Other Flows

Environmental Applications Although ion-selective electrodes find use in environmental analysis, their application is not as widespread as in clinical analysis. Standard methods have been developed for the analysis of CN , F , NH3, and in water and wastewater. Except for F , however, other analytical methods are considered superior. By incorporating the ion-selective electrode into a flow cell, the continuous monitoring of wastewater streams and other flow systems is possible. Such applications are limited, however, by the electrode s response to the analyte s activity, rather than its concentration. Considerable interest has been shown in the development of biosensors for the field screening and monitoring of environmental samples for a number of priority pollutants. 

Coriohs meters were first developed in the 1970s and continue to be improved. These meters ate being appHed in many areas that were commonly metered by other flow meter technologies. The greatest appHcation has been in food and chemical processing. 

When choosing the scale-up method, changes in other flow/power parameters and their impact on the process result must be considered. Figure 11 shows changes in important parameters for different scale-up bases. For example, scale-up based on same tip speed maintains the T / Ubut decreases P/ Uby 80%. T / Uis almost always increased on scale-up. Scale-up based on the same P/ Umeans a reduction in mixer speed by 66%, which also... 

Other flow batteries investigated for both electric vehicle appHcation and utiUty load leveling include 2inc [7440-66-6]—[7782-50-5] Zn—Q.25 and zinc—bromine [7726-95-6]., Zn—Br2, batteries (78,81,82). 

S has been approximated for flames stabili2ed by a steady uniform flow of unbumed gas from porous metal diaphragms or other flow straighteners. However, in practice, S is usually determined less directly from the speed and area of transient flames in tubes, closed vessels, soap bubbles blown with the mixture, and, most commonly, from the shape of steady Bunsen burner flames. The observed speed of a transient flame usually differs markedly from S. For example, it can be calculated that a flame spreads from a central ignition point in an unconfined explosive mixture such as a soap bubble at a speed of (p /in which the density ratio across the flame is typically 5—10. Usually, the expansion of the burning gas imparts a considerable velocity to the unbumed mixture, and the observed speed will be the sum of this velocity and S. ... 

Screens and other flow restricdions may also be used to suppress stream swirl and turbulence (Loehrke and Nagib, J. Fluids Fng., 98, 342-353 [1976]). Contraction of the channel, as in a venturi, provides further reduction in turbulence level and flow nouuniformity. 

Other Flow Straightening Deviees Other devices designed to produce uniform velocity or reduce swirl, sometimes with reduced pressure drop, are available. These include both commercial devices of proprietaiy design and devices discussed in the hterature. For pipeline flows, see the references under flow inverters and static mixing elements previously discussed in the Tncompressible Flow in Pipes and Channels subsection. For large area changes, as at the... 

Accuracy Square-edged orifices and venturi tubes have been so extensively studied and standardized that reproducibihties within 1 to 2 percent can be expected between standard meters when new and clean. This is therefore the order of reliabihty to be had, if one assumes (1) accurate measurement of meter differenfial, (2) selection of the coefficient of discharge from recommended published literature, (3) accurate knowledge of fluid density, (4) accurate measurement of critical meter dimensions, (5) smooth upstream face of orifice, and (6) proper location of the meter with respect to other flow-disturbing elements in the system. Care must also be taken to avoid even sh t corrosion or fouliug during use. 

Corrosion involving nonoxidizing acids can be highly sensitive to flow. Thus regions of high flow and turbulence are often more severely attacked than more quiescent regions. Weirs, lips, and other flow obstructions increase turbulence and thus corrosion. Pipe elbows, tees, and joints are frequently attacked. Outer curves at pipe bends often are more severely wasted than inner bends. 

Implementation of advanced performance degradation models, necessitate the inclusion of advanced instrumentation and sensors such as pyrometers for monitoring hot section components, dynamic pressure transducers for detection of surge and other flow instabilities such as combustion especially in the new dry low NO combustors. To fully round out a condition monitoring system the use of expert systems in determining fault and life cycle of various components is a necessity. 

A practical method of predicting the molecular behavior within the flow system involves the RTD. A common experiment to test nonuniformities is the stimulus response experiment. A typical stimulus is a step-change in the concentration of some tracer material. The step-response is an instantaneous jump of a concentration to some new value, which is then maintained for an indefinite period. The tracer should be detectable and must not change or decompose as it passes through the mixer. Studies have shown that the flow characteristics of static mixers approach those of an ideal plug flow system. Figures 8-41 and 8-42, respectively, indicate the exit residence time distributions of the Kenics static mixer in comparison with other flow systems. 

Figure 8-42. F-Function Exit residence time distrubtion for the Kenics Mixer and other flow systems.

Figures 4.34 and 4.35 represent two extreme cases. Drying processes represent the case shown in Fig. 4.34 and distillation processes represent Fig. 4.35. Neither case represents a convective mass transfer case while the gas flow is in the boundary layer, other flows are Stefan flow and turbulence. Thus Eqs. (4.243) and (4.244) can seldom be used in practice, but their forms are used in determining the mass transfer factor for different cases.

The use of tracers for airflow measurement in ventilation ducts is not very common. There are several reasons for this. Compared to other flow measurement methods, tracers require more complicated equipment, skilled personnel, and are more expensive. There are, however, situations when conventional measurement methods are not applicable. For instance, if the space available is small, and hence the flow meter cannot be installed, or if no space is free to carry out traversing measurements, the use of a tracer might be an alternative. 

Flow Rate. The values for volumetric or mass flow rate measurement are often determined by measuring pressure difference across an orifice, nozzle, or venturi tube. Other flow measurement techniques include positive displacement meters, turbine flowmeters, and airflow-measuring hoods. 

Because these calculations are somewhat uncertain due to lack of exact correlations, it is best to calculate pressure drop for other flow patterns, and apply a generous safety factor to the results. 

Table 2-20 gives calculated results for other flow patterns in several different sizes of lines. 

W = required vapor capacity in pounds per hour, or any flow rate in pounds per hour, vapor relief rate to flare stack, Ibs/hr W(. = charge weight of explosive, lb Wj. = effective charge weight, pounds of TNT for estimating surface burst effects in free air W, = required steam capacity flow or rate in pounds per hour, or other flow rate, Ib/hr Whe = hydrocarbon to be flared, Ibs/hr Wtnt equivalent charge weight of TNT, lb Wl = liquid flow rate, gal per min (gpm)... 

This unit consists of two pipes or tubes, the smaller centered inside the larger as shown in Figure 10-92. One fluid flows in the annulus between the tubes the other flows inside the smaller tube. The heat transfer surface is considered as the outside surface of the inner pipe. The fluid film coefficient for the fluid inside the inner tube is determined the same as for any straight tube using Figures 10-46-10-52 or by the applicable relations correcting to the O.D. of the inner tube. For the fluid in the annulus, the same relations apply (Equation 10-47), except that the diameter, D, must be the equivalent diameter, D,.. The value of h obtained is applicable directly to the point desired — that is, the outer surface of the inner tube. ... 

The thermosiphon reboiler has inherent instabilities. A valve or other flow restriction in the inlet line helps overcome these instabilities. Adjustment possibilities of a valve also compensate for variations in reboiler duty as imposed by changes in operation of the fractionator. 

Determining the total friction loss, however, is not as simple. Friction loss is caused by a number of factors and all depend on the flow velocity generated by the pump. The major sources of friction loss include friction between the pumped liquid and the sidewalls of the pipe valves, elbows, and other mechanical flow restrictions or other flow restrictions, such as back-pressure created by the weight of liquid in the delivery storage tank or resistance within the system component that uses the pumped liquid. 

Erosion Corrosion Rates at Jets, Nozzles, Orifices and Other Flow Expansions... 

All in all, this system is more complicated than the other flow batteries and this handicap postpones wider application. 

E. The Connection between Burn-Out and Various Other Flow Patterns 222... 

The annular flow pattern discussed above shows a definite connection with burn-out, and enables a simple burn-out mechanism to be set forth. There are many other flow patterns referred to in the literature, however, and we will consider here what can be said about any connection they may have with burn-out. It does not follow that there must be a connection, as a flow pattern is essentially a description of the bulk conditions in a channel and depends upon the none-too-reliable results of visual observation, which is often impeded by optical distortion. Thus, although gross conditions may appear to change and one pattern give way to another, the hydrodynamic state prevailing close to the heated surface may remain practically unaffected and the burn-out mechanisms unaltered. 

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