Morphology composite materials

Wool fibers have a very complex morphological stmcture. They can be considered as biological composite materials, in which the various regions are both chemically and physically different (87). Fine wool fibers contain two types of cell those of the internal cortex and those of the external cuticle. 

Recent demands for polymeric materials request them to be multifunctional and high performance. Therefore, the research and development of composite materials have become more important because single-polymeric materials can never satisfy such requests. Especially, nanocomposite materials where nanoscale fillers are incorporated with polymeric materials draw much more attention, which accelerates the development of evaluation techniques that have nanometer-scale resolution." To date, transmission electron microscopy (TEM) has been widely used for this purpose, while the technique never catches mechanical information of such materials in general. The realization of much-higher-performance materials requires the evaluation technique that enables us to investigate morphological and mechanical properties at the same time. AFM must be an appropriate candidate because it has almost comparable resolution with TEM. Furthermore, mechanical properties can be readily obtained by AFM due to the fact that the sharp probe tip attached to soft cantilever directly touches the surface of materials in question. Therefore, many of polymer researchers have started to use this novel technique." In this section, we introduce the results using the method described in Section 21.3.3 on CB-reinforced NR. 

The coastal race conforms to P. menziesii var. menziesii, whereas the inland races accord well with P. menziesii var. glauca (Beissn.) Franco, the form known from the Rocky Mountains. There is no established morphological equivalent to the Sierra Nevada race trees from that area are usually referred to var. menziesii. Zavarin and Snajberk (1975), however, sununarized differences between trees harvested in the Sierra Nevada Mountains and those harvested in northwestern California with regard to commercial applications, particularly in the manufacture of plywood or the production of composite materials (particle board). Differences in such factors... 

Other polymer materials which can be prepared include latexes, or particle agglomerates, by dispersed phase polymerisation. These can be either hydrophilic or hydrophobic in nature, or may have core-shell morphologies. They can be employed as support materials for a number of catalyst systems. Polymerisation of both phases of the emulsions produces composite materials, which have found use as selective membranes for the separation of mixtures of liquids with similar physical properties. 

Given the existence of interphases and the multiplicity of components and reactions that interact to form it, a predictive model for a priori prediction of composition, size, structure or behavior is not possible at this time except for the simplest of systems. An in-situ probe that can interogate the interphase and provide spatial chemical and morphological information does not exist. Interfacial static mechanical properties, fracture properties and environmental resistance have been shown to be grealy affected by the interphase. Careful analytical interfacial investigations will be required to quantify the interphase structure. With the proper amount of information, progress may be made to advance the ability to design composite materials in which the interphase can be considered as a material variable so that the proper relationship between composite components will be modified to include the interphase as well as the fiber and matrix (Fig. 26). 

Synthesis of solid state materials using surfactant molecules as template has been extensively used in this decade. Among the advantages of the use of amphiphilic molecules, the self-assembling property of the surfactants can provide an effective method for synthesising ceramic and composite materials with interesting characteristics, such as nanoscale control of morphology, and nano or mesopore structure with narrow and controllable size distribution [1-5]. 

HAPEX, a bone analogue material, with similar properties to cortical bone, was added to a HDPE matrix in different volumes (20% and 40%) to produce composite materials [271]. Confocal laser scanning microscopy (CLSM) was then used to examine cell morphology on HAPEX and the surface characteristics produced by different machining protocols. 

FIGURE 8.25 SEM showing the morphology of a PANI/CNT composite material containing 80wt% of PANI. (From Khomenko, V., et al., Electrochim. Acta, 50, 2499, 2005. With permission.)... 

The network morphology of the phase-separated composite material for enhanced transport and carrier generation. Absorption and mobility of charge carriers has to be maximized within the different components of the bulk heterojunction. 

Zhang, Y. L., R. W. Blanchar, and R. D. Hammer. 1993. Composition and pyrite morphology of materials separated from coal. In Proceeding of 10th National Meeting of American Society of Surface Mining and Reclamation, Vol. 2. Spokane, WA, May 16-19,1993. pp. 284-297. 

In utilizing the Scherrer equation, care must be exercised to properly account for instrumental factors which contribute to the measured peak width at half maximum. This "intrinsic" width must be subtracted from the measured width to yield a value representative of the sample broadening. When the experimental conditions have been properly accounted for, reasonably accurate values for the average crystallite size can be determined. Peak shapes and widths, however, can also provide other information about the catalyst materials being studied. For example, combinations of broad and sharp peaks or asymmetric peak shapes in a pattern can be manifestations of structural disorder, morphology, compositional variations, or impurities. 

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