Ozone Chapman cycle

However, at the tropopause the temperature profile changes, increasing with altitude throughout the stratosphere. The reason for this increase is a critical series of photochemical reactions involving ozone and molecular oxygen. The Chapman cycle, reactions (l)-(4), hypothesized in the 1930 s by Sir Sydney Chapman,... 

Chapman (1930) first proposed the fundamental ozone-forming and destruction reactions that lead to a steady-state concentration of O, in the stratosphere. These reactions are now known as the Chapman cycle ... 

In this project students review the Chapman cycle mechanism in detail and some photochemistry concepts including the photostationary state. A key element of this project is its focus on an important chemical mechanism and the use of exploratory options for predicting ozone concentrations as a function of time while reviewing other fundamental chemical kinetics concepts. Mathcad is used as the symbolic mathematics engine for solving the requisite differential equations and ample instruction is provided to students to guide them on the use of the software in this project. 

A British scientist Sydney Chapman suggested the basic ideas of stratospheric ozone in the 1930s, which have become known as the Chapman cycle. Short wavelength UV hv) can dissociate molecular oxygen and the atomic oxygen fragments produced react with oxygen molecules to make ozone. 

On the surface there is now an apparent contradiction with only the Chapman cycle we produce too much ozone, whereas the catalytic cycles could destroy all the ozone There are a number of cycles that can interconvert the catalytic cycles without odd oxygen removal these will be in competition with the catalytic cycles, e.g. 

Ozone is formed and destroyed in a series of stratospheric reactions. Its steady state concentration is described by the Chapman cycle. 

Terrestrial stratospheric chemistry is closely linked to the ozone (O3) layer at 15-35 km, which shields the Earth s surface from harmful UV sunlight (X<300 nm) and dissipates the absorbed solar energy as heat. The abundance of O3 in the stratosphere is a balance between production, destruction, and lateral transport. Production and destruction of O3 in the absence of other perturbing influences is described by the Chapman cycle given in Table V. 

Ozone removal by catalytic chlorine chemistry and the Chapman cycle are, therefore, roughly equal at about 40 km. 

A slightly simplified version of the steady-state process for ozone formation (reactions 1 and 2) and destruction (reactions 3 and 4) is known as the Chapman cycle (shown in left margin) after the scientist who proposed it. 

An animation of the Chapman cycle is found at a NASA website. Click on Atmospheric Chemistry under the Atmosphere heading. Then click on ozone and follow by clicking on the panel showing ozone creation to watch a movie of ozone formation, http // visibleearth.nasa.gov/... 

The Chapman cycle for the formation and destruction of stratospheric ozone. 

Chapman Cycle The set of four reactions that represents the steady-state formation and destruction of ozone in the stratosphere. 

It is known that measured ozone concentrations are lower than can be accounted for by the simple Chapman cycle. This has led scientists to look for other influences on the concentration of ozone. First, let s briefly consider one of the natural reactions that destroys ozone. UV radiation can break the oxygen-hydrogen bond of a water molecule in the stratosphere to generate hydrogen atoms and hydroxyl radicals ( OH). These two species are involved in many reactions, some of which actually convert Og to Og. However, this process, which scientists now believe is an efficient process above 50 km, has been occurring since the ozone layer developed, and there is little, if anything, that humans can do about it. The system has obviously attained a steady state that includes this perturbation. 

The Chapman cycle is a series of chemical reactions related to the oxygen-ozone screening... 

Chapter 7 is a new chapter on the relationship between GFGs and the ozone hole, expanded from the four pages in the previous edition. The mechanisms by which oxygen and ozone protect us are discussed in the context of the Chapman Cycle. Scientific responses to the issue and the replacement of CFCs are considered. There is also discussion addressing the relationship between UV exposure and skin cancer. 

In 1903, the British scientist, Sydney Chapman, first explained the chemistry of the formation of ozone in the upper atmosphere when he proposed what is now known as the Chapman cycle. Although Chapman s original proposal was quite speculative, modern measurements of a wide array of quantities support his hypothesis. The Chapman cycle begins and ends with oxygen, the more stable... 

How does the ozone hole arise We must consider the role of species other than the allotropes of oxygen in the Chapman cycle. There is evidence that chlorine and bromine in the stratosphere lead to a decrease in the amount of ozone present. How does this occur What factors influence whether or not the decrease occurs And what might be done to combat the loss of ozone These questions all point to aspects of chemical kinetics that we will address in this chapter. To begin this study, we focus first on the concepts of rate of reaction and the ways in which reaction rate can be measured. 

Earlier, we noted the net reaction of the Chapman cycle 3 O2 3 O2. In some ways, it appears pointless to talk about the kinetics of a reaction that has no net change. But as we have already seen, the importance of the Chapman cycle lies in the details. Without the Chapman cycle, the upper atmosphere would not have an ozone layer, and the quantity of harmful UV radiation reaching the surface of the planet would be significantly greater. This natural cycle points to the importance of the mechanism of the reaction. A reaction mechanism is a collection of one or more molecular steps that account for the way reactants become products. If the overall equation is like a parts list and a finished product, then the mechanism is like the assembly instructions. In many cases, such as the Chapman cycle, if we want to understand the kinetics of the process we must consider the reaction mechanism. What is the stepwise process of bond breaking and bond formation behind the overall reaction ... 

In the formation of ozone through the Chapman cycle, the slow step is the last one the reaction of ozone with atomic oxygen. 

We noted from the outset of this chapter that environmental concerns about ozone depletion arise from tbe increase in the rate of destruction of ozone in the stratosphere. This is a process apparently caused by man-made chemicals. Specifically, chlorofluorocarbons used as refrigerants have been cited as a cause of ozone depletion. Yet a look at the Chapman cycle does not show any obvious role for CFCs. So how can these molecules accelerate the destruction of ozone if they do not even appear in the underlying chemical equations Catalysis is a process in which a reaction rate is influenced by the presence of substances that are neither reactants nor products in the overall equation. A catalyst is a substance that increases the rate of the reaction but is neither created nor destroyed in the process. How can CFCs catalyze ozone depletion ... 

Ozone is considered a pollutant when it forms near the surface of the earth in the troposphere. When it forms in the stratosphere as part of the Chapman cycle, however, it has the beneficial attribute of protecting the planet from harmful UV radiation. 

Chapman cycle (11.1) A series of chemical reactions responsible for the formation and destmction of ozone in the stratosphere. 

On the simplest possible level, the ozone in the stratosphere is maintained by the Chapman mechanism, (13), (16), (22-24) plus the catalytic cycles which in cryptic form are shown as (25)-(30)... 

In these reactions NO is not consumed while it destroys ozone. Rather, NO acts as a catalyst to ozone destruction in a pure oxygen atmosphere. Because it is faster, the catalytic cycle proceeds several times during the same time interval in which the 03 loss reaction of the Chapman mechanism occurs once. 

The ozone destruction processes that must be added to the Chapman mechanism take the form of a catalytic cycle ... 

In 1930, the English geophysicist Sydney Chapman (1888-1970) worked out the cycle of ozone formation and destruction in the stratosphere. There are four chemical reactions in the cycle ... 

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