Transition morphological

O. Shochet, K. Kassner, E. Ben-Jacob, S. G. Lipson, H. Miiller-Krumbhaar. Morphology transitions during non-equilibrium growth I. Study of equilibrium shapes and properties. Physica A 757 136, 1992. 

Sakurai S., Kawada H., Hashimoto T., and Fetters L.J. Thermoreversible morphology transition between spherical and cyUndrical microdomains of block copolymers. Macromolecules, 26, 5796, 1993. 

Koberstein J.T., Gancarz I., and Clarke T.C., The effect of morphological transition on hydrogen bonding in PU Preliminary results of simultaneous DSC-FTIR experiments, J. Polym. Sci. B, 24, 2487, 1986. Skrovanek D.J., Painter P.C., and Coleman M.M., Hydrogen bonding in polymers 2. Infra red temperature studies on nylon 11, Macromolecules, 19, 699, 1986. 

Phase transitions of the PS-fo-PI system have been extensively studied. The morphological transition from the I phase to the G phase proceeds through nucleation and growth. The difference in the geometrical characteristics of these two phases induces considerable local distortion of both morphologies... 

Court and Hashimoto [186] investigated morphological transitions triggered by blending two block copolymers with different volume fractions. 

An indication of such a morphological transition is a pronounced enhancement of oxide film roughness at a thickness of 11 nm, observed by AFM, as shown in Fig. 5.5. The appearance of this surface ripple corresponds to the first potential peak in Fig. 5.4. An investigation using differential IR spectroscopy revealed that the peak position, width and degree of symmetry of the Si-O absorption bands... 

Proton conductivities of 0.1 S cm at high excess water contents in current PEMs stem from the concerted effect of a high concentration of free protons, high liquid-like proton mobility, and a well-connected cluster network of hydrated pathways. i i i i Correspondingly, the detrimental effects of membrane dehydration are multifold. It triggers morphological transitions that have been studied recently in experiment and theory.2 .i29.i ,i62 water contents below the percolation threshold, the well-hydrated pathways cease to span the complete sample, and poorly hydrated channels control the overall transports ll Moreover, the structure of water and the molecular mechanisms of proton transport change at low water contents. 

The benefits of utihzing combinatorial methods for investigating polymer properties have been outlined recently [19,166,167]. Polymer gradient brush assemblies are expected to play an active role in further combinatorial material effort. Possible areas of interest include (but are not hmited to) study of phase behavior (stability) in hquid [168] and polymer blend [169] systems, morphological transitions in block copolymers [170,171], cell culturing [58,172], and others. 

Maitani MM, Daniel TA, Cabarcos OM, Allara DL (2009) Nascent metal atom condensation in self-assembled monolayer matrices coverage-driven morphology transitions from buried adlayers to electrically active metal atom nanofilaments to overlayer clusters during aluminum atom deposition on alkanethiolate/gold monolayers. J Am Chem Soc 131 (23) 8016-8029... 

Photoirradiation of supramolecular 27 decreased the absorption due to the sorboyl groups, indicating that polymerization had occurred [367], Polymerization at 70 °C was accompanied by morphological transitions to well-... 

For the most part, even qualitative relationships between such structural considerations and film properties are lacking. Recently, however, two important correlations have been presented Device quality a-Si contains only monohydride bonding structures (207), and the intrinsic film stress rises drastically as a morphological transition from columnar to noncolumnar growth occurs (210). Both studies point to the importance of defects in a-Si, although the precise role of these defects is still unclear. 

A. Blom, G. G. Warr, and E. J. Wanless. Morphology transitions in nonionic surfactant adsorbed layers near their cloud points. Langmuir, 21(25) 11850-11855, 2005. 

Frkanec, L., Jokic, M., Makarevic, J., Wolsperger, K., Zinic, M., Bis(PheOH) maleic acid amide-fumaric acid amide photoizomerization induces microsphere-to-gel fiber morphological transition The photoinduced gelation system. J. Am. 

Figure 28 Effect of d/L0(AB) (MC simulation result origins from Figure 9 in (Xiao etai, 2007)) on morphology transitions of AB copolymers at different curvature K of (a) 0 (b) 0.03125 (c) 0.04167 and (d) 0.0625. "inco means "incompatible region, while co n is a compatible region between d and L0(AB) with N ayer = n.

XN = 30, and N = 20). Lines 1-3 concentric cylinder barrel phase at K= 0.01,0.02, and 0.03, respectively lines 4-6 sector column phase at K = 0.01, 0.02, and 0.03, respectively lines 7-9 complex multilayered sector column phase at K = 0.01, 0.02, and 0.03, respectively, (b) A sketch of morphology transition for a set of competing structures between the concentric cylinder barrel phase and the sector column phase in part (a), where sec means the sector column phase, and conVj means the concentric cylinder barrel structure with N ayer = n. 

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