Neat and reinforced polyamides

Table 4.41 displays some examples of tribological properties of neat and reinforced polyamides (the figure preceding the reinforcement or additive indicates its % loading). The coefficients of friction are in a good range, from 0.1 up to 0.3 for the static coefficients, and wear varies from near 1 (excellent) up to more than 100 (fair). 

Table 4.47 Neat and reinforced polyamides 610 and 612 examples of properties...

Figure 4.113 displays three examples of flexural strength retention versus temperature for neat, carbon fibre reinforced and glass fibre reinforced polyamide-imides. The three curves are not distinguishable note the steady decay up to 260°C. 

Figure 6.8 plots the reinforcement ratios for short glass fibre reinforced polyamide (PA-GF) versus neat polyamide for six important characteristics calculated versus density and material cost. These characteristics are tensile strength, tensile and flexural modulus, impact strength, HDT A and B. 

The endurance benefits and performance characteristics of polyamide-imides qualify them to be an excellent replacement for metal in aerospace components. Inherent nonflammability, chemical resistance, and superb strength at elevated temperatures allow polyamide-imide compounds to be used in metal applications once unheard of for plastic materials. Neat resin, friction and wear, along with glass- and carbon-reinforced polyamide-imide compounds are incorporated in a variety of parts and locations in aerospace vehicles. 

In this chapter, results from the tensile, flexural and impact tests on HDPE/PA6 and HDPE/PA12 MFC are presented, studying the effects of the compatibilizer, HDPE and PA concentration, as well as the form and arrangement of the reinforcing entities on the mechanical behavior. The UDP MFC laminae were used for tensile tests. Impact strength and three-point flexural tests were performed on the CPC laminates. MRB and NOM composites were analyzed with the three mechanical tests. The data were compared with those of the neat HDPE matrix material and/or the oriented polyamide component [69]. 

Polyamide-imides (PAIs) are thermoplastic amorphous polymers prepared by the condensation of an aromatic diamine, such as methylene diamine, and an anhydride, such as trimellitic add chloride. PAIs have good mechanical, thermal, chemical resistance, high strength, melt processability, and high heat capacity. They can be processed into a variety of forms, such as injection or compression molded articles, coatings, films, fiber, and adhesives. The typical heat deflection temperature for neat molded PAI is 278°C,but reinforcements are often used to improve mechanical properties. PAIs are generally soluble in strong aprotic solvents such as NMP and DMAc, and thus misdble blends with PBI are feasible. 

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