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Polarisation forward

Each of these two procedures can be varied by proceeding from a low to a high current density (or potential) or from a high to a low current density (or potential) the former is referred to as forward polarisation and the latter as reverse polarisation. Furthermore, there are a number of variations of the potentiostatic technique, and in the potentiokinetic method the pwtential of the electrode is made to vary continuously at a predetermined rate, the current being monitored on a recorder in the pulse method the electrode is given a pulse of potential and the current transient is determined by means of an oscilloscope. [Pg.107]

The reactions M + N02 have large reaction cross sections ( 100— 200 A2) and are consistent with a direct reaction proceeding by means of an electron jump. The MO product is scattered forward with low recoil energy [345, 346]. Visible chemiluminescence is observed from BaO (A Z) and this channel constitutes 0.18% of the total reaction [347]. The BaO (A) vibrational state distribution is found to be inverted with v = 8, 9 and 10 being preferentially populated. It is not expected that the NO fragment is appreciably excited. Polarisation measurements [344] of the BaO product in the chemiluminescent channel indicate a reasonable amount of the total angular momentum of the reactive collision appears as rotational angular momentum of the BaO product. [Pg.423]

Pleat and crease retention, 879 Pleochroism, 289 Ploughing, 841 Plunger forward time, 806 Pockels-effect, 349 Poiseuille flow, 591 number, 59 Poisson ratio, 383 Polar forces, 205 Polarisation, 319 flux density, 348 Polaron, 341... [Pg.999]

Since the laser is highly linearly polarised with its E vector along the drift tube axes, the electrons are ejected initially towards or away from the electron detector. The ions are also ejected preferentially towards (Hf ) or away from (Hb) the ion detector. The design of the double drift tube is such that the forward and backward electrons and forward and backward ions arrive at their respective detectors with a TOP, t, given by Eq. (1) the instrumental constants, A and B, differ for electrons and ions. Hence the electron and ion TOP spectra are symmetric about their respective zero energy TOPs. [Pg.17]

Center of mass differential cross sections (presented here only for 0( D) + H2) present a (juasi forward-backward symmetry and small rmdulations. The degree of polarisation (ratio of DCS for forwcu d/sideways or backward/sideways) is high ( 3) for initial rotational state j = 0 and decreases with j. The for-... [Pg.211]

Before moving forward, the chemical biology reader should appreciate that Mz(f) polarisation and recovery towards steady state bulk magnetisation Mby spin-lattice relaxation are primarily indicative of changes in the levels of spin state occupancy. By contrast, My(f) coherence and evolution by spin-spin relaxation are both primarily indicative of transitions between spin state energy levels. In this context, the nuclear Overhauser effect (NOE) is a very important through-space effect in NMR spectroscopy that results directly from dipolar coupling-mediated spin-lattice relaxation. [Pg.241]

The analysis of the polarised neutron experiment on K2NaCrFe (Fig. 9) has been completed< >. The aspherical form factor component/4(0 was shown to be particularly sensitive to the covalent spin distribution, and the shape of fi Q) supported the inference for eg spin polarization drawn from the comparison of powder neutron diffraction data and resonance data (Section VI. B). A preliminary report of the form factor determination for both tetra-hedrally and octahedrally coordinated Fe + in YaFesOis by polarized neutrons has been given ). The form factors are not the same and that for tetrahedral Fe + is contracted relative to that for octahedral Fe +, which follows closely the calculated free-ion curve. The ligand forward peak (Section VI. B) has been directly observed ) in a measurement of the critical scattering of neutrons by ferromagnetic K2CUF4. [Pg.220]

The forward -backward asymmetry in the polarised case is thus given... [Pg.152]

Figure 1. Schematic representation of a single-layer light-emitting diode polarised under forward bias. The electrons (holes) are injected in the matrix at the interface between the polymer and the low (high) workfunction metal. The charge carriers then recombine under the form of singlet and triplet excitors and light emission is obtained from the radiative decay of the singlet species. Figure 1. Schematic representation of a single-layer light-emitting diode polarised under forward bias. The electrons (holes) are injected in the matrix at the interface between the polymer and the low (high) workfunction metal. The charge carriers then recombine under the form of singlet and triplet excitors and light emission is obtained from the radiative decay of the singlet species.
To minimise reactions between the cathode and the electrolyte, in Japan, most research efforts have focused on the A-site-deficient lanthanum manganite. In the USA and Europe, however, efforts [50] have been made to seek alternative cathodes, but with only limited success. Perhaps the most significant finding has been the use of composite cathodes in contact with the YSZ electrolyte. These composite cathodes minimise cathode/electrolyte interaction by mixing LSM and YSZ powders and laying down a thin layer of this mixture on the electrolyte [10]. Another step forward has been the use of an activation process to reduce the polarisation loss at the electrode [51]. [Pg.133]


See other pages where Polarisation forward is mentioned: [Pg.818]    [Pg.93]    [Pg.211]    [Pg.4]    [Pg.103]    [Pg.469]    [Pg.155]    [Pg.521]    [Pg.535]    [Pg.4]    [Pg.121]    [Pg.320]    [Pg.225]    [Pg.153]    [Pg.431]    [Pg.789]    [Pg.423]    [Pg.201]    [Pg.153]    [Pg.205]    [Pg.158]    [Pg.247]    [Pg.47]    [Pg.193]    [Pg.847]    [Pg.22]    [Pg.337]    [Pg.170]    [Pg.432]    [Pg.441]    [Pg.52]    [Pg.337]    [Pg.444]   
See also in sourсe #XX -- [ Pg.107 ]

See also in sourсe #XX -- [ Pg.107 ]




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Forward

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Polarisability

Polarisable

Polarisation

Polariser

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