Plastic surrounding

Catalyst Research Corporation (USA) is a major manufacturer of lithium—iodine batteries used for pacemaker and other applications. The Catalyst Research Series 800 cells use the lithium envelope concept. The cell is constructed with a centrally located cathode current collector and a lithium envelope which surrounds and contains the iodine depolarizer material (Figure 24.14). This depolarizer material is corrosive to the stainless steel case and must be kept irxnn contacting the case for maximum cell life. A second barrier, formed from fluorocarbon plastics, surrounds the lithium envelope, insulates it from the case, and provides a second envelope for the containment of the depolarizer. The corrosive effect of iodine-containing depolarizer on stainless steel is lower than that of depolarizer made with more active halogens, such as bromine or chlorine. 

Fillers that contain combined water or carbon dioxide, such as alumina trihydrate, Mg(OH)2, or dawsonite [12011 -76-6] increase fire resistance by hberating noncombustible gases when they are heated. These gases withdraw heat from the plastic and can also reduce the oxygen concentration of the air surrounding the composition. 

Eoamable compositions in which the pressure within the cells is increased relative to that of the surroundings have generally been called expandable formulations. Both chemical and physical processes are used to stabilize plastic foams from expandable formulations. There is no single name for the group of cellular plastics produced by the decompression processes. The various operations used to make cellular plastics by this principle are extmsion, injection mol ding, and compression molding. Either physical or chemical methods may be used to stabilize products of the decompression process. 

The use of the single parameter, K, to define the stress field at the crack tip is justified for brittle materials, but its extension to ductile materials is based on the assumption that although some plasticity may occur at the tip the surrounding linear elastic stress field is the controlling parameter. 

When plastic deformation occurs, crystallographic planes sHp past each other. SHp is fackitated by the unique atomic stmcture of metals, which consists of an electron cloud surrounding positive nuclei. This stmcture permits shifting of atomic position without separation of atomic planes and resultant fracture. The stress requked to sHp an atomic plane past an adjacent plane is extremely high if the entire plane moves at the same time. Therefore, the plane moves locally, which gives rise to line defects called dislocations. These dislocations explain strain hardening and many other phenomena. 

Of the various processing techniques used, injection mol ding and extmsion involve Htfle or no exposure of hot product to the surrounding air, hence they give rise to no significant emission of plasticizer to the atmosphere. This is not the case in the production of sheet and film by calendering or spread coating. 

Antimony tris(isooctylthioglycolate) has found use in pipe formulations at low levels. Its disadvantage is that it cross-stains with sulfide-based tin stabilizers (122). Barium—zinc stabilizers have found use in plasticized compounds, replacing barium—cadmium stabilizers. These are used in mol dings, profiles, and wire coatings. Cadmium use has decreased because of environmental concerns surrounding certain heavy metals. 

Self-baked carbon electrodes are those whose shapes are formed in situ (33). The carbonaceous mixture is placed into a hoUow tube-shaped metal casing. The upper end receives the unbaked mixture as a soHd block, small particles, or warm plastic paste. The casing contains inwardly-projecting longitudinal perforated fins that become surrounded by baked carbon as the casing is incrementally moved downward and through the contact plates. Casing and carbon are consumed in this furnace. 

Flashback tests incorporate a flame arrester on top of a tank, with a large plastic bag surrounding the flame arrester. A specific gas mixture (for example, propane, ethylene, or hydrogen at the most sensitive composition in air) flows through and fills the tank and the bag. Deflagration flames initiated in the bag (three at different bag locations) must not pass through the flame arrester into the tank. On the unpro-tec ted side, piping and attachments such as valves are included as intended for installation a series of tests—perhaps ten—is conducted. 

The use of casein plastics was severely curtailed with the development of synthetic polymers, particularly after the Second World War. In addition stricter regulations concerning health and safety at work will have caused attention to be drawn to the formolising process. In the experience of the author the environment surrounding the formolising baths is most unpleasant and this will have accelerated the demise of the casein manufacturing industry. 

A lead-acid battery consists of electrolytic cells, each containing an anode of porous lead, a cathode of primarily lead peroxide (PbO,), and electrodes of metallic lead. The anode and cathode are separated by nonsulfuric acid and water. 

A clump or globular mass that does not blend completely into the surrounding plastic. 

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