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Organocopper

The synthesis of allenes from organocopper compounds and acetylenic acetates was... [Pg.153]

The simplest case is the substitution of a halogen at a saturated carbon atom by an alkyl group. Organocopper reagents exhibit strong carbanionic capacity, and do attack ester groups only slowly (D.E. Bergbreiter, 1975). Ketones, however, should be protected. The relative re-... [Pg.19]

Substituted epoxides are attacked by organocopper reagents at the least hindered carbon atom and form alcohols (C.R. Johnson, 1973A). With a, 9-unsaturated epoxides tram-allylic alcohols are produced selectively by 1,4-addltion (W. Carruthers, 1973 G.H. Posner, 1972). [Pg.21]

Organocopper compounds used for carbon-carbon bond formation are called Gilman reagents in honor of Henry Gilman who first stud led them Gilman s career in teaching and research at Iowa State spanned more than half a century (1919-1975)... [Pg.603]

CONJUGATE ADDITION OF ORGANOCOPPER REAGENTS TO a,p-UNSATURATED CARBONYL COMPOUNDS... [Pg.780]

This procedure illustrates a general method for the preparation of alkenes from the pal 1 adium(Q)-cata1yzed reaction of vinyl halides with organo-lithium compounds, which can be prepared by various methods, including direct regioselective lithiation of hydrocarbons. The method is simple and has been used to prepare a variety of alkenes stereoselectively. Similar stoichiometric organocopper reactions sometimes proceed in a nonstereoselective... [Pg.45]

G. H. Posner, An Introduction to Synthesis Using Organocopper Reagents (J. Wiley, New York, 1980). [Pg.94]

The TiVC) coordinated organocopper compounds 260 and 261 were obtained from 2-lithiothiophene and copper cyanide and iodide, respectively (990M1571). [Pg.40]


See other pages where Organocopper is mentioned: [Pg.153]    [Pg.154]    [Pg.242]    [Pg.602]    [Pg.603]    [Pg.408]    [Pg.36]    [Pg.726]    [Pg.73]    [Pg.699]    [Pg.602]    [Pg.603]    [Pg.703]    [Pg.292]    [Pg.1]    [Pg.1]    [Pg.6]    [Pg.7]    [Pg.8]    [Pg.8]    [Pg.8]    [Pg.9]    [Pg.12]    [Pg.16]    [Pg.16]    [Pg.17]    [Pg.17]    [Pg.19]    [Pg.19]    [Pg.22]    [Pg.22]    [Pg.23]    [Pg.25]    [Pg.26]   
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1,4-addition functionalized organocopper compounds

2-Cyclopentenone, 2-methylconjugate additions chiral organocopper compounds

Acetals reactions with organocopper compounds

Acetals, allylic reaction with organocopper compounds

Acid chlorides organocopper compounds

Acyl halides with organocopper compounds

Acylation organocopper reagents

Additions with Organocopper Reagents Derived from CuCN-2LiBr-Based Active Copper

Alkane Synthesis Using Organocopper Reagents

Alkenyl organocopper reagent

Alkyl halides reactions with organocopper reagents

Alkyl halides with organocopper reagents

Alkylation organocopper-mediation

Alkynes organocopper compounds

Alkynes organocopper reagents

Alkynes organocoppers

Alkynes reaction with organocopper reagents

Alkynes, alkoxysynthesis organocopper compounds

Allyl halides with organocopper compounds

Allylic organocopper reagents

Amides reactions with organocopper complexes

Amines Organocopper reagents

Aryl halides with organocopper compounds

Arylation and Alkynylation of Neutral Organocopper Compounds

Aziridines reaction with organocopper

Benzylic organocopper reagents

Boron trifluoride reactions with organocopper compounds

Cadiot-Chodkiewicz coupling organocopper compounds

Conjugate addition of organocopper

Conjugate addition of organocopper reagents

Conjugate addition organocopper compounds

Conjugate addition reactions of organocopper reagents

Conjugate addition reactions with organocopper reagents

Conjugate organocopper-mediated

Copper Compounds Organocopper reagents

Copper organocopper compound addition

Coriolin organocopper compounds

Coupling of organocopper reagents

Coupling reactions Organocopper reagents

Cycloalkylidene epoxides, a-methylenemacrocyclic reaction with organocopper compounds

Dioxolenes reaction with organocopper compounds

Enones, 367. organocoppers

Epoxides organocopper compounds

Epoxides organocopper reagents

Epoxides with organocopper reagents

Esters (cont addition of organocopper reagents

Esters acetylenic, addition of organocopper reagents

Esters reaction with organocopper reagents

Ethers, epoxy reaction with organocopper compounds

Halides organocopper compounds

Halides reaction with organocopper reagents

Homoleptic Organocopper Compounds CunRn

Hydrazone, bis reactions with organocopper complexes

Hydrazones, a-alkoxyacyclic reactions with organocopper reagents

Imides, a-allenylreaction with organocopper reagents

Imines reactions with organocopper complexes

Imines, N-acylreactions with organocopper complexes

Imines, N-acylreactions with organocopper complexes reactivity

Iminium chlorides, aci-nitroreactions with organocopper complexes

Iminium chlorides, aci-nitroreactions with organocopper complexes synthesis of ketoximes

Ketones reactions with organocopper compounds

Leukotriene via organocopper reagents

Menthol, phenylcrotonate ester addition reactions with organocopper reagents

Nature of Organocopper Reagents

Nucleophilic reaction with organocopper

Opening reactions with organocopper compounds

Organo organocoppers

Organocopper 1,4-addition

Organocopper Chemistry. Edited by Norbert Krause opyright

Organocopper Compounds as Intermediates in Organic Syntheses

Organocopper II) compounds

Organocopper alkylation

Organocopper allylic substitution

Organocopper and -silver compounds

Organocopper chemistry

Organocopper complexes

Organocopper complexes 3-unsaturated carbonyls

Organocopper complexes addition reactions

Organocopper complexes aldehydes

Organocopper complexes alkynes

Organocopper complexes carboxylates

Organocopper complexes dimerization reactions

Organocopper complexes ketones

Organocopper complexes nitriles

Organocopper complexes olefins

Organocopper complexes organometallics

Organocopper complexes oxidation reactions

Organocopper complexes preparation

Organocopper complexes reactions

Organocopper complexes reduction

Organocopper compound alkynylation

Organocopper compound arylation

Organocopper compounds

Organocopper compounds Lewis acid-activation

Organocopper compounds acylation

Organocopper compounds addition reactions

Organocopper compounds alkenes

Organocopper compounds alkylation

Organocopper compounds alkylations

Organocopper compounds bonding

Organocopper compounds catalysts

Organocopper compounds chiral

Organocopper compounds conjugate

Organocopper compounds coordinating substituents

Organocopper compounds coordination numbers

Organocopper compounds coupling

Organocopper compounds cross-coupling reactions

Organocopper compounds crystallization

Organocopper compounds decomposition

Organocopper compounds determination

Organocopper compounds diorganocuprates

Organocopper compounds enolates

Organocopper compounds functionalized

Organocopper compounds heteroleptic

Organocopper compounds in nucleophilic aliphatic

Organocopper compounds mechanism

Organocopper compounds oxidation

Organocopper compounds preparation

Organocopper compounds reaction with amines

Organocopper compounds reaction with electrophiles

Organocopper compounds reaction with epoxides

Organocopper compounds rearrangement

Organocopper compounds solubility

Organocopper compounds stability

Organocopper compounds stabilization

Organocopper compounds stereoselective alkylation

Organocopper compounds substitution

Organocopper compounds synthesis

Organocopper compounds thermal decomposition

Organocopper compounds thermal stability

Organocopper compounds vinylation

Organocopper compounds, and

Organocopper compounds, reaction with

Organocopper compounds, reactions

Organocopper compounds, reactions with acyl halides

Organocopper compounds, reactions with alkyl halides

Organocopper compounds, reactions with allyl halides

Organocopper compounds, reactions with aryl halides

Organocopper compounds, reactions with dienes

Organocopper compounds, reactions with enynes

Organocopper compounds. See

Organocopper compounds. See Lithium diorganocuprates

Organocopper formation

Organocopper intermediate

Organocopper reactions

Organocopper reactions 2- benzothiazole

Organocopper reagent, conjugate

Organocopper reagent, conjugate carbonyl addition reactions

Organocopper reagents

Organocopper reagents 462 Reagent

Organocopper reagents Lipshutz)

Organocopper reagents additions

Organocopper reagents alkenes

Organocopper reagents alkylations

Organocopper reagents alkynyl

Organocopper reagents allylic halides

Organocopper reagents catalysis

Organocopper reagents catalysts

Organocopper reagents conjugate additions

Organocopper reagents coupling

Organocopper reagents cross-coupling reactions

Organocopper reagents development

Organocopper reagents enolates

Organocopper reagents formation

Organocopper reagents higher-order

Organocopper reagents homocuprates

Organocopper reagents mechanism

Organocopper reagents palladium catalysis

Organocopper reagents preparation

Organocopper reagents reactions

Organocopper reagents reactions with enones

Organocopper reagents reactivity

Organocopper reagents stable intermediates

Organocopper reagents stoichiometric

Organocopper reagents synthetic utility

Organocopper reagents-Boron trifluoride etherate

Organocopper reagents. See

Organocopper species

Organocopper, Silver, and Gold Compounds

Organocopper-mediated Alkylation

Organocopper-mediation reduction-alkylation

Organocopper/zinc reagents

Organocopper/zirconium reagents

Organocoppers

Organocoppers

Organocoppers exchange with

Organocoppers formation

Organocoppers organometallics

Organocoppers reactions with

Organocoppers, 154. reacting with enones

Organocoppers, amination

Organometallic compounds organocopper

Organometallic reagents organocopper compounds

Oxabetweenallenes organocopper compounds

P-Lactones reaction with organocopper compounds

Preparation and Structure of Organocopper Reagents

Preparation of Active Copper and Reaction with Organic Halides to Yield Organocopper Reagents

Preparation of Functionalized Organocopper Reagents

Preparation of Organocopper Reagents

Preparation of organometallics organocopper

Propargyl bromide, coupling with an organocopper reagent

Reaction mechanisms organocopper compounds

Reaction of Allyl Organocopper Reagents Derived from CuCN-2LiBr with Benzoyl Chloride

Reaction of Organocopper Reagent

Reaction of Organocopper Reagent with Acid Chlorides

Reactions Involving Organocopper Intermediates

Reactions Involving Organocopper Reagents and Intermediates

Reactions of organocopper intermediates

Rearrangements reaction with organocopper compounds

Reduction organocopper-mediation

Schiff bases reactions with organocopper complexes

Section 1.2 Organocopper Reagents

Serine reaction with organocopper compounds

Substitution reactions using organocopper

Substitution reactions using organocopper reagents

Substitution reactions, of organocopper

Thermal Stability and Bonding in Organocopper(l) Compounds

Transmetalation Reactions Producing Organocopper Reagents

Ullmann reaction organocopper compounds

Unsaturated carbonyl compounds Organocopper reagents

Unsaturated carbonyl compounds reaction with organocopper reagents

Vinyl halides with organocopper compounds

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