscible electrolyte solutions in the presence of any number of ions with any valence, also including the cases of association or complexing in one of the phases. Makrlik [26] described the cases of association and formation of complexes with participation of one of the ions but in both phases. In a later work [27] Le Hung extended his approach and also considered any mutual interaction of ions and molecules present in both phases. Buck and Vanysek performed the detailed analysis of various practical cases, including membrane equilibria, of multi-ion distribution potential equations [28,29]. [Pg.22]

Chromate is a strong oxidizing agent in acidic media and produces Cr(III) ions in the hydrate form, Equation 6. In neutral and basic media, chromate is a rather weak oxidizer, as evidenced by its negative oxidation potential (Equation 7), and the product is chromic hydroxide (8). [Pg.146]

And each proton is attracted to one of the electron clouds through the point-cloud potential (Equation 3.7). The attractive force is given by the gradient of the point-cloud potential ... [Pg.35]

After the electrode reaction starts at a potential close to E°, the concentrations of both O and R in a thin layer of solution next to the electrode become different from those in the bulk, cQ and cR. This layer is known as the diffusion layer. Beyond the diffusion layer, the solution is maintained uniform by natural or forced convection. When the reaction continues, the diffusion layer s thickness, /, increases with time until it reaches a steady-state value. This behaviour is also known as the relaxation process and accounts for many features of a voltammogram. Besides the electrode potential, equations (A.3) and (A.4) show that the electrode current output is proportional to the concentration gradient dcourfa /dx or dcRrface/dx. If the concentration distribution in the diffusion layer is almost linear, which is true under a steady state, these gradients can be qualitatively approximated by equation (A.5). [Pg.85]

In the DCA-sensitized reaction of silyl amino esters 46 (equation 16) the formation of pyrrolidines 48 must be obtained through a desilylmethylation. This process can be prevented by attaching an electron-withdrawing group to the amine that obviously reduces its oxidation potential (equation 17)48. [Pg.691]

The interfacial charge-related capacity, Cum, due to the internal polarization of adsorbed water molecules remains constant in the potential range where no reorganization of adsorbed water molecules occurs. On the other hand, the interfacial capacity related to water dipoles, Cs.di i, on the aqueous solution side depends on the orientation of adsorbed water molecules which changes with the interfacial charge and, hence, with the electrode potential. Further, the dipole capacity. Cm, dtp > on the metal side appears to slightly depend upon the interfacial charge and, hence, the electrode potential. Equation 5-11, then, yields Eqn. 5-12 ... [Pg.135]

The point at which the straight line of (tph) versus Eintersects the coordinate of electrode potential represents the flat band potential. Equation 10-15 holds when the reaction rate at the electrode interface is much greater than the rate of the formation of photoexcited electron-liole pairs here, the interfadal reaction is in the state of quasi-equilibrium and the interfadal overvoltage t)j, is dose to zero. [Pg.337]

Within the framework of commercial CFD codes where sequential solution methods are standard, as they need to solve a number of user-specified transport equations, the two potential equations must then be solved through innovative source term linearization. ... [Pg.491]

Nernst Equation for Concentration Dependence of RedOx Potential. Equation (5.9) applied to the general RedOx electrode (5.16) yields... [Pg.62]


See other pages where Potential equation is mentioned: [Pg.315]    [Pg.1645]    [Pg.595]    [Pg.270]    [Pg.392]    [Pg.166]    [Pg.38]    [Pg.442]    [Pg.213]    [Pg.89]    [Pg.139]    [Pg.406]    [Pg.475]    [Pg.131]    [Pg.166]    [Pg.213]    [Pg.165]    [Pg.165]    [Pg.227]    [Pg.230]    [Pg.56]    [Pg.381]    [Pg.490]    [Pg.490]    [Pg.502]    [Pg.53]   
See also in sourсe #XX -- [ Pg.381 ]




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Action potentials Nernst equation

Arrhenius equation, potential energy surfaces

Butler-Volmer equation current-potential dependence

Butler—Volmer equation current—potential relationship

Cell potential Electrochemical cells. Nernst equation)

Charge Transport and Electrical Potential Equation

Chemical potential Clausius-Clapeyron equation

Chemical potential change equation

Chemical potential equation

Cottrell equation, potential step methods

Current potential equation

Current-potential curves Butler-Volmer equation

Debye-Hiickel equation chemical potentials

Debye-Hiickel equation electrostatic potential

Debye-Huckel equation electrostatic potential

Diffusion Equation for Two-component Gas Mixture (Without and With a Potential Field)

Dirac equation central potential

Dirac equation electric potentials

Dirac equation magnetic potentials

Discretization of the electromagnetic potential differential equations

Dubinin Equation for Potential Theory

Electrode Potential, E, and the Rate Equations for Electron Transfer Reactions

Electrode potentials and activity. The Nernst equation

Electromagnetic potential equations and boundary conditions

Electrostatic potential Poisson equation

Electrostatic potential Poisson-Boltzmann equation

Electrostatic potential distribution Poisson-Boltzmann equation

Equation for Separation Potential

Equation for the Membrane Potential

Equations, mathematical Coulomb potential

Equilibrium electrode potentials Nernst equation

Exchange potential from Kohn-Sham equations

Gibbs, adsorption equation chemical potential

Gibbs, adsorption equation potential

Gibbs, adsorption equation thermodynamic potential

Gibbs-Duhem equation chemical potential

Goldman equation, membrane potential

Hamiltonian equation electrical potential

Hamiltonian equations potentials

Helmholtz-Smoluchowski equation zeta potential determination

Hodgkin-Katz equation, membrane potential

Inner potential Poisson equation

Inner potential Poisson-Boltzmann equation

Integral equations potential scattering

Langevin equation potential

Lennard-Jones equation pair potential

Lennard-Jones equation potential parameters

Lennard-Jones intermolecular potential function, equation

Lennard-Jones potential equation

Liquid junction potential, Henderson equation

Membrane potential Nemst equation

Morse equation, potential

Mott-Schottky equation flat band potentials

Nematic potentials equation

Nemst equation potential

Nemst equation reversible electrode potential

Nernst equation resting membrane potential

Nernst equation transmembrane potential

Nernst potential equation

Nernst-Planck equation, membrane potential

Oxidation-reduction equations standard cell potential

Poisson equation solution electrostatic potential

Polanyi potential theory Dubinin-Radushkevich equation

Potential electric double layer, equation defining

Potential energy surfaces quantum chemical equations

Potential energy, equation

Potentials integral equation, derivation

Reduction potentials Nernst equation

Schrodinger equation Coulomb potential

Schrodinger equation confinement potential with

Schrodinger equation harmonic oscillator potential

Schrodinger equation potential energy

Schrodinger equation potential scattering

Schrodinger equation potentials

Schrodinger equation short-range potential

Smoluchowski equation potential

Stack potential, equation

Standard cell potential Nemst equation

Surface potential equations

Surface potential minerals equation

The Nernst Equation Effect of Concentration on Half-Cell Potential

The Nikolsky-Eisenman equation and phase boundary potential model

The Schrodinger equation for a local, central potential

Zeta potential Helmholtz-Smoluchowski equation

Zeta potential Henry equation

Zeta potential Huckel equation

Zeta potential Smoluchowski equation

Zeta potential equation defining

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