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Phosphite functionality

Since carbohydrates constitute an inexpensive and highly modular chiral source for preparing chiral ligands," Claver et al. have reported the use of a series of thioether-phosphite" and thioether-phosphinite furanoside ligands" in the test palladium-catalysed allylic substitution reaction. In the first type of ligand, a systematic variation of the donor group attached to the carbon atom C5 indicated that the presence of a bulky phosphite functionality had a positive effect on the enantioselectivity. Indeed, the enantioselectivity was controlled mainly by the phosphite moiety. This was confirmed by the use of a ligand... [Pg.20]

The trivalent phosphorus atom in triphenylphosphine is quantitatively oxidized by in-situ-generated or isolated DMD, to afford triphenylphosphine oxide under a variety of conditions Recently, the selective oxidation of the phosphite functionality in nucleosides was reported to produce the corresponding nucleotides in nearly quantitative yields". One example of such an oxidation is shown in equation 16, to illustrate that this phosphorus oxidation may offer an expedient way of preparing unusual nucleotides. [Pg.1154]

Phosphite functionality reduces epoxy viscosity without accelerating cure... [Pg.195]

Phosphite-functionalized polymers were prepared by llthlatlon of brominated poly(styrene-DVB) membranes or beads followed by hydroxyethylation with ethylene oxide and phosphitation with chlorodlalkylphosphlte and a base dlmethylanillne was found to be most suitable (22). Dlmethylanillne hydrochloride, which is formed in the reaction, is highly soluble in chloroform and thus can be conveniently removed without the need for a more polar solvent which may cause solvolysis of the attached... [Pg.22]

A direct comparison of the additive behavior of neutral phosphates and phosphites in the four-ball test under relatively mild conditions is reported in the work of Goldblatt and Appeldoorn [43]. The data shown in Table 11-15 are their findings for 3% of the additive dissolved in a heavy white oil and run in the four-ball machine for 15 minutes at 1200 rpm. In wet air all the phosphates show about the same wear im.provement under a 10 kg load over wear with the base oil in dry argon there is no significant improvement. Tributyl phosphite functions consistently poorer in the wear test than either triallyl or triphenyl phosphite, whose behavior is not significantly different from that of the corresponding phosphates. All the additives improve the performance of the... [Pg.281]

Figure 5. Distribution of cyclooligomerization products as a funciton of the Ni to ligand ratio in the cyclooligomerization of 1,3-butadiene using di-(ortho tolyl)-phosphite functionalized ethylene oligomers in toluene at 100 °C filled circles, 4-vinylcyclohexene squares, ( , ,E)-l,5,9-cyclododecatriene and diamonds,... Figure 5. Distribution of cyclooligomerization products as a funciton of the Ni to ligand ratio in the cyclooligomerization of 1,3-butadiene using di-(ortho tolyl)-phosphite functionalized ethylene oligomers in toluene at 100 °C filled circles, 4-vinylcyclohexene squares, ( , ,E)-l,5,9-cyclododecatriene and diamonds,...
Phosphites function by reducing hydroperoxides to alcohols, and thus, converting themselves to phosphates. [Pg.442]

Function 3 affects performance as determined by the chemistry of alkylate, carboxyl, sulfonyl, phenolic, phosphate, pyrophosphate, and phosphite groups. [Pg.1009]

Cost bilizers. In most cases the alkyl tin stabilizets ate particularly efficient heat stabilizers for PVC without the addition of costabilizers. Many of the traditional coadditives, such as antioxidants, epoxy compounds, and phosphites, used with the mixed metal stabilizer systems, afford only minimal benefits when used with the alkyl tin mercaptides. Mercaptans are quite effective costabilizets for some of the alkyl tin mercaptides, particularly those based on mercaptoethyl ester technology (23). Combinations of mercaptan and alkyl tin mercaptide ate currendy the most efficient stabilizers for PVC extmsion processes. The level of tin metal in the stabilizer composition can be reduced by up to 50% while maintaining equivalent performance. Figure 2 shows the two-roU mill performance of some methyl tin stabilizers in a PVC pipe formulation as a function of the tin content and the mercaptide groups at 200°C. [Pg.548]

Organophosphoms compounds, primarily phosphonic acids, are used as sequestrants, scale inhibitors, deflocculants, or ion-control agents in oil wells, cooling-tower waters, and boiler-feed waters. Organophosphates are also used as plasticizers and flame retardants in plastics and elastomers, which accounted for 22% of PCl consumed. Phosphites, in conjunction with Hquid mixed metals, such as calcium—zinc and barium—cadmium heat stabilizers, function as antioxidants and stabilizer adjutants. In 1992, such phosphoms-based chemicals amounted to slightly more than 6% of all such plastic additives and represented 8500 t of phosphoms. Because PVC production is expected to increase, the use of phosphoms additive should increase 3% aimually through 1999. [Pg.383]

Phosphites Tris-(p-nonylphenyl) phosphite (X) No Widely used in conjunction with conventional stabilisers (q.v.) in PVC. Some types appear to be useful heat and light stabilisers in polyolefins. Function primarily as peroxide decomposers rather than chain-breaking antioxidants. [Pg.137]

Phosphites are also believed to function, at least in part, in this way. Proposed mechanisms for the thio and phosphite compositions are shown in Figure 7.6. [Pg.140]

In addition to stabilisers, antioxidants and ultra-violent absorbers may also be added to PVC compounds. Amongst antioxidants, trisnonyl phenyl phosphite, mentioned previously, is interesting in that it appears to have additional functions such as a solubiliser or chelator for PVC insoluble metal chlorides formed by reaction of PVC degradation products with metal stabilisers. Since oxidation is both a degradation reaction in its own right and may also accelerate the rate of dehydrochlorination, the use of antioxidants can be beneficial. In addition to the phenyl phosphites, hindered phenols such as octadecyl 3-(3,5-di-tcrt-butyl-4-hydroxyphenyI)propionate and 2,4,6-tris (2,5-di-rcrt-butyl-4-hydroxybenzyl)-1,3,5-trimethylbenzene may be used. [Pg.330]

When two antioxidants are used together, a synergistic improvement in activity usually results. Synergism can arise from three combinations (1) homosynergism — two chemically similar antioxidants (for instance, two hindered phenols) (2) autosynergism — two different antioxidants functions that are present in the same molecule (3) heterosynergism — the cooperative effect between mechanistically different classes of antioxidants, such as the combined effect of primary and secondary antioxidants. Thus, combinations of phenols and phosphites are widely used to stabilize synthetic rubbers. [Pg.643]

PD—S) to yield phosphates and alcohols, see Scheme 5 reaction a. Sterically hindered aryl phosphites (e.g., AO 14) have an additional chain breaking activity, i.e. they react with peroxyl and alkoxyl radicals during their function as antioxidants (reactions 5b and 5c) [18]. [Pg.109]

Sulfonic esters are most frequently prepared by treatment of the corresponding halides with alcohols in the presence of a base. The method is much used for the conversion of alcohols to tosylates, brosylates, and similar sulfonic esters. Both R and R may be alkyl or aryl. The base is often pyridine, which functions as a nucleophilic catalyst, as in the similar alcoholysis of carboxylic acyl halides (10-21). Primary alcohols react the most rapidly, and it is often possible to sulfonate selectively a primary OH group in a molecule that also contains secondary or tertiary OH groups. The reaction with sulfonamides has been much less frequently used and is limited to N,N-disubstituted sulfonamides that is, R" may not be hydrogen. However, within these limits it is a useful reaction. The nucleophile in this case is actually R 0 . However, R" may be hydrogen (as well as alkyl) if the nucleophile is a phenol, so that the product is RS020Ar. Acidic catalysts are used in this case. Sulfonic acids have been converted directly to sulfonates by treatment with triethyl or trimethyl orthoformate HC(OR)3, without catalyst or solvent and with a trialkyl phosphite P(OR)3. ... [Pg.576]

An interesting variation of this reaction that made use of a three-component, one-pot solventless procedure with the corresponding trialkyl phosphites gave dramatically improved yields of many heterosubstituted glyphosate phosphonate diesters (37). When exactly one equivalent of water, 25, and tris-p-chloroethyl phosphite were mixed and heated under neat conditions for a few hours, nearly quantitative yields of displaced p-chloroethanol and the desired triester product 27 were obtained. If desired, the displaced alcohol was first removed by vacuum distillation, or the mixture could be hydrolyzed directly to GLYH3. Various oxygen, sulfur, nitrogen, cyano, and carboxylate functionalities were similarly accommodated in the trialkyl phosphite. [Pg.23]

The functionalized benzaldehyde derivative in Scheme 5-41 underwent diastere-oselective addition of diethyl phosphite catalyzed either by LLB (75 25 ratio of di-astereomers) or ALB (80 20 ratio) [30]. [Pg.164]


See other pages where Phosphite functionality is mentioned: [Pg.90]    [Pg.90]    [Pg.249]    [Pg.97]    [Pg.214]    [Pg.217]    [Pg.237]    [Pg.23]    [Pg.852]    [Pg.374]    [Pg.682]    [Pg.51]    [Pg.115]    [Pg.211]    [Pg.90]    [Pg.90]    [Pg.249]    [Pg.97]    [Pg.214]    [Pg.217]    [Pg.237]    [Pg.23]    [Pg.852]    [Pg.374]    [Pg.682]    [Pg.51]    [Pg.115]    [Pg.211]    [Pg.493]    [Pg.356]    [Pg.360]    [Pg.229]    [Pg.438]    [Pg.334]    [Pg.557]    [Pg.120]    [Pg.85]    [Pg.290]    [Pg.384]    [Pg.102]    [Pg.31]    [Pg.480]    [Pg.163]    [Pg.128]   
See also in sourсe #XX -- [ Pg.550 ]




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Functionalizations tris phosphite

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