Organometallic polymers, thermal dependence

The fibers are produced continuously (endless fibers, filaments) or discontinuously (short or staple fibers) depending upon the application. Most of the fibers are obtained by extruding a flowable form (melt or solution) of appropriate chemieal composition (Section 5.2.3 - 5.2.4). Other processes are based on deposition from the gas phase (Section 5.2.6.2) or thermal transformation (pyrolysis) of organic (Section 5.2.5) or organometallic polymers (Section 5.2.7). 

In this coimection, a cryochemical solid-phase synthesis of metal-polymer systems is of special importance. As a result of such a synthesis, metal clusters and organometallic assemblies formed at low temperatures are buried in a polymer environment, which offers possibilities to stabilize and study these products over a large temperature range. This method was first offered and described in reference 10. The thermal rearrangement of the initial low-temperature system is governed by relaxation processes in polymer matrix. In particular, the aggregation of metal atom clusters to form metal nanocrystals in cryochemically produced metal-polymer systems yields new nanocomposite materials with valuable properties. The study of the mechanism of cluster aggregation, which depends on the characteristics of the polymer matrix, will allow the nanocomposite structure to proceed in the needed direction. Thus, it becomes possible to determine the methods of cryochemical synthesis of metal-polymer materials with predetermined properties. 

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