Methyl peroxide

Methyl ethyl ketone peroxide Methyl formate... 

Methyl ethyl ketone peroxide Methyl formate Methyl iodide Methyl isoamyl acetate Methyl isobutyl carbinol Methyl isobutyl ketone (hexone)... 

Methylene chloride 4,4 -Methylerte bis(2-chlofoaniline) Methylene bis(4-cyclo-hexylisocyanate) 4,4 -Medtylerj dianiline Methyl ethyl ketone (MEK) Methyl ethyl ketone peroxide Methyl formate... 

Dimethyl peroxide Diethyl peroxide Di-t-butyl-di-peroxyphthalate Difuroyl peroxide Dibenzoyl peroxide Dimeric ethylidene peroxide Dimeric acetone peroxide Dimeric cyclohexanone peroxide Diozonide of phorone Dimethyl ketone peroxide Ethyl hydroperoxide Ethylene ozonide Hydroxymethyl methyl peroxide Hydroxymethyl hydroperoxide 1-Hydroxyethyl ethyl peroxide 1 -Hydroperoxy-1 -acetoxycyclodecan-6-one Isopropyl percarbonate Isopropyl hydroperoxide Methyl ethyl ketone peroxide Methyl hydroperoxide Methyl ethyl peroxide Monoperoxy succinic acid Nonanoyl peroxide (75% hydrocarbon solution) 1-Naphthoyl peroxide Oxalic acid ester of t-butyl hydroperoxide Ozonide of maleic anhydride Phenylhydrazone hydroperoxide Polymeric butadiene peroxide Polymeric isoprene peroxide Polymeric dimethylbutadiene peroxide Polymeric peroxides of methacrylic acid esters and styrene... 

PEDRiELLi p and SKIBSTED L H (2002) Antioxidant syneigy and regeneration effect of quercetin, (-)epicatechin, and (+)-catechin on a-tocopherol in homogeneous solutions of peroxidating methyl linoleate, JAgric Food Chem, 50, 7138-44. 

Methyl methacrylate poses the same risks as the previous ones. This compound had been exposed to air for two months and polymerised partly. An attempt was made to recover the monomer. This monomer was evaporated by heating it to 60°C instead of 40 C. The medium detonated due to excessive heating of the peroxides that had formed. A study showed that in the presence of air or peroxide, methyl methacrylate gives rise to an auto-accelerated polymerisation during which the ester reaches a temperature of 90°C. Rust catalyses this polymerisation. 

Generated from diacetyl peroxide, methyl radicals attack 2-methylfuran at position 5 preferentially if both 2- and 5-positions are occupied as in 2,5-dimethylfuran there is still little or no attack at the 3(4)-position. If there is a choice of 2(5)-positions, as in 3-methylfuran, then that adjacent to the methyl substituent is selected.249 These orientation rules are very like those for electrophilic substitution, but are predicted for radical attack by calculations of superdelocalizability (Sr) by the simple HMO method. Radical bromination by IV-bromsuccinimide follows theory less closely, presumably because it does not occur through a pure radical-chain mechanism.249... 

Dry deposition terms have also been incorporated in the model based on the values of Derwent et al. (1996) except for peroxides (1.1 cms-1 forH202 and 0.55 cms-1 for organic peroxides), methyl and ethyl nitrate (1.1cm s-1) and... 

Uses Manufacture of vanillin, Michler s ketone, methyl violet, and other dyes solvent reagent for methyl alcohol, hydrogen peroxide, methyl furfural, nitrate, and formaldehyde chemical intermediate stabilizer reagent. 

V-Nitrosodimethylamine was the major product of ozonation of 1,1-dimethylhydrazine in the dark. Hydrogen peroxide, methyl hydroperoxide, and methyl diazene were also identified (HSDB, 1989). 

Lind, J.A. and Kok, G.L. Henry s law determination for aqueous solutions of hydrogen peroxide, methyl hydroperoxide, and peroxyacetic acid, J. Geophys. Res., 91(D7) 7889-7895, 1986. 

O Sullivan, D. W., M. Lee, B. C. Noone, and B. G. Heikes, Henry s Law Constant Determinations for Hydrogen Peroxide, Methyl Hydroperoxide, Hydroxymethyl Hydroperoxide, Ethyl Hydroperoxide, and Peroxyacetic Acid, . /. Phys. Chem., 100, 3241-3247 (1996). 

Pale crepe, 20 phenol-formaldehyde resin, 3 dicumyl peroxide Methyl methacrylate 94 95 94 95... 

Ketone peroxides Methyl ethyl ketone peroxide Cyclohexanone peroxide... 

Calvert and Hanst88 using infrared analysis, have also re-investigated the photooxidation of acetaldehyde at 20°C. using 3130 A. radiation. Acetaldehyde pressures were chiefly about 42.5 nun., but the oxygen pressure was varied from 0 to 745 mm. Analyses were made for carbon monoxide, carbon dioxide, formic acid, methanol, acetic acid, peracetic acid, acetyl peroxide, methyl hydroperoxide, and unreacted acetaldehyde (Table X). Chains were short. Although they do not detect methyl hydroperoxide or diacetyl peroxide, the non-observance of a peroxide does not necessarily mean it is not formed. The decomposition of hydroperoxides on the smallest particle of catalyst is remarkably fast. 

Organic peroxides (methyl ethyl ketone peroxide) Acetyl peroxide, aqueous alkaline hydrogen peroxide Hydrogen peroxide Hydrogen peroxide... 

Young, S. H., Lau, S., Hsieh, Y., and Karel, M., Degradation products of L-tryp-tophan reacted with peroxidizing methyl linoleate, in Autooxidation in Food and Biological Systems, Simic, M. and Karel, G., Eds., Plenum Press, New York, 1980, 237. 

Acrylic monomers are polymerized by a free-radical process with the aid of peroxides. Methyl methacrylate is usually copolymerized with other acrylates (e.g., methyl or ethyl acrylate) for molding and extrusion compounds. Methyl methacrylate is used in a variety of products such as Plexiglas, lighting fixtures, plumbing and bathroom fixtures, surface-coating resins, and in automotive industries for control knobs, instrument covers, and taillights [46]. 

Linear unsaturated and epoxidized polyesters via enzymatic polymerization were reported as well [58]. For this long-chain symmetrically unsaturated a,co-dicarboxylic acid dimethyl esters (C18, C20, C26) were synthesized using metathesis techniques from 9-decanoic, 10-undecanoic, and 13-tetradecanoic acid methyl esters, respectively. The dicarboxylic acid dimethyl esters were epoxidized via chemoenzymatic oxidation with hydrogen peroxide/methyl acetate and Novozym... 

A number of peroxidases were investigated for their use in oxidizing organic sulfides, p-Substituted thioanisols were oxidized by partially purified soybean sulfox-idase using 13(S)-hydroperoxylinoleic acid as the peroxide. Methyl p-tolyl sulfide gave the (S)-sulfoxide with about 90% ee 121. 

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