POLYETHER-ETHERKETONE

UV detector. A small-diameter tube is placed in the side arm of the tee and runs to the inlet to the MS. The tubing is usually either PEEK (polyether-etherketone) or fused silica. A smaller-inner-diameter tube penetrates into the source and acts as a restrictor, limiting the flow through this side arm. The fluid pressure drops below the two-phase region somewhere in the transfer line. The small droplets of modifier formed clean the transfer line and rapidly delivers the solute to the MS source. 

Polymer blends leading to high-end polymers, e.g. from sulfonated polymers (sPEEK - sulfonated polyether-etherketone, sPPSU - sulfonated polyphenyl-sulfone) combined with alkaline components (amine, imidazole, polybenzimidazole) The combination results in ionic cross-linked phases. Commercially available polymers can be modified by different sulfonation reagents. Another possibility is to combine different monomers based on block co-polymers. The conductivity can be controlled by the number of S03H groups due to the dependence of the water uptake from the number of groups ([23] and references cited therein). 

The Bell/Boeing V22 Osprey tilt-rotor aircraft uses carbon fiber-reinforced polyether etherketone (PEEK) for doors and housings of the engine air particle separator and for fuel vent tanks (Figure 6.44). TP polyimide (TPI) forms the basis for an injection-molded spline adapter in the drive train which tilts the rotors. Costs were reduced some 22%. The parts were developed by RTP Company with Bell Helicopter and molder RAM Inc., Texas. The tanks are molded by the lost core process. 

The search for thermoplastic materials that may be used at elevated temperatures has received much attention in recent years. Materials that are relatively difficult to prepare like polyetherimide and polyether-etherketone have been proposed as High Temperature Plastics. Our aim has been the development of materials that would be fairly inexpensive by virtue of simple raw materials and a relatively simple polymerization process. 

Figure 1 Cost-related (specific) flexural strength of major thermoplastics, versus cost-related (specific) thermal tolerance. The unit cost is the market price in US cents (1992) of 1 cm plastics. The thermal tolerance is the temperature difference (AT) over room temperature (AT — T - room T), by which temperature (7 ) the flexural modulus is equal to 1 GPa. Designations, abbreviations WFRP-S, wood fiber reinforced PP (S type) of AECL, Canada (See Table 1) PMMA, polymethylmethacrylate PVC, pol)winyl chloride PS, polystyrene PP, polypropylene UP, unsaturated polyesters PA-GF, glass fiber (35%) reinforced polyamide PHR, phenolic resin EP, epoxy resin ABS, acrylonitrile/butadiene/styrene copolymer UF, urea/formaldehyde LDPE, low density polyethylene PC, polycarbonate POM, polyoxymethylene CAB, cellulose acetate butyrate LCP, liquid crystal polymers PEEK, polyether-etherketone PTFE, polytetrafluorethylene.

The model material used is a unidirectional carbon fiber-reinforced, thermoplastic polyether-etherketone (PEEK) composite with fiber diameter of = 8 fim. The fiber orientations studied are shown in Figure 1. The mechanical properties of this material are listed in Table 1. The first principal material direction, indicated by 1 in Table 1, is parallel to the fiber direction (Figure 1), the second and the third one are perpendicular to the fiber orientation. The anisotropic composite material properties were specified using the rule of mixture type equations. ... 

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