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Near-zone boundary conditions

Near- and Far-Zone Boundary Conditions Resulting from the Form of the Phase Factors and Parametrization of the Interaction Tensor... [Pg.74]

Modeling of the transport of the long-lived nuclides, especially U, require knowledge of the input at the water table as a boundary condition for aquifer profiles. There are few studies of the characteristics of radionuclides in vadose zone waters or at the water table. Significant inputs are likely to occur to the aquifer due to elevated rates of weathering in soils, and this is likely to be dependent upon climatic parameters and has varied with time. Soils may also be a source of colloids and so provide an important control on colloidal transport near recharge regions. [Pg.355]

Figure 5.20. The flamelet model requires the existence of unmixed regions in the flow. This will occur only when the mixture-fraction PDF is non-zero at = 0 and = 1. Normally, this condition is only satisfied near inlet zones where micromixing is poor. Beyond these zones, the flamelets begin to interact through the boundary conditions, and the assumptions on which the flamelet model is based no longer apply. Figure 5.20. The flamelet model requires the existence of unmixed regions in the flow. This will occur only when the mixture-fraction PDF is non-zero at = 0 and = 1. Normally, this condition is only satisfied near inlet zones where micromixing is poor. Beyond these zones, the flamelets begin to interact through the boundary conditions, and the assumptions on which the flamelet model is based no longer apply.
The last issue that remains to be addressed is whether the MBL results are sensitive to the characteristic diffusion distance L one assumes to fix the outer boundary of the domain of analysis. In the calculations so far, we took the size L of the MBL domain to be equal to the size h - a of the uncracked ligament in the pipeline. To investigate the effect of the size L on the steady state concentration profiles, in particular within the fracture process zone, we performed additional transient hydrogen transport calculations using the MBL approach with L = 8(/i — a) = 60.96 mm under the same stress intensity factor Kf =34.12 MPa /m and normalized T-stress T /steady state distributions of the NILS concentration ahead of the crack tip are plotted in Fig. 8 for the two boundary conditions, i.e. / = 0 and C, =0 on the outer boundary. The concentration profiles for the zero flux boundary condition are identical for both domain sizes. For the zero concentration boundary condition CL = 0 on the outer boundary, although the concentration profiles for the two domain sizes L = h - a and L = 8(/i - a) differ substantially away from the crack tip. they are very close in the region near the crack tip, and notably their maxima differ by less than... [Pg.195]

The Presumed Probability Density Function method is developed and implemented to study turbulent flame stabilization and combustion control in subsonic combustors with flame holders. The method considers turbulence-chemistry interaction, multiple thermo-chemical variables, variable pressure, near-wall effects, and provides the efficient research tool for studying flame stabilization and blow-off in practical ramjet burners. Nonreflecting multidimensional boundary conditions at open boundaries are derived, and implemented into the current research. The boundary conditions provide transparency to acoustic waves generated in bluff-body stabilized combustion zones, thus avoiding numerically induced oscillations and instabilities. It is shown that predicted flow patterns in a combustor are essentially affected by the boundary conditions. The derived nonreflecting boundary conditions provide the solutions corresponding to experimental findings. [Pg.205]

The reaction scheme at and near the phase boundary during the phase transformation is depicted in Figure 10-14. The width of the defect relaxation zone around the moving boundary is AifR, it designates the region in which the relaxation processes take place. The boundary moves with velocity ub(f) and establishes the boundary conditions for diffusion in the adjacent phases a and p. The conservation of mass couples the various processes. This is shown schematically in Figure 10-14b where the thermodynamic conditions illustrated in Figure 10-12 are also taken into account. The transport equations (Fick s second laws) have to be solved in both the a and p... [Pg.255]

Figure 5.11 Schematic diagrams of the FASS model, (a) Capillary conditioned with a BGE, sample, injection and a high positive voltage, (b) focusing of analytes near the boundaries between the sample zone and BGE, and (c) stacked analytes separated [97]. Figure 5.11 Schematic diagrams of the FASS model, (a) Capillary conditioned with a BGE, sample, injection and a high positive voltage, (b) focusing of analytes near the boundaries between the sample zone and BGE, and (c) stacked analytes separated [97].
Assuming a fixed band structure (the rigid band model), a decrease in the density of states is predicted for an increase in the electron/atom ratio for a Fermi surface that contacts the zone boundary. It will be recalled that electrons are diffracted at a zone boundary into the next zone. This means that A vectors cannot terminate on a zone boundary because the associated energy value is forbidden, that is, the first BZ is a polyhedron whose faces satisfy the Laue condition for diffraction in reciprocal space. Actually, when a k vector terminates very near a BZ boundary the Fermi surface topology is perturbed by NFE effects. For k values just below a face on a zone boundary, the electron energy is lowered so that the Fermi sphere necks outwards towards the face. This happens in monovalent FCC copper, where the Fermi surface necks towards the L-point on the first BZ boundary (Fig. 4.3f ). For k values just above the zone boundary, the electron energy is increased and the Fermi surface necks down towards the face. [Pg.190]

For solving Eq. (15), appropriate boundary conditions must be prescribed. Normally, the boundary of the machining zone consists of several sections at which the boundary conditions of different types are prescribed. The type of the boundary conditions depends on the character of the boundary section TE, WP, insulator, or the line (the plane of symmetry), and also on the operating conditions of the power supply the conditions of stabilization of the applied voltage, the conditions of current stabilization, and the natural current-voltage characteristics. In the general case, the boundary conditions that account for the kinetics of the electrode reactions and the transfer processes in the near-electrode diffusion layers can be written as follows ... [Pg.829]

In the first example shown in Table 9.2, a warm (25°C) water from the ocean s surface (1 atm) has been modeled. In the zone near the equator, where this water sample had been taken, carbon dioxide partial pressures of 400 patm (equivalent to a pCO of 0.0004 atm or a log pCO of -3.40) have been measured which is somewhat higher than the corresponding atmospheric value. This sample of ocean water thus displays a CQ -gradient directed towards the atmosphere and therefore continually releases CQ into the atmosphere. This situation is accounted for in the model by pre-setting pCO to 0.0004 atm as an open boundary condition with regard to CQ. Accordingly, a state of supersaturation ensues equivalent to a SI, , value of 0.77 or an f2, , value of 5.9. Such a supersaturation state is, according to the... [Pg.321]

As was pointed out earlier in this chapter, an opaque solid absorbs radiation in a narrow zone near the surface rather than attenuating within its volume so, the second term on the right side of Equation 19.12 must appear in the boundary condition. Thus, the boundary condition given by Equation 19.15 transforms to... [Pg.409]

This solution clearly does not satisfy the boundary condition at the particle surface. However, the above solution is valid for most of the interior region of the catalyst, except for a thin zone very close to the particle surface. This solution, therefore, is called the outer solution. (g) To find the solution that is valid close to the particle surface, the coordinate must be stretched (magnified) near the surface as... [Pg.214]

At high intensities a laser-supported detonation (LSD) wave is ignited. In this case absorption takes place in a thin zone of hot, high-pressure air behind the detonation wave (see Fig. 4). Since this wave takes air away from the surface, expansion fans form to satisfy the boundary conditions at the target surface. The plasma remains nearly one-dimensional until the expansion fans from the edge reach the center. This time is given approximately by the beam radius divided by the speed of sound in the plasma. In the vicinity of the surface there is no laser absorption... [Pg.6]

The other boundary conditions (at the inlet, at the outlet, and at the interfaces between successive zones) remain the same as for the one-dimensional model. Solving Eq. (5.123) may seem exhausting, but the application of a standard mathematical technique, namely separation of variables, is very helpful. To understand its working, first consider that a function of several variables/(x,y,z) can always be expanded in a local Taylor series, for example, near (0,0,0) as... [Pg.134]

Cell-level models solve the species [Eq. (26.1)], momentum [Eq. (26.5)], and energy [Eq. (26.7)] conservation equations using the effective properties of the electrodes and can include the electrochemistry using a continuum-scale (Section 26.2.4.1) or a mesoscale (Section 26.2.4.2) approach. Traditionally, cell-level models use a continuum-scale electrochemistry approach, which includes the electrochemistry as a boundary condition at the electrode-electrolyte interface [17, 51, 54] or over a specified reaction zone near the interface. The electrochemistry is modeled via the Nernst equation [Eq. (26.12)] using a prescribed current density and assumptions for the polarizations in the cell. The continuum-scale electrochemistry is then coupled to the species conservation equation [Eq. (26.1)] using Faraday s law ... [Pg.756]


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See also in sourсe #XX -- [ Pg.74 , Pg.76 ]




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Boundary zones

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