Packing cellulosics

Cellulose fibers are in fhe form of hollow fubes of several hundreds of micromefers long and with a cavity mouth of several micrometers wide. The fiber wall section consists of densely packed cellulose microfibrils, wifh a preferential orientation along the fiber axis. Cellulose microfibrils consisf of glucose units bounded in a /i-conformation favoring straight... 

FIGURE 1.9 The different structural levels of a typical cellulose fiber the fiber wall consists of closely packed cellulose microfibrils oriented mainly in the direction of the fiber. 

One of the most special aspects of cellulose polymorphy is the transformation from I to II. The conversion of the parallel-packed cellulose I structures to an antiparallel cellulose II structure is interesting because it can occur without loss of the fibrous form. This transformation is widely thought to be irreversible, although there are several reports [231-233] of regenerated cellulose I. The observation that there are two different forms of cellulose III and of IV is also remarkable. The two subforms of each allomorph have essentially identical lattice dimensions and at least similar equatorial intensities. Other intensities are different, particularly the meridional intensities, depending on whether the structures were prepared initially from cellulose I or II. The formation of the III and IV structures is reversible and the preceding polymorph (I or II) results. 

Add dialyzed antiserum to the packed cellulose and mix by gentle rotation for 1 hr at room temperature. 

Continuous beds including methacrylate-based disks CIM QA from BIA Separations (Figure 3.22) and SWIFT from Isco, acrylamide UNO monoliths from Bio-Rad, Ultimate polystyrene divinylbenzene disks from LC-Packings, cellulose-based Seprasorb monoliths from Sepragen and silica units Conchrom from Conchrom or Chromolith from Merck are also... 

As Figure 25 8 shows the glucose units of cellulose are turned with respect to each other The overall shape of the chain however is close to linear Consequently neigh boring chains can pack together m bundles where networks of hydrogen bonds stabilize the structure and impart strength to cellulose fibers... 

A common surface cartridge is the pleated paper constmction type, which allows larger filtration areas to be packed iato a small space. Oil filters ia the automobile iadustry are of this type. The paper is impregnated, for strength, with epoxy or polyurethane resia. Any other medium ia sheet form, similar to cellulose paper, such as wool, polypropylene, or glass may be used. 

The superimposition of diffraction spots from both phases gives the previously reported pattern that was thought to require an eight-chain unit cell. In the la stmcture, because of its one-chain unit cell, all chains must have parallel packing. Since the la and ip stmctures exist in the same microfibril of cellulose, the chains in the ip stmcture should also be parallel. 

Similar models for the crystal stmcture of Fortisan Cellulose II came from two separate studies despite quite different measured values of the diffraction intensities (66,70). Both studies concluded that the two chains in the unit cell were packed antiparallel. Hydrogen bonding between chains at the corners and the centers of the unit cells, not found in Cellulose I, was proposed to account for the increased stabiUty of Cellulose II. The same model, with... 

Cellulose III. Cellulose III results from treatment of cellulose with Hquid ammonia (ammonia mercerization) or amines. Cellulose III can be made from either Cellulose I or II. When treated with water. Cellulose III can revert to its parent stmcture. Some cellulose III preparations are much more stable than other preparations. The intensities on diffraction patterns from Cellulose III differ slightly depending on whether the Cellulose III was made from Cellulose I or II, and thus these allomorphs are called IIIj or IHjj- Workers studying III concluded, based partiy on the results of I and II, that the packings of IIIj and IIIjj are parallel and antiparallel, respectively (67). IIIjj also is thought to have hydrogen bonds between the corner and center chains. 

It is difficult for dye solutions in water to penetrate synthetic fibers such as polyester, cellulose triacetate, polyamides, and polyacryUcs which are somewhat hydrophobic. The rate of water imbibition differs with each fiber as shown in Table 1 as compared to viscose (see Fibers, regenerated CELLULOSics), which imbibes water at the rate of 100% (1). The low imbibition rate is attributed to the high T obtained when the polymeric fibers are drawn. During this drawing operation the polymer chains become highly oriented and tightly packed, forming a stmcture practically free of voids. 

Ptdp) filtei. s. These filters employ one or more packs of filtermasse (cellulose fibers compressed to a compact cylinder) stacked into a pressure case. The packs are sometimes supported in individual trays which provide drainage channels and sometimes rest on one another with a loose spacer plate between each two packs and with a drainage screen buried in the center of each pack. The liquid being clarified flows under a pressure of 345 kPa (50 psig) or less through the pulp packs and into a drainage manifold. Flow rates are somewhat less than for disk filters, on the order of 20 L/(min-m ) [0.5 gal/ (min-ft")]. Pulp filters are used chiefly to polish beverages. The filtermasse may be washed in special washers and re-formed into new cakes. 

Strength increase (because the cellulose fibrils pack more closely). To prevent movement, wood should be dried to the value which is in equilibrium with the humidity where it will be used. In a centrally heated house (20°C, 65% humidity), for example, the equilibrium moisture content is 12%. Wood shows ordinary thermal expansion, of... 

Nitration of cellulose followed by plasticisation of the product with camphor has the effect of reducing the orderly close packing of the cellulose molecules. Hence whereas cellulose is insoluble in solvents, except in certain cases where there is chemical reaction, celluloid is soluble in solvents such as acetone and amyl acetate. In addition the camphor present may be dissolved out by chloroform and similar solvents which do not dissolve the cellulose nitrate. 

Cellulose acetate-propionate (Tenite Propionate-Kodak) is similar to cellulose propionate. With the shorter side chains, cellulose propionate and cellulose acetate propionate tend to be harder, stiffer and of higher tensile strength than CAB. Like CAB they are easy to vacuum form and also tend to be used for similar applications such as steering wheels, tool handles, safety goggles and blister packs. 

FIGURE 7.29 Like cellulose, chitin, man-nan, and poly(D-mannuronate) form extended ribbons and pack together efficiently, taking advantage of multiple hydrogen bonds. 

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