Multifunctional polyester-based

Multifunctional Polyester-Based Materials with Controlled Degradability... 

The core-first approach is based on the initiation of polymerization by a multifunctional initiator. The number of arms is then defined by the number of functional units present on the core. In order to have a good control of the molecular structure of star-shaped polyesters, the initiation must be quantitative and fast. It is also mandatory to avoid possible side-reactions between the initiating species on the core. 

Thus, in alkyd, polyester, and epoxy coatings applied to CRS, phosphatized steel, and aluminum, the use of ZAs APG (aminofunctional) and CPG (carboxy-functional) has allowed for the virtual elimination of blister formation and corrosion after 300 h of salt fog exposure. The use of multifunctional ZAs in a Kraton base adhesive has allowed for a 52% increase in T-peel strength on EPDM rubber when compared with the same adhesive containing aminofunctional silane. Incorporation of mercaptofunctional ZA into crosslinkable elastomers has... 

The choice exists between using a one-part or a two-part formulation. One-part formulations are based on polyurethanes of very high molecular weight that are still soluble in petroleum-ester mixtures. Two-part adhesives are normally used where high cohesive strength and improved heat resistance are required and these comprise with the prepolymer terminated in some active group (such as polyether or polyester polyols) and as the second part either a multifunctional isocyanate (e.g., MDl) or an isocyanate... 

Poly (styrene), saturated polyahcycUc resins and terpene phenol reduce viscosity and impart high flow to the resulting composition. For this reason, the polymers added are sometimes addressed as flow promoters. The materials have some adverse effect as they reduce the heat deflee-tion temperature of the product and increase the flanunability. High flow polyphenylene ether resin compositions have been described." Dendrilie polymers based on polyesters with multifunctional hydroxy compounds offer the advantage to be effective in smaller amounts in comparison to common flow improvers." In addition, heterogeneous blends of PPE with PA have been introduced. 

The most frequently apphed technique for the separation of polymers, namely size-exclusion chromatography (SEC), is based on the well-balanced interactions between the column material, the solvent, and the polymer sample. In order to achieve a complete separation according to size, and also to determine reliable polydispersity values, enthalpic interactions between the sample and column material must be excluded, as only entropic interactions lead to SEC separation. This is not always possible in the case of dendritic polymers which, being multifunctional architectures, have interactions with the column material that are effectively predestined. It has been repeatedly observed that this problem is more severe for higher molar mass products. An example of aromatic hb polyesters with different... 

Dendritic polymers based on polyesters with multifunctional hydroxy compounds offer the advantage to be effective in smaller amounts in comparison to common flow improvers [48], In addition, heterogeneous blends of PPE with PA have been introduced. 

In this approach, AB2 type or other similar monomers such as AB (x = 4, 6, 8, etc.) monomers are polymerised by a polycondensation reaction. Gelation, a general problem in the polymerisation of multifunctional monomers, is avoided by the use of a dilute solution and the slow addition of monomer(s). Vegetable oil-based hyperbranched polyhydrocarbons, polyethers, polyesters, polyamides, and so on may be prepared by this method. 

Nuclear magnetic resonance (NMR) spectroscopy is one of the other basic methods for structural analysis. Aluri et al. [16] proposed a one-pot synthesis route to obtain two polymers of ABB for linear polyester and hyperbranched poly(ester-urethane)s based on multifunctional L-amino acid monomers using a temperature-selective melt... 

Vinylester (VE) resins are prepared by an addition reaction between epoxy resin (difunctional or multifunctional) with an unsaturated carboxylic acid such as acrylic acid or methacrylic acid [77]. The simplest form of VE is the product of the reaction between one mole of diglycidyl ether of BPA and 2 moles of methacylic acid (Figure 2.21). The reaction is carried out at about 100 °C using a catalyst such as triphenyl phosphine. To stop the polymerisation of methacylic acid, an inhibitor such as hydroquinone is used. By changing the nature of base epoxy resin, various types of VE resins can be produced. The vinyl-ended prepolymer is then dissolved in styrene to produce a polymerisable resin similar to an unsaturated polyester resin. Styrene content is adjusted to provide a wide range of viscosities, typically 0.1-4 Pa-s. 

Glass fiber reinforced composites based on epoxy-acrylate modified UPRs were studied [228]. The authors showed that UPRs, endcapped with acrylate groups and diluted with reactive multifunctional acrylic and allylic monomers in the presence of a photoinitiator, can be photocrosslinked with UV radiation as glass fiber laminates in a rapid process. It was found that the physical properties of the photo-crosslinked laminates are well correlated with the molecular weight of the polyester, the amount of multifunctional monomer added, and the glass fiber content. A greater improvement of the tensile and flexural properties of the photocured products was observed for multifunctional acrylate or acrylether monomers added to the UPR (Table 31) than for allylic monomers. 

One of the developments in the field of PSAs is the category of UV-crosslinkable, solvent-free, low-viscosity acrylic PSAs systems. These systems contain unsaturated polyurethanes and multifunctional acrylates in contrast to other PSA systems comprising acrylic polyester and photoreactive acrylic hot melts. They are likely to have significant market potential based on the degree of cohesion achieved (measured according to the self-adhesive failure temperature (°C)). 

---