Poly engineering plastic

Stewart, M. E., Cox, A. J. and Naylor, D. M., Transesterification of poly(ethylene-2,6-naphthalene dicarboxylate/poly(ethyleneterephthalate) blends, in Proceedings of the 51st SPE ANTEC 93 Conference, May 9-13, 1993, New Orleans, LA, Society of Plastics Engineers, Brookfield, CT,... 

Bicakci, E., Zhou, X. and Cakmak, M., Phase and uniaxial deformation behavior of ternary blends of poly(ethylene naphthalate), poly(ether imide) and poly(ether ether ketone), in Proceedings of the 55th SPE ANTEC 97 Conference, May 5-8, 1997, Toronto, ON, Canada, Society of Plastics Engineers, Brookfield, CT, 1997, Vol. 2, pp. 1593-1599. 

Figure 8. Submicrometer (0.75- ym) features generated in a bilayer of 0,2 fim of poly(cyclohexylmethylsilane) coated over 2.0 xm of a hard-baked AZ photoresist by mid-UV projection lithography (100 mjlcm ). Image transfer was by O2-RIE. (Top photo is reproduced with permission from reference 66. Copyright 1984 Society of Photo-Optical Instrumentation Engineers. Bottom photo is reproduced with permission from reference 63. Copyright 1986 Society of Plastics Engineers.)...

Brecker, L.R. Mechanism of organotin stabilization of poly(vinyl chloride). 1. The structure and equilibria of alkyltin alkyl mercaptopropionates and their compatibility with PVC. In Plastics Plastics on My Mind, Proceedings Antec 1998 Brookfield, Society of Plastic Engineering Vol. 3, 33291. 

Shell Chemical has commercialized poly(trimet-hylene terephthalate) (based on 1,3 propane diol) under the trade name Corterra [Plastics Engineering, Nov. 1997]. This polyester will exhibit performance intermediate between PET and PBT and should exhibit blend potential similar to that enjoyed by these well established polyesters. 

Clear bottles/sheet. pata from Carroll, W. F., Johnson, R. W., Moore, S. S., Paradis, R. A., Applied Plastics Engineering Handbook, Chapter 5. Poly(vinyl chloride), Elsevier, 2011, p. 61-76.]... 

These types of composite sheet materials based upon engineering plastics like Poly-amides, PBT, XENOY etc. are now becoming available. By hot pressing, stamping... 

Commercial plastics are invariably mixtures of one or more polymers blended with a variety of additives such as colorants, flame-retardants, biocides, etc., all tailored to achieve cost-effective performance for specific applications or processibility requirements. For example, flexible PVC for wire insulation contains one or more plasticizers, and poly (2,6-dimethyl-1,4-phenylene oxide) (PPO), an engineering plastic, is marketed in several grades which may contain varying amounts of lubricants, stabilizers, fillers etc., in addition to the high-impact PS (HIPS) which is added to PPO to modify impact properties and melt viscosity. 

Figure 4.10. Correlation of the Tg and values as measured by TMA and DSC for engineering plastics from the Society of Plastic Engineers (SPE) resin kit ( 1043), including polystyrene, poly(methyl methacrylate), polycarbonate, polytetrafluoroeth-ylene, and polypropylene [From Riga and Collins (1991) reprinted with permission of ASTM].

Figure 5.35. DMA storage modulus curves for as-spun and drawn poly(ethylene-2,6-naphthalene dicarboxylate) (PEN) monofilaments the as-spun fiber, which is unoriented and amorphous, exhibits a modulus decrease due to the glass transition of the polymer then, the modulus increases again due to cold crystallization. [From Saw et al. (1997) reprinted with permission of Society of Plastics Engineers.]...

Figure 19. Response of a poly(3-hexylthiophene) sensor to toluene vapor. Reproduced with permission ftom reference 50. Copyright 1997 Society of Plastics Engineers.

Song, K., et al. (2013). Lubrication of Poly (vinyl alcohol) Chain Orientation by Carbon Nano-Chips in Composite Tapes. Journal of Applied Polymer Science, 127(4), 2977-2982. Theodorou, D. N. (1996). Molecular Simulations of Sorption andDiffusion in Amorphous Polymers. Plastics Engineering-New York, 32, 67-142. 

The Applied Plastics Engineering Handbook opens with a brief introductory chapter on the plastics industry. Then the handbook is divided into five sections. The first section presents in-depth discussions of important polymeric materials and is divided into three parts. The first part, on plastics, begins with a brief survey chapter, and then deals with engineering thermoplastics, polyolefins, fluoropolymers, and poly (vinyl chloride) the second part covers thermoplastic and thermoset elastomers and the third part focuses on nanocomposites. 

Carter C M (2001) Crystallization kinetics of poly(ethylene-terephthaJate) based iono-iner nauocomposite materials, in Annual Technical Conference, Dallas (The Society of Plastics Engineers), pp. 3210-3213. 

Figure5.1 Tg data for nitrated polystyrene/poly(acrylicacid) blends (Reprinted (replotted)from Al-Naijar, M. M., Hamid, S. H.and Hamad, E. Z., Po/ym. Eng. Sc/. (1996) 36, p. 2083, with permission of the Society of Plastics Engineers)...

Chloroform 100 70 122 170 1 4 1 1 Specimen is not resistant swelling >8% or weight loss >5% and/or break elongation decreased by >50% 15-30% loss in property values minor chemical attack Not recommended >50% loss in property values II Polystone M Rochling Engineered Plastics Tivar Poly Hi Solidur Specimen Based on well-processed or well-fabricated test specimen... 

FIGURE 2.9 Typical creep curve (a) with linear time scale and (b) with logarithmic time scale, (c) Family of creep curves for poly(methyl methacrylate) at 20 C (1 kgf/cm = 0.098 MPa). (Adapted from Crawford, R. J. 1981. Plastics Engineering, Pergamon, London.)... 

Sheth, K. C. R. Gallucci, R. R.and Haralur, G., Thermoplastic polyimide - poly-etheretherketone blends with exceptional high temperature properties, ANTEC 2008, Proceedings of the 66th Annual Technical Conference Exhibition, Milwaukee, WI, 4-8.05.2008, Society of Plastics Engineers, pp. 794-797. 

Tian, J. Kim, S. D.and Chakravarti S., Phase behavior of blends containing poly(resorcinol phthalate-block-carbonate) and poly(ethylene terephthalate) , ANTEC 2009,Proceedings of the 67thAnnual Technical Conference Exhibition, Chicago, IL, 22-2406.2009, Society of Plastics Engineers, pp. 1438-1442. 

Polyoxyethylene. Synthetic polymers with a variety of compositionaHy similar chemical stmctures are as follows. Based on polarity, poly(oxymethylene) (1) would be expected to be water soluble. It is a highly crystalline polymer used in engineering plastics, but it is not water-soluble (see... 

Butanediol. 1,4-Butanediol [110-63-4] made from formaldehyde and acetylene, is a significant market for formaldehyde representing 11% of its demand (115). It is used to produce tetrahydrofuran (THF), which is used for polyurethane elastomers y-butyrolactone, which is used to make various pyrroHdinone derivatives poly(butylene terephthalate) (PBT), which is an engineering plastic and polyurethanes. Formaldehyde growth in the acetylenic chemicals market is threatened by alternative processes to produce 1,4-butanediol not requiring formaldehyde as a raw material (140) (see Acetylene-derived chemicals). 

Acrylic ESTER POLYMERS Acrylonitrile POLYMERS Cellulose esters). Engineering plastics (qv) such as acetal resins (qv), polyamides (qv), polycarbonate (qv), polyesters (qv), and poly(phenylene sulfide), and advanced materials such as Hquid crystal polymers, polysulfone, and polyetheretherketone are used in high performance appHcations they are processed at higher temperatures than their commodity counterparts (see Polymers containing sulfur). 

Hydroformylation. Hydroformylation of aEyl alcohol is a synthetic route for producing 1,4-butanediol [110-63-4] a raw material for poly(butylene terephthalate), an engineering plastic (qv) many studies on the process have been carried out. 

Not only ate ABS polymers useful engineering plastics, but some of the high mbber compositions are excellent impact modifiers for poly(vinyl chloride) (PVC). Styrene—acrylonitrile-grafted butadiene mbbers have been used as modifiers for PVC since 1957 (87). 

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