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Organocopper compounds,

Brown et al. [270] applied high performance liquid chromatography to the determination of organocopper speciation in soil-pore waters. [Pg.146]

Reactions of Organic Halides and Pseudo-Halides -COjEt + MeCu(NCy2)Li — [Pg.243]

See also page 420, Section 2.5 page 421, Section 2.8 page 434, Section 2.11 and page 445, Section 2.19., R2Cu-MgX2 or [Pg.452]

For the use of vinylic copper reagents and X = COSiPh3 or C02R, see page 506, Section 3.22. [Pg.457]

E+ =H20, D20,I2, Me3Sia, TsCN (E = CN), ClC02Et [cat PdCl2(PPh3)2], RCOC1, RCHO JOC 60 5370 (1995) tyCssCHOfeZiiBr [Pg.460]


The synthesis of allenes from organocopper compounds and acetylenic acetates was... [Pg.153]

Organocopper compounds used for carbon-carbon bond formation are called Gilman reagents in honor of Henry Gilman who first stud led them Gilman s career in teaching and research at Iowa State spanned more than half a century (1919-1975)... [Pg.603]

The TiVC) coordinated organocopper compounds 260 and 261 were obtained from 2-lithiothiophene and copper cyanide and iodide, respectively (990M1571). [Pg.40]

Ttansmetalation of tliioetliets to organocopper compounds can also be performed in some special cases. Tluis, tteatment of the ester 119 with MeyCuLi-LiCN provides the copper reagent 120, which can be treated successfully witli several electrophiles such as allyl bromide ot acid chlorides to afford the expected products such as 121 iScbeme 2.54) [115, 116]. [Pg.68]

As precursors of the organocopper compounds, organolithium reagents are slightly preferable to organomagnesium halides. [Pg.904]

The relative reactivity of organocopper compounds in additions to 6 and 7 is as follows vinyl > aryl > isopropyl > ethyl > methyl. [Pg.904]

When X=OH, this conversion of acetylenic alcohols to unsaturated aldehydes or ketones is called the Meyer-Schuster rearrangement The propargyl rearrangement can also go the other way that is, 1-haloalkenes, treated with organocopper compounds, give alkynes. ... [Pg.423]

Organocopper compounds have been trapped by coordination with organic bases. In addition, arylcopper compounds (ArCu) have been independently prepared and shown to give biaryls (ArAr ) when treated with aryl iodides (Ar I). A similar reaction has been used for ring closure. [Pg.871]

Pentafluorophenylcopper is representative of a series of fluori-nated organocopper compounds that are highly soluble in organic solvents, more thermally stable than their hydrocarbon analogs, and useful as synthetic intermediates. " Pentafluorophenylcopper has been used to introduce the pentafluorophenyl groups and as a reagent for an improved Ullman diphenyl ether synthesis. It is... [Pg.64]


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1,4-addition functionalized organocopper compounds

2-Cyclopentenone, 2-methylconjugate additions chiral organocopper compounds

Acetals reactions with organocopper compounds

Acetals, allylic reaction with organocopper compounds

Acid chlorides organocopper compounds

Acyl halides with organocopper compounds

Alkynes organocopper compounds

Alkynes, alkoxysynthesis organocopper compounds

Allyl halides with organocopper compounds

Aryl halides with organocopper compounds

Arylation and Alkynylation of Neutral Organocopper Compounds

Boron trifluoride reactions with organocopper compounds

Cadiot-Chodkiewicz coupling organocopper compounds

Conjugate addition organocopper compounds

Copper Compounds Organocopper reagents

Copper organocopper compound addition

Coriolin organocopper compounds

Cycloalkylidene epoxides, a-methylenemacrocyclic reaction with organocopper compounds

Dioxolenes reaction with organocopper compounds

Epoxides organocopper compounds

Ethers, epoxy reaction with organocopper compounds

Halides organocopper compounds

Homoleptic Organocopper Compounds CunRn

Ketones reactions with organocopper compounds

Opening reactions with organocopper compounds

Organocopper

Organocopper Compounds as Intermediates in Organic Syntheses

Organocopper II) compounds

Organocopper and -silver compounds

Organocopper compound alkynylation

Organocopper compound arylation

Organocopper compounds Lewis acid-activation

Organocopper compounds acylation

Organocopper compounds addition reactions

Organocopper compounds alkenes

Organocopper compounds alkylation

Organocopper compounds alkylations

Organocopper compounds bonding

Organocopper compounds catalysts

Organocopper compounds chiral

Organocopper compounds conjugate

Organocopper compounds coordinating substituents

Organocopper compounds coordination numbers

Organocopper compounds coupling

Organocopper compounds cross-coupling reactions

Organocopper compounds crystallization

Organocopper compounds decomposition

Organocopper compounds determination

Organocopper compounds diorganocuprates

Organocopper compounds enolates

Organocopper compounds functionalized

Organocopper compounds heteroleptic

Organocopper compounds in nucleophilic aliphatic

Organocopper compounds mechanism

Organocopper compounds oxidation

Organocopper compounds preparation

Organocopper compounds reaction with amines

Organocopper compounds reaction with electrophiles

Organocopper compounds reaction with epoxides

Organocopper compounds rearrangement

Organocopper compounds solubility

Organocopper compounds stability

Organocopper compounds stabilization

Organocopper compounds stereoselective alkylation

Organocopper compounds substitution

Organocopper compounds synthesis

Organocopper compounds thermal decomposition

Organocopper compounds thermal stability

Organocopper compounds vinylation

Organocopper compounds, and

Organocopper compounds, reaction with

Organocopper compounds, reactions

Organocopper compounds, reactions with acyl halides

Organocopper compounds, reactions with alkyl halides

Organocopper compounds, reactions with allyl halides

Organocopper compounds, reactions with aryl halides

Organocopper compounds, reactions with dienes

Organocopper compounds, reactions with enynes

Organocopper compounds. See

Organocopper compounds. See Lithium diorganocuprates

Organocopper, Silver, and Gold Compounds

Organocoppers

Organometallic compounds organocopper

Organometallic reagents organocopper compounds

Oxabetweenallenes organocopper compounds

P-Lactones reaction with organocopper compounds

Reaction mechanisms organocopper compounds

Rearrangements reaction with organocopper compounds

Serine reaction with organocopper compounds

Thermal Stability and Bonding in Organocopper(l) Compounds

Ullmann reaction organocopper compounds

Unsaturated carbonyl compounds Organocopper reagents

Unsaturated carbonyl compounds reaction with organocopper reagents

Vinyl halides with organocopper compounds

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