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Paper validity

This paper validates the assumption that ligands for asymmetric catalysis can be obtained by simple functionalization of common carbohydrates. Condensation of 2-aminoglucose with substituted-2-hydroxybenzaldehydes affords 0,N,0 -tridentate ligands whose activity in the V-catalyzed asymmetric oxidation of thioanisole is reported in Table 9.6. [Pg.296]

This paper is structured as follows in section 2, we recall the statement of the forward problem. We remind the numerical model which relates the contrast function with the observed data. Then, we compare the measurements performed with the experimental probe with predictive data which come from the model. This comparison is used, firstly, to validate the forward problem. In section 4, the solution of the associated inverse problem is described through a Bayesian approach. We derive, in particular, an appropriate criteria which must be optimized in order to reconstruct simulated flaws. Some results of flaw reconstructions from simulated data are presented. These results confirm the capability of the inversion method. The section 5 ends with giving some tasks we have already thought of. [Pg.327]

In this paper, we have exposed a solution to improve the resolution in Low Frequency Ultrasonic Tomography. Since the basic principle of ultrasonic reflection tomography prohibits the inspection of objects with strong contrast and large extension, we turn down the frequency of the transducer, in order to increase the penetration length of the wave and the validity of the method. But this is done at the expense of resolution. [Pg.749]

The correlations used are based partly on theoretical consideration and partly on empirical observations. The basic filtration data are correlated by application of the classic cake-filtration equation, aided by various simplifying assumptions which are sufficiently valid for many (but not all) situations. Washing and drying correlations are of a more empirical nature but with strong experimental justification. If steam or thermal diying is being examined, additional correlations are required beyond those summarized below for such applications, it is advisable to consult an eqmpment manufacturer or refer to pubhshed technical papers for guidance. [Pg.1699]

Actual emission data are available from many handbooks, government publications, and literature searches of appropriate research papers and journals. It is always wise to verify the data, if possible, as to the validity of the source and the reasonableness of the final number. Some emission factors, which have been in use for years, were only rough estimates proposed by someone years ago to establish the order of magnitude of the particular source. [Pg.94]

Bowne, N. E., Validation and performance criteria for air quality models, in "Conference Papers, Second Joint Conference on Applications of Air Pollution Meteorology." American Meteorological Society, Boston, 1980, pp. 614-626. [Pg.342]

Construet, on log-linear graph paper, using asymptotes, and validate using MATLAB or a similar tool, the Bode diagrams for... [Pg.161]

Only a small amount of work has been done up to now concerning the prediction of bond strengths and other properties based on the results of the analysis of the resin. Ferg et al. [59] worked out correlation equations evaluating the chemical structures in various UF-resins with different F/U molar ratios and different types of preparation on the one hand and the achievable internal bond as well as the subsequent formaldehyde emission on the other hand. These equations are valid only for well defined series of resins. The basic aim of such experiments is the prediction of the properties of the wood-based panels based on the composition and the properties of the resins used. For this purpose various structural components are determined by means of - C NMR and their ratios related to board results. Various papers in the chemical literature describe examples of such correlations, in particular for UF, MF, MUF and PF resins [59-62]. For example one type of equation correlating the dry internal bond (IB) strength (tensile strength perpendicular to the plane of the panel) of a particleboard bonded with PF adhesive resins is as follows [17]... [Pg.1053]

For a new process plant, calculations can be carried out using the heat release and plume flow rate equations outlined in Table 13.16 from a paper by Bender. For the theory to he valid, the hood must he more than two source diameters (or widths for line sources) above the source, and the temperature difference must be less than 110 °C. Experimental results have also been obtained for the case of hood plume eccentricity. These results account for cross drafts which occur within most industrial buildings. The physical and chemical characteristics of the fume and the fume loadings are obtained from published or available data of similar installations or established through laboratory or pilot-plant scale tests. - If exhaust volume requirements must he established accurately, small scale modeling can he used to augment and calibrate the analytical approach. [Pg.1269]

Al-Rashed, M.H. and Jones, A.G., 1999a. Validation of a CFD model of a gas-liquid precipitation system. In Industrial Crystallization 99. (Rugby Institution of Chemical Engineers). Cambridge, 13-15 September 1999. Paper 157, p. 160. [Pg.299]

The papers that have been done over the past few years by Hjertager (1989, 1991) and Hjertager et al. (1991a,b) give a review of the validation of the method as well as recent applications to offshore modules. [Pg.367]

The most complicated aspect of the CHIRBASE project effort is the actual incorporation and validation of data. It is largely due to the complexity of the problem and to the difficulty of extracting and interpreting the relevant information, since the vast majority of all useful data is disseminated in the papers rather than in a user-readable or a computer-readable form. [Pg.100]

The importance of the method in corrosion testing and research has stimulated other work, and since Stern s papers appeared there have been a number of publications many of which question the validity of the concept of linear polarisation. The derivation of linearity polarisation is based on an approximation involving the difference of two exponential terms, and a number of papers have appeared that have attempted to define the range of validity of polarisation resistance measurements. Barnartt" derived an analytical expression for the deviations from linearity and concluded that it varied widely between different systems. Leroy", using mathematical and graphical methods, concluded that linearity was sufficient for the technique to be valid in many practical corrosion systems. Most authors emphasise the importance of making polarisation resistance measurements at both positive and negative overpotentials. [Pg.1012]

In all these investigations Lewis acids were used as initiators at temperatures between -30 and 60 °C. The arguments used to substantiate the validity of structure 12 are unconvincing to this reviewer particularly because of the lack of sufficient experimental evidence. A subsequent paper on this subject40 did not improve the understanding of either the polymer structure or the mechanism. [Pg.60]

Chapter 9, on entropy and molecular rotation in crystals and liquids, is concerned mostly with statistical mechanics rather than quantum mechanics, but the two appear together in SP 74. Chapter 9 contains one of Pauling s most celebrated papers, SP 73, in which he explains the experimentally measured zero-point entropy of ice as due to water-molecule orientation disorder in the tetrahedrally H-bonded ice structure with asymmetric hydrogen bonds (in which the bonding proton is not at the center of the bond). This concept has proven fully valid, and the disorder phenomenon is now known to affect greatly the physical properties of ice via the... [Pg.458]

Equations 11 and 12 are only valid if the volumetric growth rate of particles is the same in both reactors a condition which would not hold true if the conversion were high or if the temperatures differ. Graphs of these size distributions are shown in Figure 3. They are all broader than the distributions one would expect in latex produced by batch reaction. The particle size distributions shown in Figure 3 are based on the assumption that steady-state particle generation can be achieved in the CSTR systems. Consequences of transients or limit-cycle behavior will be discussed later in this paper. [Pg.5]

Farland, D. L., McComas, W. F. (2007, 15-18 April). The enhanced (E-DAST) A more valid, efficient, reliable and complete method of identifying students perceptions of scientists. Paper presented at the National Association of Research in Science Teaching (NARST), New Orleans, USA. [Pg.72]

The description of configuration interaction given for rr-electron methods is also valid for all-valence-electron methods. Recently, two papers were published in which the half-electron method was combined with a modified CNDO method (69) and the MINDO/2 method was combined with the Roothaan method (70). Appropriate semiempirical parameters and applications of all-valence-electron methods are most probably the same as those reviewed for closed-shell systems (71). [Pg.342]

The identification of inhibitors of virus subunit assembly has been an objective of virologists for several years but it is only recently that papers have been published that demonstrate the validity of this approach to antiviral chemotherapy. It is hoped that the information provided by the compounds described above will provide the foundation for the generation of potent antiviral drugs to combat diseases caused by HIV, HBV and other viruses. [Pg.169]

Lee N, Beasley HE, Silbum M, et al. 1997b. Validation and application of immunoassays to studies of the environmental fate of endosulfan. 213th National Meeting Of The American Chemical Society, San Francisco, California, USA, April 13-17, 1997. Abstracts of Papers American Chemical Society. Abstract 117. [Pg.303]

A second company in this arena, Entelos, has over the past decade developed numerous disease PhysioLabs. These include comprehensive disease maps that are connected by validated mathematical equations, a knowledge management infrastructure with links to papers and documentation, and... [Pg.142]


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See also in sourсe #XX -- [ Pg.116 , Pg.124 ]




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Quantification and Validation (Paper II)

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