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Non-basic

In concentrated sulphuric acid. The way in which the rate of nitration of some non-basic compounds depends upon acidity in the region above that of maximum rate ( 90% sulphuric acid) has been discussed ( 2.3.2). Cationic species behave similarly (table 2.4, fig. 2.1). [Pg.152]

An alternative approach is to assume, in the light of the experimental evidence just mentioned, that the reactions of cations and neutral molecules have similar values of (or, equivalently, of log ( /l mol and to try to calculate the difference which would arise from the fact that the observed entropy of activation for a minority free base includes a contribution from the acidic dissociation of the conjugate acid in the medium in question (see (5) above). Consider the two following reaction schemes one (primed symbols) represents nitration via the free base, the other the normal nitration of a non-basic majority species (unprimed symbols) ... [Pg.157]

Torgov introduced an important variation of the Michael addition allylic alcohols are used as vinylogous a -synthons and 1,3-dioxo compounds as d -reagents (S.N. Ananchenko, 1962, 1963 H. Smith, 1964 C. Rufer) 1967). Mild reaction conditions have been successful in the addition of ],3-dioxo compounds to vinyl ketones. Potassium fluoride can act as weakly basic, non-nudeophilic catalyst in such Michael additions under essentially non-acidic and non-basic conditions (Y. Kitabara, 1964). [Pg.71]

The nucleophilicity of the nitrogen atom survives in many different functional groups, although its basicity may be lost. Reactions of non-basic, but nucleophilic urea nitrogens provide, for example, an easy entry to sleeping-pills (barbiturates) as well as to stimulants (caffeine). The nitrogen atoms of imidazoles and indole anions are also nucleophilic and the NH protons can be easily substituted. [Pg.306]

Non-basic materials, including nitro compounds were removed from aniline in 40% H2SO4 by passing steam through the soln for Ih. Pellets of KOH were added to liberate the aniline which was steam distd, dried with KOH, distd twice from zinc dust at 20mm, dried with freshly prepared BaO, and finally distd from BaO in an allglass apparatus [Few and Smith J Chem Soc 753 7949]. Aniline is absorbed by skin and is TOXIC... [Pg.113]

Steam distd from a soln containing 1-2 equivalents of 20% H2SO4 until about 10% of the base had been carried over with the non-basic impurities, then the acid soln was made alkaline, and the base separated, dried with NaOH and fractionally distd twice. Dried with Na and fractionally distd through a Todd column packed with glass helices (see p. 174). [Pg.279]

The nitrogen atom included in the lactam group is non-basic and is conveniently distinguished as N(a), the second and basic nitrogen being written N(6). [Pg.561]

Forsyth et al. found that gelsemicine contains three active hydrogen atoms (Zerewitinov determination), yields a non-basic, monobenzoyl derivative, m.p. 232°, and behaves as a secondary base giving JV-methyl-gelsemicine hydriodide, m.p. 227°, on treatment with methyl iodide. It does not react with either hydroxylamine or 2 4-dinitrophenylhydrazine. On hydrogenation in dry acetic acid in presence of Adams s platinic oxide catalyst it absorbs three molecules of hydrogen. [Pg.739]

Nitrogen compounds in crudes may generally be classified into basic and non-basic categories. Basic nitrogen compounds are mainly those having a pyridine ring, and the non-basic compounds have a pyrrole structure. Both pyridine and pyrrole are stable compounds due to their aromatic nature. [Pg.16]

Primary Raw Materials for Petrochemicals 17 Non-Basic Nitrogen Compounds... [Pg.17]

El eliminations begin with the same uni molecular dissociation we saw in the Sfsjl reaction, but the dissociation is followed by loss of H+ from the adjacent carbon rather than by substitution. In fact, the El and SN1 reactions normally occur together whenever an alkyl halide is treated in a protic solvent with a non-basic nucleophile. Thus, the best El substrates are also the best SN1 substrates, and mixtures of substitution and elimination products are usually obtained. For example, when 2-chloro-2-methylpropane is warmed to 65 °C in 80% aqueous ethanol, a 64 36 mixture of 2-methyl-2-propanol (Sjql) and 2-methylpropene (El) results. [Pg.392]

The amide bond that links different amino acids together in peptides is no different from any other amide bond (Section 24.3). Amide nitrogens are non-basic because their unshared electron pair is delocalized by interaction with the carbonyl group. This overlap of the nitrogen p orbital with the p orbitals of the carbonyl group imparts a certain amount of double-bond character to the... [Pg.1028]

Phenyl trimethylsilylethyne (Chapter 20) undergoes a fluoride-ion-catalysed addition to aldehydes and ketones. This provides a remarkably mild, relatively non-basic method for the generation of an alkynyl anion or its equivalent. [Pg.34]

Inhibition of o-Glucosidase Aj from Aspergillus wentii and / D-Gluco idase B (Ref. 51) from Bitter Almonds by Basic and Non-Basic Derivatives of D-Glucose... [Pg.334]

Y Picoline. Commercially pure y-picoline contains )S-picoline and 2 6-lutidine and sometimes traces of non-basic impurities (aromatic hydrocarbons) which cannot be separated by fractionation. The non-basic impurities are removed by steam distillation of the base in dilute hydrochloric or sulphuric acid solution (for details, see under a Picoline). The impure y-picoline is converted into the zinc chloride complexes of the component bases the 2 6-lutidine - ZnClj complex is the least stable and upon steam distillation of the mixture of addition compounds suspended in water, 2 6-lutidine passes over flrst. The complete separation of the 2 6-lutidine may be detected by a determination of the density and the refractive index of the dry recovered base at varioiu stages of the steam distillation. The physical properties are —... [Pg.178]

Quinoline that has been purified by steam distillation of an acid solution should be used. Crude quinoline sometimes contains non-basic, high-boiling impurities such as nitrobenzene, which make the purification of m-nitrostyrene more difficult. [Pg.92]

Pyrrole (68) also has 6n electrons in delocalised n orbitals, but here the nitrogen atom has to contribute two electrons to make up the six (thus becoming essentially non-basic in the process, cf. p. 73), and the dipole of pyrrole is found to be in the opposite direction to that of pyridine, i.e. with the positive end on nitrogen and the negative end on the nucleus ... [Pg.166]

Examples of the nitrogen compounds commonly found in crude oil were included in Table 2. In the diesel fraction, the population comprises basic and non-basic compounds, such as quinoline, indole, and carbazole families. [Pg.33]

Carbazole is a non-basic nitrogen compound, whose removal via hydrotreating is limited by its low reactivity. The removal of nitrogen by hydrotreatment involves a number of steps that take place on the catalyst surface. The weak interaction of neutral nitrogen compounds with catalysts precludes carbazole and its derivatives from being denitro-genated and makes them the most recalcitrant components in HDN of gas oils [308], In fact, it has been found that the nitrogen content of hydrotreated gas oil from Athabasca bitumen was composed primarily of alkyl carbazoles [309],... [Pg.152]


See other pages where Non-basic is mentioned: [Pg.209]    [Pg.114]    [Pg.178]    [Pg.178]    [Pg.144]    [Pg.213]    [Pg.278]    [Pg.343]    [Pg.347]    [Pg.148]    [Pg.228]    [Pg.278]    [Pg.352]    [Pg.381]    [Pg.400]    [Pg.719]    [Pg.756]    [Pg.164]    [Pg.164]    [Pg.296]    [Pg.184]    [Pg.17]    [Pg.378]    [Pg.178]    [Pg.110]    [Pg.169]    [Pg.67]    [Pg.18]    [Pg.18]    [Pg.34]    [Pg.151]   
See also in sourсe #XX -- [ Pg.18 ]




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