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Organic solvents, cellulose

Viet D, Beck-Candanedo S, Gray DG. Dispersion of cellulose nanocrystals in polar organic solvents. Cellulose 2007 14 109-13. [Pg.284]

Cellulosics. CeUulosic adhesives are obtained by modification of cellulose [9004-34-6] (qv) which comes from cotton linters and wood pulp. Cellulose can be nitrated to provide cellulose nitrate [9004-70-0] which is soluble in organic solvents. When cellulose nitrate is dissolved in amyl acetate [628-63-7] for example, a general purpose solvent-based adhesive which is both waterproof and flexible is formed. Cellulose esterification leads to materials such as cellulose acetate [9004-35-7], which has been used as a pressure-sensitive adhesive tape backing. Cellulose can also be ethoxylated, providing hydroxyethylceUulose which is useful as a thickening agent for poly(vinyl acetate) emulsion adhesives. Etherification leads to materials such as methylceUulose [9004-67-5] which are soluble in water and can be modified with glyceral [56-81-5] to produce adhesives used as wallpaper paste (see Cellulose esters Cellulose ethers). [Pg.234]

Most cellulose acetate is manufactured by a solution process, ie, the cellulose acetate dissolves as it is produced. The cellulose is acetylated with acetic anhydride acetic acid is the solvent and sulfuric acid the catalyst. The latter can be present at 10—15 wt % based on cellulose (high catalyst process) or at ca 7 wt % (low catalyst process). In the second most common process, the solvent process, methylene chloride replaces the acetic acid as solvent, and perchloric acid is frequentiy the catalyst. There is also a seldom used heterogeneous process that employs an organic solvent as the medium, and the cellulose acetate produced never dissolves. More detailed information on these processes can be found in Reference 28. [Pg.294]

Suspension polymerization of VDE in water are batch processes in autoclaves designed to limit scale formation (91). Most systems operate from 30 to 100°C and are initiated with monomer-soluble organic free-radical initiators such as diisopropyl peroxydicarbonate (92—96), tert-huty peroxypivalate (97), or / fZ-amyl peroxypivalate (98). Usually water-soluble polymers, eg, cellulose derivatives or poly(vinyl alcohol), are used as suspending agents to reduce coalescence of polymer particles. Organic solvents that may act as a reaction accelerator or chain-transfer agent are often employed. The reactor product is a slurry of suspended polymer particles, usually spheres of 30—100 pm in diameter they are separated from the water phase thoroughly washed and dried. Size and internal stmcture of beads, ie, porosity, and dispersant residues affect how the resin performs in appHcations. [Pg.386]

Diacetone Alcohol. Diacetone alcohol (DAA) (4-hydroxy-4-methyl-2-pentanone) is a colorless, mild smelling Hquid which is completely miscible with water and most organic solvents. It is the simplest aldol condensation product of acetone, and because of its keto-alcohol functionahes it has special utility in the coatings industry where it is used to dissolve cellulose acetate to give solutions with high tolerance for water (115). [Pg.493]

Production of cellulose esters from aromatic acids has not been commercialized because of unfavorable economics. These esters are usually prepared from highly reactive regenerated cellulose, and their physical properties do not differ markedly from cellulose esters prepared from the more readily available aHphatic acids. Benzoate esters have been prepared from regenerated cellulose with benzoyl chloride in pyridine—nitrobenzene (27) or benzene (28). These benzoate esters are soluble in common organic solvents such as acetone or chloroform. Benzoate esters, as well as the nitrochloro-, and methoxy-substituted benzoates, have been prepared from cellulose with the appropriate aromatic acid and chloroacetic anhydride as the impelling agent and magnesium perchlorate as the catalyst (29). [Pg.251]

Uses. Cellulose nitrates with differing nitrogen contents have various appHcations (Table 3). The largest iadustrial use of CN is protective and decorative lacquer coatings. CN is soluble ia a variety of organic solvents and yields clear, tough films. CN is also compatible with many plasticizers and resias. [Pg.268]

Unlike HEC and CMC, which are purified by washing with aqueous organic solvents, methylceUulose and its hydroxyalkyl modifications are purified in hot water where they are insoluble. As with other cellulose ethers, drying and grinding complete the process. [Pg.277]

Properties. Ethyl cellulose [9004-57-3] (EC) is a nonionic, organo-soluble, thermoplastic cellulose ether, having an ethyl DS in the range of 2.2-2.7. Actually, EC is water-soluble at DS 1.2, but only those products that are thermoplastic and soluble in organic solvents are of commercial importance, because of thek abiUty to form tough, stable films. Above a DS of about 2.5, EC is soluble in many nonpolar solvents. [Pg.278]

Properties. Hydroxypropylcellulose [9004-64-2] (HPC) is a thermoplastic, nonionic cellulose ether that is soluble in water and in many organic solvents. HPC combines organic solvent solubiUty, thermoplasticity, and surface activity with the aqueous thickening and stabilising properties characteristic of other water-soluble ceUulosic polymers described herein. Like the methylceUuloses, HPC exhibits a low critical solution temperature in water. [Pg.279]

Cyclohexanoae is miscible with methanol, ethanol, acetone, benzene, / -hexane, nitrobenzene, diethyl ether, naphtha, xylene, ethylene glycol, isoamyl acetate, diethylamine, and most organic solvents. This ketone dissolves cellulose nitrate, acetate, and ethers, vinyl resias, raw mbber, waxes, fats, shellac, basic dyes, oils, latex, bitumea, kaure, elemi, and many other organic compounds. [Pg.425]

Cellulose acetate butyrate is not affected by dilute acids and alkalies or gasoline, but chlorinated solvents cause some swelhng. Nylons resist many organic solvents but are attacked by phenols, strong oxidizing agents, and mineral acids. [Pg.2458]

A variety of synthetic polymers, including polycarbonate resins, substituted olefins, and polyelectrolyte complexes, are employed as ultrafiltration membranes. Many of these membranes can be handled dry, have superior organic solvent resistance, and are less sensitive to temperature and pH than cellulose acetate, which is widely used in RO systems. [Pg.345]

If paraffin permeates a white opaque paper, one can read letters through the paper because the paper becomes transparent. This phenomenon is based on the simple principle that micropores in the paper are filled with paraffin, which has a refractive index that is close to that of cellulose. If the porous PVA-PVAc composite film is soaked in organic solvents having the same refractive indices as that of PVA, the porous film is expected to become transparent again, according to the same principle as the phenomenon between paraffin and cellulose. On the basis of this consideration, subsequent experi-... [Pg.173]

The membrane is critically important in osomometry. Selection of a membrane involves reconciliation of high permeability toward the solvent with virtual impermeability to the smallest polymer molecules present in the sample. Membranes of cellulose are most widely used. Commercially Regenerated cellulose film is a common source. The undried gel cellophane film is often preferred, but the dry film may be swollen in water (or in aqueous solutions of caustic or zinc chloride ) to satisfactory porosity. Useful cellulose membranes may also be prepared by denitration of nitrocellulose films/ and special advantages have been claimed for bacterial cellulose films. The water in the swollen membrane in any case may be replaced by a succession of miscible organic solvents ending with the one in which osmotic measurements are to be made. Membranes of varying porosity may be... [Pg.278]


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See also in sourсe #XX -- [ Pg.199 ]




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