Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Structural organosulfur

It is obvious from the FTIR and NMR analyses of these extracts that in order to positively identify organosulfur structures we need an analytical technique that is sulfur selective. That is, a technique that responds to sulfur uniquely. One such technique, applicable to the problem in hand, is GLC-FID/FPD where the flame photometric detector is set in the sulfur selective mode. [Pg.304]

Although desulfurization is a process, which has been in use in the oil industry for many years, renewed research has recently been started, aimed at improving the efficiency of the process. Envii onmental pressure and legislation to further reduce Sulfur levels in the various fuels has forced process development to place an increased emphasis on hydrodesulfurization (HDS). For a clear comprehension of the process kinetics involved in HDS, a detailed analyses of all the organosulfur compounds clarifying the desulfurization chemistry is a prerequisite. The reactivities of the Sulfur-containing structures present in middle distillates decrease sharply in the sequence thiols sulfides thiophenes benzothiophenes dibenzothio-phenes (32). However, in addition, within the various families the reactivities of the Substituted species are different. [Pg.396]

Strong L, Whitesides GM (1988) Structures of self-assembled monolayer films of organosulfur compounds adsorbed on gold single crystals electron diffraction studies. Langmuir 4 546-558... [Pg.195]

Maksymovych P, Voznyy O, Dougherty DB, Sorescu Dan DC, Yates JT (2010) Gold adatom as a key structural component in self-assembled monolayers of organosulfur molecules on Au(l 11). Prog Surf Sci 85 206-240... [Pg.79]

Ultraviolet Photodissociation Studies of Organosulfur Molecules and Radicals Energetics, Structure Identification, and Internal State Distribution (Cheuk-Yiu Ng). [Pg.182]

Mikolajczyk, M., Grzeijszczak, S., and Zatorski, A., Organosulfur compounds IX NMR and structural assignments in a,)3-unsaturated sulphoxides using additive increments method, Tetrahedron, 32, 969, 1976. [Pg.422]

The amount of information on the microbial metabolism of hydrocarbons is much greater than the amount of information on the metabolism of organosulfur compounds (OSC). As work is progressing with studies on the latter group of compounds, results are showing that there are many similarities between the biodegradation pathways of OSC and those of hydrocarbons with similar structures. Therefore, included below is a short section describing some aspects of hydrocarbon metabolism. [Pg.100]

Substitution of alkyl or aryl hydrocarbon groups, such as phenyl and methyl for H on hydrogen sulfide, H2S, leads to a number of different organosulfur thiols (mercaptans, R-SH) and sulfides, also called thioethers (R-S-R). Structural formulas of examples of these compounds are shown in Figure 1.19. [Pg.50]

Many important organosulfur compounds also contain nitrogen. One such compound is thiourea, the sulfur analog of urea. Its structural formula is shown in Figure 1.19. Thiourea and phenylthiourea have been used as rodenticides. Commonly called ANTU, 1-naphthylthiourea is an excellent rodenticide that is virtually tasteless and has a very high rodent human toxicity ratio. [Pg.52]

In the 1940s, it was demonstrated in the pioneering work of Zisman and coworkers [8] that the LB technique is not the only way to create an organized organic monolayer on a solid substrate. It was demonstrated that when a compatible substrate is exposed to a solution of an amphiphilic compound, the dissolved molecules form a self-assembled monolayer on the substrate surface. Such films maintain their structural integrity after they are removed from solution. The most common examples of such films are organosulfur films on gold substrates [9] and alkyltrichlorosilane films on silicon dioxide substrates [10]. Compared with the LB films, the self-assembled films are somewhat less ordered. On the other hand, these films are easier to prepare, since they do not require special instrumentation and can easily be deposited on both planar and non-planar substrates. Also, in many cases the amphiphilic molecules which make the self-assembled film are chemisorbed on the substrate. Such films are more stable when heated or exposed to solvents than are typical LB films, which are held to the substrate by non-covalent interactions. [Pg.644]

Volume 2 begins with a thorough survey of sulfur radical cations, covering their synthesis, structure, stability, and reactivity, by Prof. Richard Glass. Prof. Naomichi Furukawa and Prof. Soichi Sato describe recent developments in the area of hypervalent organosulfur compounds, and the volume is completed by a discussion of the chemistry of thiophene 1,1 -dioxides by Prof. Juzo Nakayama and Prof. Yoshiaki Sugihara. [Pg.192]

You shouldn t at this stage try to leam ail the names for every type of organosulfur compound—what matters is the structures. Here the names are ail very similar and easily confused so. just for reference, here are the structures of a sulfonate ester (such as a tosylate or mesylate), a sulfinate ester, and a sulfenate ester. [Pg.1267]


See other pages where Structural organosulfur is mentioned: [Pg.334]    [Pg.262]    [Pg.334]    [Pg.262]    [Pg.737]    [Pg.92]    [Pg.118]    [Pg.1081]    [Pg.1081]    [Pg.606]    [Pg.193]    [Pg.262]    [Pg.335]    [Pg.213]    [Pg.216]    [Pg.228]    [Pg.767]    [Pg.834]    [Pg.931]    [Pg.33]    [Pg.2]    [Pg.116]    [Pg.44]    [Pg.277]    [Pg.304]    [Pg.308]    [Pg.330]    [Pg.330]    [Pg.347]    [Pg.82]    [Pg.59]    [Pg.117]    [Pg.117]    [Pg.458]   
See also in sourсe #XX -- [ Pg.44 ]




SEARCH



Organosulfur

Organosulfurs

Structure-Chemical Relationships in Organosulfur Compounds

© 2024 chempedia.info