Organometallics polymers

Harrod JF (1988) In Inorganic and organometallic polymers, Zeldin M, Wynn KJ, Alcock HR (eds) ACS Symposium Series 360, Washington DC... 

In summary, for metal surfaces in boundary lubrication, complex tribochemical reactions occur along with the physical/chemical adsorptions, which lead to the formation of surface hlms, consisting of reaction products, oxide layer, the mixture of particles and organometallic polymer, and perhaps a viscous layer. The surface hlms operate as a sacri-... 

There are, however, other classes of inorganic and organometallic polymers that deserve consideration due to their considerable scientific and applicative relevance, such as polysilanes [28-31], polycarbosilanes [32,33],polysilazanes [33],polyborazines [34,35],polythiazenes [36], and, as an example,polymetal-locenylsilanes [37]. 

Carraher CE,Sheats JE, Pittman CU (eds) (1978) Organometallic polymers. Academic, New York... 

Archer RD (2001) Inorganic and organometallic polymers. Wiley-VCH, New York... 

NeUson RH, Hani R, Scheide GM.Wettermark UG,Wisian-NeUson P.Ford RR.RoyAK (1988) In Zeldin M, Wynne KJ, AUcock HR (eds) Inorganic and organometallic polymers. ACS Symposium Series, Washington, chap 22,360 283... 

Gleria M, Bortolus P, Flamigni L, Minto F (1992) In Laine RM (ed) Inorganic and organometallic polymers with special properties. Nato ASI Series E Applied Sciences 206 375... 

Singler, R. E., Sennett, M. S., and Willingham, R. A., Phos-phazene polymers Synthesis, structure, and properties, in Inorganic and Organometallic Polymers (M. Zeldin, K. J. Wynne,... 

Metal-acetylide complexes have been used as a unit of organometallic polymers that have metallic species in the main chain [20]. Representative examples are metal-poly(yne) polymers (19) of group 10 metals depicted in Scheme 5. These polymers are easily prepared from M(PR3)2Cl2 (M=Pt, Pd) and dialkynyl compounds catalyzed by Cu(I) salts in amine. Recently, this synthetic method was successfully applied to the construction of metal-acetylide dendrimers. 

Finally, one additional comment concerning the nature of progress from interdisciplinary research is evident from the results reported in this Symposium Volume. Once again it is seen that most rapid progress is made when synthetic chemists collaborate with their colleagues in materials science or physics to determine properties of new inorganic and organometallic polymers. 

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