2- phenyl methylcarbamate

Carbamate pesticides A salt or ester of carbamic acid used as a pesticide and known to cause death of animals at high concentrations. Aldicarb is effective against thrips, aphids, spider mites, lygus, fleahoppers, and leafminers but is mainly used against nematodes. Carbofuran is the most toxic of the carbamate pesticides used to control insects in potatoes, corn, and soybeans. Carbaryl kills beneficial insect and crustacean species along with the target pests. 2-(i-Methylpropyl)phenyl methylcarbamate is used as an insecticide on rice and cotton. 

METHYLETHYL)PHENYL METHYLCARBAMATE O MIPC MIPCIN MIPCINE MIPSIN OMS-32 PHENOL, 0-ISOPROPYL-, METHYLCARBAMATE PHENOL, 2-(l-METHYLETHYL)-, METHYLCARBAMATE (9CI) PPC 3 RO 7-5050... 

C12H15N05 N-carbobenzyloxy-D-serine methyl ester 93204-36-5 25.00 1.2347 2 24314 C12H17N02 2-(1-methylpropyl)phenyl methylcarbamate 3766-81-2 25 lj2 31... 

P-Hydroxy-2P-tropanecarboxylic Acid Methyl Ester, Benzoate 3-Hydroxypropene 3-Hydroxyquinuclidine 3-Hydroxyquinuclidine Benzilate 3-(Mercaptomethyl)-l,2,3-benzotriazin-4(3H)-one 0,0-Dimethyl Phosphorodithioate 3-(Mercaptomethyl)-l,2,3-benzotriazin-4(3H)-one 0,0-Dimethyl Phosphorodithioate S-Ester 3-Methyl-4-(dimethylamino)phenyl Methylcarbamate... 

The role of the sulfur atom in modifying their efficiency has been shown by Durden and Weiden (1969) as well as by Nikles (1969), when demonstrating that the anticholinesterase activity of phenyl methylcarbamates containing a dithiolane... 

Synonyms mixture of m-(l-ethylpropyl) phenyl methylcarbamate and m-(l-methyl-butyl)phenyl methylcarbamate methylcar-bamic acid m-(l-methyl)butyl)phenyl ester mixed with methylcarbamic acid m-(l-ethylpropyl)phenyl ester But Metalkamate... 

Dimethyl-4-(methylthio) phenol methylcarbamate 3,5-Dimethyl-4-(methylthio) phenyl methylcarbamate 3,5-Dimethyl-4-methylthiophenyl-N-methylcarbamate. See Methiocarb... 

Synonyms Carbamic acid, methyl-, o-isopropy I phenyl ester Carbamic acid, methyl-, 2-(1-methylethyl) phenyl ester o-Cumenyl methylcarbamate Isoprocarb o-Isopropylphenol methylcarbamate o-lsopropylphenyl N-methylcarbamate Methyl carbamic acid-o-cumenyl ester 2-(1-Methylethyl) phenyl methylcarbamate MIPC Phenol, o-isopropyl-, methylcarbamate Phenol, 2-(1-methylethyl)-, methylcarbamate Empiricai C11H15NO2... 

Synonyms 3,5-Dimethyl-4-(methylthio) phenol methylcarbamate 3,5-Dimethyl-4-(methylthio) phenyl methylcarbamate 3,5-Dimethyl-4-methylthiophenyl-N-methylcarbamate Mercaptodimethur Methylcarbamic acid-4-(methylthio)-3,5-xylyl ester 4-Methylmercapto-3,5-dimethylphenyl N-methylcarbamate 4-Methylmercapto-3,5-xylyl methylcarbamate 4-Methylthio-3,5-dimethylphenyl methylcarbamate 4 ... 

Methylethyl) phenyl methylcarbamate. See 2-lsopropylphenyl N-methylcarbamate [4-(1-Methylethyl) phenyl] methyl salicylate. See Isopropylbenzyl salicylate 1 -[4-(1 -Methylethyl) phenyl]-3-phenyl-1,3-propanedione. See Isopropyl dibenzoylmethane... 

Other substituted phenyl A/-methylcarbamates that have been used for insect control include metalkamate [8065-36-9] a 1 4 mixture of y -(l-ethylpropyl)-phenyl A[-methylcarbamate [672-04-8] and y -(l-methylbutyl)-phenyl A/-methylcarbamate [2282-34-0], rat oral LD qS 87, 170 mg/kg, used as a soil insecticide MTMC [1129-41 -5], 3-methylphenyl N-methylcarbamate (mp 76°C), rat oral LD q 268 mg/kg, used for rice pests MPMC [2425-10-7], 3,5-dimethylphenyl A/-methylcarbamate (mp 79°C), rat oral LD q 380 mg/kg, used for rice pests TBPMC [780-11-0], 3-/ l -butylphenyl A/-methylcarbamate (mp 140°C), mouse oral LD q 470 mg/kg, for rice pests and butacarb [2655-19-8], 3,5-di-/ l -butylphenyl A/-methylcarbamate (mp 98°C), rat oral LD q >4000 mg/kg, for sheep blowfly larvae control. 

Di-ferf-butyl-4-carbox3 phenyl IV-methylcarbamate, see Terbutol... 

CASRN 2032-59-9 molecular formula C11H16N2O2 FW 208.26 Plant/Surface Water. Several transformation products reported by Day (1991) include 4-amino-/n-tolyl-7V-methylcarbamate (AA), 4-amino-3-methylphenol (AC), 4-formamido-/n-tolyl-TV-methylcarbamate (FA), 7V-(4-hydroxy-2-methylphenyl)-yV-methylformamide (FC), 4-methyl-formamido-/n-tolyl-7V-methylcarbamate (MFA), 4-methylamino-/n-tolyl-Wmethylcarbamate (MAA), 3-methyl-4-(methylamino)phenyl-Wmethylcarbamate (MAC), phenol, methylamine, and carbon dioxide. MAA was not detected in natural water but was detected in fish tissues following exposure to aminocarb-treated water in the laboratory. The metabolites FA, AC, and MAC were detected in Canadian forests treated with aminocarb but the metabolites AA, MAA, and FC were not detected (Day, 1991). 

Initially, the allylation reaction was studied with the /V-benzyloxycarbonylamino sulfone derived from benzaldehyde and benzoyloxycarbonyl (Cbz) carbamate (Scheme 1, R1 = Ph, R = Bn). Various catalysts were screened for the allylation of benzyl phenyl(phenylsulfonyl)methylcarbamate la with allyltrimethylsilane in dichloromethane (Table 1). Among the various Bi catalysts tested, Bi(OTf)3 4H20 was shown to be the most efficient (Table 1, entry 5). BiCl3, BiBr3, Bi(OAc)3, or Bi(OCOCF3)3 did not allow the reaction to proceed and starting material was... 

Conditions benzyl phenyl(phenylsulfonyl)methylcarbamate la (1.0 equiv.), allyltrimethylsilane (1.5 equiv.), metal salt (2 mol%) in dry CH2C12 at 22 °C for 5 h Isolated yield... 

Substituted phenyl N-methylcarbamates (ArOCONHMe) are one of the most widely used agricultural insecticide classes which inhibit acetylcholinesterase (AChE). The steps by which they react with AChE are shown in Eq. 13, where EOH denotes the enzyme. 

Fig. 2. Two reaction pathways of phenyl N-methylcarbamates with acetylcholinesterase the boldfaced arrow indicates an electron pair migration as the driving force of the reaction14) (reproduced with permission from Academic Press, Inc.)...

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